Oyonite, Ag3Mn2Pb4Sb7As4S24, a New Member of the Lillianite Homologous Series from the Uchucchacua Base-Metal Deposit, Oyon District, Peru
Abstract
:1. Introduction
2. Mineral Description and Physical Properties
3. Chemical Data
4. Crystallography
5. Results and Discussion
5.1. Crystal Structure Description
5.2. Relation to the Other Species
Supplementary Materials
Author Contributions
Acknowledgments
Conflicts of Interest
References
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Element | wt (%) (n = 5) | Range | Estimated Standard Deviation |
---|---|---|---|
Cu | 0.76 | 0.50–1.05 | 0.02 |
Ag | 8.39 | 8.08–8.91 | 0.10 |
Mn | 3.02 | 2.89–3.22 | 0.07 |
Pb | 24.70 | 24.55–25.81 | 0.25 |
As | 9.54 | 9.11–9.82 | 0.12 |
Sb | 28.87 | 28.24–29.61 | 0.21 |
S | 24.30 | 23.63–24.71 | 0.18 |
Total | 99.58 | 99.18–100.41 | 0.23 |
Crystal Data | |
Crystal size (mm3) | 0.045 × 0.055 × 0.070 |
Cell setting, space group | Monoclinic, P21/n |
a (Å) | 19.1806 (18) |
b (Å) | 12.7755 (14) |
c (Å) | 8.1789 (10) |
β (°) | 90.471 (11) |
V (Å3) | 2004.1 (4) |
Z | 2 |
Data collection and Refinement | |
Radiation, wavelength (Å) | MoKα, λ = 0.71073 |
Temperature (K) | 293 |
2θmax (°) | 64.63 |
Measured reflections | 27568 |
Unique reflections | 6272 |
Reflections with Fo > 4σ(Fo) | 2199 |
Rint | 5.01 |
Rσ | 6.16 |
Range of h, k, l | −27 ≤ h ≤ 28, 0 ≤ k ≤ 18, 0 ≤ l ≤ 12 |
R [Fo > 4σ(Fo)] | 0.0227 |
R (all data) | 0.0317 |
wR (on Fo2) | 0.0756 |
Number of least-squares parameters | 206 |
Maximum and minimum residual peak (e Å−3) | 1.22 (at 1.26 Å from S9) − 2.98 (at 1.00 Å from M8) |
Site | s.o.f. | x | y | z | Ueq |
---|---|---|---|---|---|
M1 | Sb0.69(1)Mn0.31(1) | 0.13588 (7) | 0.33007 (10) | 0.12257 (19) | 0.0516 (6) |
M2 | As0.96(1)Sb0.04(1) | 0.06326 (7) | 0.62044 (9) | 0.1240 (2) | 0.0285 (4) |
M3 | Pb0.91(1)Sb0.09(1) | 0.24633 (3) | 0.58190 (5) | 0.38468 (9) | 0.0473 (2) |
M4 | Ag0.80(1)Cu0.20(1) | 0.35946 (6) | 0.32999 (10) | 0.1290 (2) | 0.0526 (6) |
M5 | Sb1.00 | 0.45771 (5) | 0.60464 (6) | 0.12818 (14) | 0.0335 (2) |
M6 | Sb1.00 | 0.11431 (5) | 0.33212 (7) | 0.61891 (14) | 0.0379 (3) |
M7 | Sb0.92(1)As0.08(1) | 0.05163 (5) | 0.63732 (8) | 0.64699 (15) | 0.0378 (4) |
M8 | Pb1.00 | 0.24437 (3) | 0.57781 (4) | 0.88178 (8) | 0.0376 (2) |
M9 | Mn0.55(1)Ag0.45(1) | 0.36399 (6) | 0.34426 (9) | 0.61981 (19) | 0.0206 (4) |
M10 | As1.00 | 0.43438 (6) | 0.59947 (9) | 0.6332 (2) | 0.0254 (3) |
S1 | S1.00 | 0.10164 (17) | 0.5080 (3) | 0.3380 (5) | 0.0387 (10) |
S2 | S1.00 | −0.00527 (16) | 0.2329 (2) | 0.1480 (5) | 0.0307 (8) |
S3 | S1.00 | 0.25202 (18) | 0.4302 (2) | 0.1411 (4) | 0.0360 (8) |
S4 | S1.00 | 0.16552 (16) | 0.7182 (2) | 0.1134 (5) | 0.0294 (8) |
S5 | S1.00 | 0.3869 (2) | 0.4998 (3) | 0.4219 (6) | 0.0470 (12) |
S6 | S1.00 | 0.3468 (15) | 0.7112 (2) | 0.1078 (6) | 0.0302 (9) |
S7 | S1.00 | 0.09078 (17) | 0.5105 (3) | 0.8998 (6) | 0.0446 (12) |
S8 | S1.00 | 0.48785 (19) | 0.2893 (3) | 0.0896 (4) | 0.0410 (10) |
S9 | S1.00 | 0.23509 (15) | 0.4183 (2) | 0.6086 (5) | 0.0327 (9) |
S10 | S1.00 | 0.16473 (15) | 0.7199 (2) | 0.6453 (6) | 0.0325 (9) |
S11 | S1.00 | 0.39479 (17) | 0.4896 (2) | 0.8338 (5) | 0.0397 (11) |
S12 | S1.00 | 0.34339 (15) | 0.7228 (2) | 0.6462 (5) | 0.0283 (8) |
M1 | −S3 | 2.575 (4) | M2 | −S4 | 2.327 (3) | M3 | −S3 | 2.781 (4) | M4 | −S3 | 2.429 (3) | M5 | −S8 | 2.476 (4) |
−S12 | 2.624 (4) | −S7 | 2.372 (4) | −S9 | 2.789 (4) | −S8 | 2.540 (4) | −S6 | 2.531 (3) | |||||
−S6 | 2.698 (4) | −S1 | 2.376 (4) | −S5 | 2.907 (4) | −S4 | 2.594 (4) | −S2 | 2.615 (3) | |||||
−S1 | 2.952 (4) | −S2 | 3.108 (4) | −S1 | 2.953 (3) | −S10 | 2.686 (4) | −S11 | 3.061 (4) | |||||
−S2 | 2.985 (3) | −S8 | 3.337 (4) | −S10 | 3.187 (4) | −S11 | 3.236 (4) | −S5 | 3.076 (4) | |||||
−S7 | 3.056 (4) | −S7 | 3.400 (3) | −S4 | 3.208 (4) | −S5 | 3.271 (4) | −S11 | 3.088 (3) | |||||
−S12 | 3.350 (3) | |||||||||||||
−S6 | 3.411 (4) | |||||||||||||
M6 | −S12 | 2.505 (4) | M7 | −S10 | 2.412 (3) | M8 | −S3 | 2.840 (3) | M9 | −S4 | 2.556 (4) | M10 | −S11 | 2.293 (4) |
−S6 | 2.531 (4) | −S2 | 2.525 (4) | −S4 | 3.023 (4) | −S10 | 2.557 (4) | −S5 | 2.326 (4) | |||||
−S9 | 2.568 (3) | −S7 | 2.727 (5) | −S9 | 3.028 (4) | −S5 | 2.603 (4) | −S12 | 2.354 (3) | |||||
−S8 | 2.887 (4) | −S8 | 2.840 (4) | −S10 | 3.053 (4) | −S11 | 2.616 (4) | −S8 | 3.054 (4) | |||||
−S1 | 3.222 (4) | −S1 | 3.175 (5) | −S7 | 3.074 (4) | −S9 | 2.648 (3) | −S2 | 3.178 (4) | |||||
−S7 | 3.271 (5) | −S1 | 3.480 (4) | −S11 | 3.125 (4) | −S2 | 2.703 (3) | −S5 | 3.687 (4) | |||||
−S6 | 3.181 (4) | |||||||||||||
−S12 | 3.288 (4) |
Site | M1 | M2 | M3 | M4 | M5 | M6 | M7 | M8 | M9 | M10 | Σanion |
---|---|---|---|---|---|---|---|---|---|---|---|
S1 | 0.22 | 0.75 | 0.33 | 0.12 | 0.14 0.06 | 1.62 | |||||
S2 | 0.20 | 0.10 | 0.64 | 0.79 | 0.24 | 0.08 | 2.05 | ||||
S3 | 0.61 | 0.52 | 0.42 | 0.46 | 2.01 | ||||||
S4 | 0.86 | 0.17 | 0.27 | 0.28 | 0.36 | 1.94 | |||||
S5 | 0.37 | 0.04 | 0.18 | 0.32 | 0.84 0.02 | 1.77 | |||||
S6 | 0.43 | 0.10 | 0.80 | 0.80 | 0.18 | 2.31 | |||||
S7 | 0.16 | 0.76 0.05 | 0.11 | 0.46 | 0.24 | 1.78 | |||||
S8 | 0.06 | 0.31 | 0.93 | 0.31 | 0.34 | 0.12 | 2.07 | ||||
S9 | 0.51 | 0.73 | 0.27 | 0.28 | 1.79 | ||||||
S10 | 0.17 | 0.21 | 1.07 | 0.26 | 0.36 | 2.07 | |||||
S11 | 0.05 | 0.19 0.18 | 0.21 | 0.31 | 0.92 | 1.86 | |||||
S12 | 0.53 | 0.11 | 0.86 | 0.14 | 0.78 | 2.42 | |||||
Σcation | 2.15 | 2.58 | 2.17 | 1.30 | 2.92 | 2.93 | 2.86 | 2.04 | 1.87 | 2.64 | |
Theor. | 2.69 | 3.00 | 2.09 | 1.00 | 3.00 | 3.00 | 3.00 | 2.00 | 1.55 | 3.00 |
Iobs | dobs | Icalc | dcalc | h | k | l |
---|---|---|---|---|---|---|
- | - | 13 | 9.5900 | 2 | 0 | 0 |
15 | 6.05 | 21 | 6.0605 | 1 | 2 | 0 |
10 | 5.32 | 14 | 5.3164 | 2 | 2 | 0 |
- | - | 12 | 3.8947 | 0 | 1 | 2 |
25 | 3.83 | 25 | 3.8348 | 4 | 2 | 0 |
20 | 3.62 | 21 | 3.6183 | −2 | 1 | 2 |
- | - | 16 | 3.5986 | 2 | 1 | 2 |
40 | 3.34 | 40 | 3.3377 | −3 | 1 | 2 |
- | - | 42 | 3.3146 | 3 | 1 | 2 |
100 | 3.29 | 100 | 3.2886 | 5 | 2 | 0 |
- | - | 12 | 3.1967 | 6 | 0 | 0 |
10 | 3.20 | 14 | 3.1939 | 0 | 4 | 0 |
30 | 3.15 | 30 | 3.1505 | 1 | 4 | 0 |
40 | 2.920 | 25 | 2.9179 | −1 | 3 | 2 |
- | - | 28 | 2.9127 | 1 | 3 | 2 |
30 | 2.860 | 30 | 2.8587 | 6 | 2 | 0 |
70 | 2.821 | 55 | 2.8240 | −2 | 3 | 2 |
- | - | 54 | 2.8146 | 2 | 3 | 2 |
35 | 2.678 | 20 | 2.6843 | −3 | 3 | 2 |
- | - | 24 | 2.6723 | 3 | 3 | 2 |
20 | 2.241 | 11 | 2.2493 | −7 | 1 | 2 |
- | - | 12 | 2.2328 | 7 | 1 | 2 |
- | - | 20 | 2.0488 | −8 | 1 | 2 |
50 | 2.045 | 35 | 2.0447 | 0 | 0 | 4 |
- | - | 20 | 2.0346 | 8 | 1 | 2 |
20 | 1.980 | 16 | 1.9779 | −4 | 5 | 2 |
10 | 1.971 | 14 | 1.9714 | 4 | 5 | 2 |
25 | 1.945 | 25 | 1.9460 | 4 | 6 | 0 |
10 | 1.919 | 9 | 1.9180 | 10 | 0 | 0 |
5 | 1.863 | 9 | 1.8659 | −8 | 3 | 2 |
- | - | 9 | 1.8551 | 8 | 3 | 2 |
15 | 1.740 | 14 | 1.7419 | −5 | 2 | 4 |
- | - | 14 | 1.7309 | 5 | 2 | 4 |
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Bindi, L.; Biagioni, C.; Keutsch, F.N. Oyonite, Ag3Mn2Pb4Sb7As4S24, a New Member of the Lillianite Homologous Series from the Uchucchacua Base-Metal Deposit, Oyon District, Peru. Minerals 2018, 8, 192. https://doi.org/10.3390/min8050192
Bindi L, Biagioni C, Keutsch FN. Oyonite, Ag3Mn2Pb4Sb7As4S24, a New Member of the Lillianite Homologous Series from the Uchucchacua Base-Metal Deposit, Oyon District, Peru. Minerals. 2018; 8(5):192. https://doi.org/10.3390/min8050192
Chicago/Turabian StyleBindi, Luca, Cristian Biagioni, and Frank N. Keutsch. 2018. "Oyonite, Ag3Mn2Pb4Sb7As4S24, a New Member of the Lillianite Homologous Series from the Uchucchacua Base-Metal Deposit, Oyon District, Peru" Minerals 8, no. 5: 192. https://doi.org/10.3390/min8050192