Preparation and Properties of Biobased, Cationic, Waterborne Polyurethanes Dispersions from Castor Oil and Poly (Caprolactone) Diol
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemicals
2.2. Synthesis of WPU
2.3. Characterization
3. Results and Discussion
3.1. Mechanical Performance of WPUs
3.2. T-Peel Strength Tests
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Samples | PCL-OH (Molar) | CO (Molar) | MDEA (wt%) | Hard Segment (wt%) | CO (wt%) | T-Peel Strength (N/25 mm) | Zeta Poterntial (mV) |
---|---|---|---|---|---|---|---|
CO0%–WPU | 1 | 0 | 3.8 | 37.5 | 0 | 17.2 | 39 |
CO2.50%–WPU | 1 | 0.095 | 3.3 | 38.9 | 2.5 | 23.4 | 45 |
CO5.04%–WPU | 1 | 0.190 | 3.2 | 40.3 | 5.0 | 29.5 | 50 |
CO7.40%–WPU | 1 | 0.285 | 3.2 | 41.6 | 7.4 | 36.8 | 54 |
CO9.66%–WPU | 1 | 0.380 | 3.1 | 42.8 | 9.7 | 26.8 | 55 |
Sample | CO0%–WPU | CO2.50%–WPU | CO5.04%–WPU | CO7.40%–WPU | CO9.66%–WPU |
---|---|---|---|---|---|
Tm (°C) | 48.8 | 48.2 | 47.5 | 46.8 | 45.2 |
ΔH (J/g) | 47.7 | 44.6 | 42.2 | 39.1 | 38.0 |
CO0%–WPU | CO2.50%–WPU | CO5.04%–WPU | CO7.40%–WPU | CO9.66%–WPU | |
---|---|---|---|---|---|
σm(MPa) | 24.1 | 18.7 | 17.8 | 17.0 | 15.3 |
εb (%) | 5.0 | 110 | 189 | 241. | 391 |
σb (MPa) | - | 10.8 | 11.5 | 11.3 | 12.0 |
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Li, Y.; Chen, S.; Shen, J.; Zhang, S.; Liu, M.; Lv, R.; Xu, W. Preparation and Properties of Biobased, Cationic, Waterborne Polyurethanes Dispersions from Castor Oil and Poly (Caprolactone) Diol. Appl. Sci. 2021, 11, 4784. https://doi.org/10.3390/app11114784
Li Y, Chen S, Shen J, Zhang S, Liu M, Lv R, Xu W. Preparation and Properties of Biobased, Cationic, Waterborne Polyurethanes Dispersions from Castor Oil and Poly (Caprolactone) Diol. Applied Sciences. 2021; 11(11):4784. https://doi.org/10.3390/app11114784
Chicago/Turabian StyleLi, Ying, Sichong Chen, Jun Shen, Siqi Zhang, Ming Liu, Ruixue Lv, and Wang Xu. 2021. "Preparation and Properties of Biobased, Cationic, Waterborne Polyurethanes Dispersions from Castor Oil and Poly (Caprolactone) Diol" Applied Sciences 11, no. 11: 4784. https://doi.org/10.3390/app11114784