Polylactic Acid Composites Reinforced with Eggshell/CaCO3 Filler Particles: A Review
Abstract
:1. Introduction
2. Biopolymers
Polylactic Acid (PLA)
3. Polylactic Acid (PLA) Composites
4. Fillers
4.1. Natural
4.2. Synthetic
5. Calcium Carbonate (CaCO3)
5.1. Mineral Calcium Carbonate
5.2. Biogenic Sources of Calcium Carbonate
6. Chicken Eggshells
6.1. Global Egg Production
Eggshell Applications
- (1)
- Food additive for human nutrition
- (2)
- Food additive for animal nutrition
- (3)
- Soil amendment
- (4)
- Purified calcium carbonate
- (5)
- Cosmetics
- (6)
- Catalyst and sorbent
- (7)
- Polymer composites
7. Polylactic Acid Composites Reinforced with Eggshell/Calcium Carbonate Particles
The Effect of Chemical Modification (Coating) of Eggshell/Calcium Carbonate Particles to Prevent Agglomeration in PLA Composites
8. Sustainability of PLA Composites
9. Conclusions and Future Perspective
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Property | Normal Range |
---|---|
Specific gravity | 2.7 |
Average particle size (µm) | 0.5–10.0 |
Specific surface area (m2/g) | >1–10 |
Powder density (kg/m3) | 800–1700 |
Countries | Number of Egg Production in Billions | |
---|---|---|
Year 2019 | Year 2021 | |
Peoples Republic of China (PRC) | 636.82 | 586.31 |
United States of America (USA) | 147.85 | 110.73 |
India | 127.31 | 122.00 |
Indonesia | 104.79 | 114.58 |
Brazil | 69.62 | 58.20 |
Mexico | 65.03 | 57.49 |
Japan | 58.19 | 42.90 |
Russia | 54.92 | 44.58 |
Turkey | 27.41 | 19.30 |
Pakistan | 19.05 | 21.28 |
Type of Coating (Fatty Acid) | Eggshell Filler Loading (%) | Tensile Strength (MPa) | Tensile Elastic Modulus (MPa) | Elongation at Break (%) | Impact Strength (kJ/m2) |
---|---|---|---|---|---|
Non-modified | 15 phr | 37.5 | 1310.0 | 3.8 | 2.1 |
Oleic acid | 15 phr | 39.0 | 970.0 | 16.0 | 6.8 |
Propionic acid | 15 phr | 41.0 | 1202.0 | 9.3 | 2.8 |
- | 0 (pure PLA) | 54.2 | 1080.0 | 11.3 | 3.8 |
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Homavand, A.; Cree, D.E.; Wilson, L.D. Polylactic Acid Composites Reinforced with Eggshell/CaCO3 Filler Particles: A Review. Waste 2024, 2, 169-185. https://doi.org/10.3390/waste2020010
Homavand A, Cree DE, Wilson LD. Polylactic Acid Composites Reinforced with Eggshell/CaCO3 Filler Particles: A Review. Waste. 2024; 2(2):169-185. https://doi.org/10.3390/waste2020010
Chicago/Turabian StyleHomavand, Anahita, Duncan E. Cree, and Lee D. Wilson. 2024. "Polylactic Acid Composites Reinforced with Eggshell/CaCO3 Filler Particles: A Review" Waste 2, no. 2: 169-185. https://doi.org/10.3390/waste2020010