Hydrogenation Thermodynamics of Ti16V60Cr24−xFex Alloys (x = 0, 4, 8, 12, 16, 20, 24)
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Microstructure, Crystal Structure and First Hydrogenation
3.2. Pressure Composition Isotherms (PCIs)
3.3. Enthalpy and Entropy
3.4. Enthalpy–Entropy Compensation
- Step 1
- Step 2
- Step 3
- Step 4
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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x | Maximum Hydrogen Capacity (wt.%) | Crystal Structure | |
---|---|---|---|
As-Cast | After Hydrogenation | ||
0 | 3.78 | BCC (100%) | BCT (100%) |
4 | 3.09 | BCC (100%) | BCT (80%) + C14 (20%) |
8 | 2.08 | BCC (100%) | BCT (78%) + C14 (22%) |
12 | 1.89 | BCC (79%) + C14 (21%) | BCT (76%) + C14 (24%) |
16 | 2.06 | BCC (77%) + C14 (23%) | BCT (58%) + C14 (24%) + C15 (18%) |
20 | 1.94 | BCC (74%) + C14 (26%) | BCT (64%) + C14 (23%) + C15 (13%) |
24 | 1.99 | BCC (72%) + C14 (28%) | BCT (53%) + C14 (37%) + C15 (11%) |
x | ΔS (J/K·mol H2) | ΔH (kJ/mol H2) |
---|---|---|
0 | −134 ± 14 | −41 ± 5 |
4 | −150 ± 12 | −44 ± 4 |
8 | −126 ± 12 | −39 ± 4 |
12 | −114 ± 6 | −36 ± 2 |
16 | −98 ± 5 | −33 ± 2 |
20 | −84 ± 12 | −30 ± 4 |
24 | −57 ± 5 | −21 ± 2 |
Thm (K) | Tcomp (K) | R2 | Tmin (K) (from Equation (2)) | Tmin (K) (from Figure 5) | T* (K) |
---|---|---|---|---|---|
309 | 254 | 0.982 | 258 | 242 | 323 |
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Ravalison, F.; Huot, J. Hydrogenation Thermodynamics of Ti16V60Cr24−xFex Alloys (x = 0, 4, 8, 12, 16, 20, 24). Hydrogen 2024, 5, 29-38. https://doi.org/10.3390/hydrogen5010003
Ravalison F, Huot J. Hydrogenation Thermodynamics of Ti16V60Cr24−xFex Alloys (x = 0, 4, 8, 12, 16, 20, 24). Hydrogen. 2024; 5(1):29-38. https://doi.org/10.3390/hydrogen5010003
Chicago/Turabian StyleRavalison, Francia, and Jacques Huot. 2024. "Hydrogenation Thermodynamics of Ti16V60Cr24−xFex Alloys (x = 0, 4, 8, 12, 16, 20, 24)" Hydrogen 5, no. 1: 29-38. https://doi.org/10.3390/hydrogen5010003