2. Simplified Model
Before we get started with the ratchet surface condition, we start with a self-levitated condition with an average clearance to the flat rigid surface
. The levitated liquid droplet is also simplified as a symmetric button shape with a circular bottom cross-section with a radius
R. To establish the needed critical Leidenfrost temperature
, we assume the mass flow rate through the entire circular cross section due to evaporation
as
, where
stands for the average vapor velocity discharged from the bottom surface of the droplet. Naturally, during evaporation, under the atmospheric pressure, the droplet temperature remains as the saturated temperature
. Therefore, the thermal condition introduces a heat flux
, where
k stands for the thermal conductivity of the vapor. Notice that the physical intuition based on the bulk air (vapor) flow direction suggests that the convection effect is not as significant as the conduction effect, which is validated with the simplified model in Equations (
5) and (
6). Based on the mass conservation and the energy conservation, we have the following important governing equation
where
stands for a coefficient as a measure of the contribution of the heat flux due to conduction to the evaporation of the saturated liquid surface of the droplet,
represents the saturated gas (vapor in this case) density, and
stands for the latent heat at the atmospheric pressure.
Note that Equation (
1) is indeed identical to Equation (
5) in Ref. [
24] with a slight adjustment of the geometrical parameter. Furthermore, based on the levitation condition, the self-weight of the button-shape liquid must be balanced by the change in the linear momentum in the gravitational direction, namely,
where
refers to the discharging velocity of the vapor,
stands for a coefficient as a measure of the weight proportion carried by the vertical change in the linear momentum,
g is the gravitational constant,
H represents the average height of the button-shape droplet, and
is the saturated liquid density at the atmospheric pressure.
Combining Equations (
1) and (
2), we can easily establish the following critical temperature condition
for Leidenfrost effects
Using the steam table, at the atmospheric pressure, we have the saturated temperature
,
,
, and
. At the atmospheric pressure, we typically have the thermal conductivity of the vapor
. Therefore, we have the following parametric relationship to compare with the existing literature and experimental evidence
where
is the clearance in micrometer (μm) and
H is the droplet height in millimeter (mm).
According to the literature [
25], the radius of the droplet with a 5-microliter (μL) volume is around 1 mm. Therefore, we can easily assume
H to be around 1 mm. Theoretically speaking, if the coefficients
and
are around the order 1, the levitation clearance
should be around 1 μm to match the empirical evidence of the Leidenfrost temperature around 300 °C [
25]. Notice that the proper justification of these two coefficients
and
can only be derived from a two-dimensional and three-dimensional modeling in which the geometrical effects can be fully explored. In this paper, to further the discussion, we limit our study to the ratchet surface as illustrated in
Figure 1, in which the horizontal and incline periods of the ratchet are denoted as
p and
l, respectively, whereas the vertical and normal clearances are denoted as
d and
h, respectively. In this study, we assume that
and
are much less than 1. Assume the droplet spans over
N periods of the ratchet teeth; we have
, where
R is the radius of the curvature of the droplet bottom. In fact, according to Ref. [
25], the capillary length
a, depicted as
, where
is the liquid droplet’s surface tension and
is the liquid density, defines the geometry of the droplet with the expression
, where
denotes the lowering of the center of mass. This length scale is confirmed for a spherical droplet. The total surface tension lifting the weight of the droplet around the equator of the droplet is
, and the total weight is approximated by
. Substituting the surface tension
as
and using
, we can easily have
or
. For example, for the temperature inside the water droplet to be around the saturation temperature of the water at the atmospheric pressure, namely, 100 °C, the droplet liquid density
is around
and the surface tension
is around
. Therefore, the capillary length
a is calculated to be 2.5 mm. Moreover, the lowering of the center of mass
can be denoted as
, where
h is the current thickness of the oval-shape liquid droplet. If the radium of the droplet
R is set to be 10 mm, we have the lowering of the center of mass
estimated to be
, namely, 2.492 mm. Therefore, according to Ref. [
25], the geometric Hertz relation
calculated with
is approximated as 2.496 mm, almost identical to the value estimated with
, which is 2.496 mm.
Naturally, the radius of the curvature of the droplet depends very much on the surface tension and the pressure difference. We also denote the temperatures at the ratchet surface and the droplet surface as and , respectively. In an atmospheric environment on Earth’s surface, the phase transition temperature for pure water is around 100 °C or 373 K. In this work, the ratchet temperature is around 550 K.
From the derivation of Equation (
3) and the empirical evidence of the threshold temperature for Leidenfrost effects, it is feasible for us to utilize a simplified model with the vapor film thickness
no more than 20 μm, much smaller than the normal clearance
h for this very complex phenomenon [
25], which is essential for the levitation. It is safe to adopt a vapor film thickness or clearance
between 10 μm and 30 μm for the hot surface temperature in the range from 200 to 400 °C.
Assuming the normal clearance
h is 150 μm, the vapor film thickness normal to the ratchet surface
is approximated as 10 μm, whereas the droplet radius is around 1.06 mm. Furthermore, based on Ref. [
26], we have the thermal conductivity
k as 33 mW/Km for the film of saturated water vapor. Thus, the rate of heat transfer per unit area or heat flux due to thermal conduction within the vapor film between the droplet and the ratchet surface is calculated as follows:
Similarly, based on Ref. [
27], we have the convective heat transfer coefficient
as 30 W/Km
2 for the same film of saturated water vapor. Consequently, the heat flux due to thermal convection within the vapor film is calculated as follows:
We should note that the convective heat transfer coefficient
depends very much on the air velocity. For the droplet traveling velocity ranges measured in the study of the Leidenfrost effect, the adopted convective heat transfer coefficient is reasonably representative. The Stefan Boltzmann constant for thermal radiation
is
. Assuming the emissivity for radiation
is
, we can calculate the heat flux due to thermal radiation as follows:
Based on the second law of thermodynamics, the direction of the heat transfer in all three means is from the hot ratchet surface to the relatively cold droplet with the saturated temperature at the atmospheric pressure. In fact, the thermal energy required for the phase transition at the surface of the droplet is supplied through the conduction, convection, and radiation heat transfer within the vapor film between the droplet and the ratchet surface as illustrated in Equations (
5)–(
7). Moreover, it is also clear that the main source of thermal energy is from conduction rather than convection and radiation. Therefore, in the simplified model presented in this paper, we focus exclusively on the thermal conduction within the vapor film.
The lateral dimension of the droplet is of the order of the radius, which is much larger than the typical section or period of the ratchet. Hence, instead of handling a full-fledged three-dimensional droplet hovering on top of many periods of the ratchets, we employ a much simplified two-dimensional generic model to evaluate the propulsion force due to evaporation within each period of the ratchets. This two-dimensional vapor domain is also used to estimate the viscous drag due to the shear of the vapor film. Assuming the droplet travels at a velocity
V, the average normal gradient of the vapor film can be estimated as follows:
where the dynamic viscosity of the vapor film
is roughly
with one
defined as one dyne per square centimeter multiplied by a second which equals
.
Of course, this simple estimate was confirmed by a computational fluid dynamics (CFD) calculation of the vapor film between the moving droplet and the stationary ratchet surface. As depicted in
Figure 1, the incline of the ratchet surface is defined by an angle
with
, which corresponds to the incline angle
equaling
. For the vapor film, the specific heat
is averaged as 1.9 kJ/kgK for the temperature range between 373 K and 550 K [
28]. Furthermore, during this temperature range, the saturation pressure for water vapor is from 0.1 MPa to 6.0 MPa. Since the atmospheric pressure is constant, the relative humidity within the vapor film can change from 100% to merely 1.7%. This relative humidity is a good indication of the composition of the air within the vapor film, which directly influences the dynamic viscosity and density. In the CFD computation, we employed an average viscosity with a half air and half vapor mixture at the ambient pressure of 0.1 MPa, namely, the density
was 1.06 kg/m
3 and the dynamic viscosity
was
. It is important to note that the density of moist air is smaller than the density of the corresponding dry air. Moreover, in the full-fledged CFD modeling, the so-called Boussinesq approximation was applied, and the thermal expansion coefficient was adopted at an average temperature of 250 °C as
In
Figure 2, a two-dimensional computational model is represented. The top surface is moving at a fixed velocity, and the ratchet surface is assumed to be fixed, namely, a wall boundary condition. Moreover, we also adopted a linear velocity profile as the inlet and outlet velocity conditions for a narrow gap between the moving droplet surface and the tip of the ratchets from the moving droplet surface. Similarly, the temperature distribution within the inlet and outlet gap was also linear with the endpoints matching the temperature on the droplet and ratchet surfaces. The illustration of the boundary conditions for fluid dynamics and heat transfer is documented in
Figure 2.
The temperature distribution within the vapor film is captured in
Figure 3. It is noted that inside the cavity with the aspect ratio of interest to us, the temperature gradient was normal to the top surface, which is confirmed by the vector fields and magnitude distribution of the heat flux in
Figure 4 and
Figure 5. Furthermore, the temperature gradient was among the highest within the vapor film or cavity.
Furthermore, it is evident from
Figure 6 and
Figure 7 that the velocity within the cavity was a shear-driven Couette flow. In fact, within the period, as shown in
Figure 8 and
Figure 9, the normalized maximum shear stress
at the moving droplet’s surface merely changed from
to
as depicted in
Figure 8, with an average over the period of
, which was significantly larger than the one-dimensional estimate as follows:
In this paper, we adopted the average value
as the normalized shear stress on the lower surface of the droplet. Likewise, we also compared the simulation results to the simplified thermal conduction calculation. In the vertical heat transfer band plot, it is easy to identify that the normal heat transfer ranged from 49.155 to 584.100 kW/m
2, as depicted in
Figure 10, with an average over the period of 121.903 kW/m
2, which was on the same magnitude but slightly larger than the high estimate of the one-dimensional simplified model as follows:
Now, we are ready to handle the linear momentum conservation and the motion of the droplet. Notice that in the simplified models, we first had to use the one-dimensional model to identify the order of magnitude for the thermal conduction, convection, and radiation. However, it was more accurate for us to use the heat flux and the shear stress derived from a more sophisticated two-dimensional model.
The key physics for the propulsion of the droplet is the evaporation-induced loss of linear momentum in the horizontal direction. The governing equation for the droplet can then be expressed as
where
V stands for the droplet’s traveling velocity in the horizontal direction,
is the propulsion force due to evaporation, and the air resistance to the motion of the droplet is quantified as three portions, namely, the form drag due to the shape of the droplet
, the skin friction due to the upper surface of the exposed droplet surface
, and the viscous shear within the vapor film between the lower surface of the droplet and the ratchet surface
.
As illustrated in
Figure 10, the contributions of the pressure within the vapor film were not as significant as those of the shear stress and the discharge of vapor from the droplet. Needless to say, we assumed that the droplet was afloat and there was no vertical motion in comparison with the horizontal motion. With the help of the two-dimensional fluid dynamics simulation of the vapor film, we have the heat flux and the viscous shear at the lower surface of the droplet as
and
, respectively. More specifically, we have the following averaged values
the shear force
can be simply expressed as
with
as the lower surface area of the droplet, whereas the rate of evaporation is measured by the rate of the water vapor mass
, which is calculated as
with
as the latent heat for water evaporation, as well as the discharge vapor velocity
, which is calculated as
with
as the density of water vapor at the saturation temperature at the atmospheric pressure.
According to Ref. [
28], at one atmospheric pressure,
equals 2257 kJ/kg and
equals 0.5903 kg/m
3. Thus, adopting the results from our two-dimensional CFD modeling summarized in Equation (
12), we can estimate the rate of the discharging vapor as
Moreover, using the domain near the ratchet, the discharge vapor velocity can also be estimated as
Therefore, the propulsion due to the discharge of water vapor projected to the horizontal direction can be evaluated as
where the width of the droplet is denoted as
w, and
is the angle of the incline. Ignoring the form drag and the skin drag of the droplet, the terminal velocity of the droplet balancing only the shear stress of the vapor film cavity can be simply calculated as
which yields a simple estimate for the terminal velocity based on both analytical and computational approaches.
This simplified model based on both analytical and computational methods yields a promising result close to the experimental observation. However, more accurate models based on physics can also be proposed. Firstly, as indicated in
Figure 4 and
Figure 5, the heat flux around the corner is the highest. Adopting the slope defined by the incline angle
, the heat flux around the corner area defined within a radius of 400 μm, we have the average heat flux as 128.8 kW/m
2, which is almost two times the value in Equation (
12). While the shear stress and pressure distribution with the consideration of the slope around the corner remain roughly the same.
Consequently, Equations (
13) and (
14) are modified as
Moreover, the discharge vapor velocity can be estimated as
Again, if we ignore the form drag and the skin drag of the droplet, the terminal velocity of the droplet balancing only the shear stress of the vapor film cavity can be simply calculated as
which yields a much closer simple estimate for the terminal velocity based on both analytical and computational approaches.
Finally, we must reiterate here that the effects of convection and radiation as depicted in Equations (
6) and (
7) constitute only a very small portion of the heat transfer. The droplet velocity
V is not altered significantly.
In aerodynamics, the form drag and skin friction are quantified by the nondimensional form drag coefficient and the skin friction drag coefficient as well as the dynamic pressure . Note that the vapor density is abbreviated as
Assume that for the duration of observation, the mass loss is insignificant and as a result the radius of the droplet
R remains unchanged. Therefore, the final governing dynamic equation for the translational motion of the droplet can be expressed as
where
,
, and
represent the upper-side surface area, the lower-side surface area, and the middle-section cross-section area of the droplet, respectively, and
is the form drag
,
is the friction drag
at the upper surface of the droplet, and
is the viscous shear force
within the vapor film, or the lower droplet surface as depicted in Equation (
11).
In this paper, because the lateral shape of the droplet with an approximate volume of 5 microliter is supposed to be close to a spherical shape instead of a pancake shape [
25], we approximated
,
, and
as
,
, and
, respectively. Consequently, we can estimate the terminal velocity using the right-hand side of Equation (
20)
Notice that the shear stress acting on the droplet as well as the thrust due to evaporation introduces a torque on the droplet. As result, the droplet tends to rotate or tumble as it moves along the horizontal axis. This rotational motion as reported in Refs. [
29,
30] along with flow instabilities as discussed in Ref. [
31] will be studied in a subsequent paper.