Photoelectrochemical Hydrogen Production System Using Li-Conductive Ceramic Membrane
Abstract
:1. Introduction
2. Experimental Section
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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R3c Phase | P4/mmm | |
---|---|---|
Unit cell parameters | ||
a, A | 5.4836(4) | 5.4720(3) |
c, A | 13.44(1) | 7.7735(6) |
V, A3 | 349.9(3) | 232.76(3) |
Coordinates of ions * | ||
Ti z/c | 0 | 0.251(4) |
O1 x/a | 0.53(3) | ½ |
O3/O4 z/c | - | 0.21(2) |
Reliability factor | ||
X2 | 9.53 | 9.53 |
RB, % | 6.74 | 13.5 |
Rf, % | 8.86 | 10.5 |
Rexp,% | 9.17 | 9.17 |
Membrane Thickness 0.70 mm | Membrane Thickness 1.35 mm | ||
---|---|---|---|
electrolyte 30% KOH + 2 M LiOH | |||
R1 (Ohm) | 82.32 | R1 (Ohm) | 164.2 |
CPE1 | 3.895 × 10−7 | CPE1 | 2.579 × 10−7 |
R2 (Ohm) | 5069 | R2 (Ohm) | 9911 |
CPE2 | 1.038 × 10−4 | CPE2 | 0.8163 × 10−4 |
R3 (Ohm) | 1.3573 × 105 | R3 (Ohm) | 2.0037 × 105 |
electrolyte 30% H2SO4 + 1 M Li2SO4 | |||
R1 (Ohm) | 82.09 | R1 (Ohm) | 157.3 |
CPE1 | 4.3954 × 10−7 | CPE1 | 2.3086 × 10−7 |
R2 (Ohm) | 4985 | R2 (Ohm) | 9588 |
CPE2 | 4.2605 × 10−5 | CPE2 | 3.3769 × 10−5 |
R3 (Ohm) | 3.7751 × 105 | R3 (Ohm) | 2.0456 × 105 |
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Rusetskyi, I.A.; Kovalenko, L.L.; Danilov, M.O.; Slobodyanyuk, I.A.; Fomanyuk, S.S.; Smilyk, V.O.; Belous, A.G.; Kolbasov, G.Y. Photoelectrochemical Hydrogen Production System Using Li-Conductive Ceramic Membrane. Membranes 2022, 12, 1189. https://doi.org/10.3390/membranes12121189
Rusetskyi IA, Kovalenko LL, Danilov MO, Slobodyanyuk IA, Fomanyuk SS, Smilyk VO, Belous AG, Kolbasov GY. Photoelectrochemical Hydrogen Production System Using Li-Conductive Ceramic Membrane. Membranes. 2022; 12(12):1189. https://doi.org/10.3390/membranes12121189
Chicago/Turabian StyleRusetskyi, Ihor A., Leonid L. Kovalenko, Michail O. Danilov, Ivan A. Slobodyanyuk, Sergii S. Fomanyuk, Vitaliy O. Smilyk, Anatolii G. Belous, and Gennadii Ya. Kolbasov. 2022. "Photoelectrochemical Hydrogen Production System Using Li-Conductive Ceramic Membrane" Membranes 12, no. 12: 1189. https://doi.org/10.3390/membranes12121189