Editor’s Choice Articles

A facile strategy to boost anticorrosion potency of graphene oxide/silica hybrid sol-gel coating is developed through fully exploiting the capabilities of graphene oxide (GO). Together with a barrier to corrosives and crack inhibitor, GO was further explored herein as a regulator to regulate the gelation process and provide robust coating films with stratified microstructures and ultimately extended diffusion paths. The sol-gel coating with stratified microstructure achieved on AA5052 aluminum alloy surface afforded greatly enhanced corrosion protection capability as assessed by electrochemical measurements and immersion tests. The corrosion current density of the sample of a hybrid GO sol-gel film was about 30 times less than that of sample of pure sol-gel film sample. The regulation mechanism of GO during the film formation process and the anticorrosive protection properties of the film were discussed. Full article

Laser cutting is used in the production of formed sheet metal components. However, the cyclic load capacity is reduced compared to other subtractive processes. Laser cutting results in a significant loss of fatigue strength; however, thermal joining has its own effect on the cyclic load capacity. Accordingly, brazing causes a significant reduction in the mechanical strength. However, the open question is what consequences a combination of both processes may have on the overall fatigue strength of sheet metals. Laser-cut samples of AISI 304 with and without a brazed-on element were investigated for their microstructure and mechanical properties. The brazing process was found to have an annealing effect on the microstructure. It was further observed that the fatigue behavior of brazed specimens is dominated by inhomogeneities at the surface of the filler metal fillet located in the geometric notch of the brazed joint. Fatigue strength decreased by almost 50% compared to as-cut specimens. As long as no shared diffusion zone is formed between the laser-cut and the brazed joint, the use of laser cutting for the production of such components appears to be reasonable and does not further contribute to the loss of cyclic strength. Full article

The effect of multi-step austempering treatments on the microstructure and mechanical properties of a novel medium carbon high silicon carbide-free bainitic steel was studied. Five different isothermal treatment processes were selected, including single-step isothermal treatments above martensite start temperature (at 350 °C and 370 °C, respectively), and three kinds of two-step routes (370 °C + 300 °C, 370 °C + 250 °C, and 350 °C + 250 °C). In comparison with single-step austempering treatment adopting a two-step process, a microstructure with a bimodal-size distribution of bainitic ferrite and without martensite was obtained. Bainitic transformation was studied using dilatometry both for single-step and two-step routes and the specimens were completely characterised by electron microscopy (SEM and TEM), X-ray diffraction (XRD) and standard tensile tests. The mechanical response of the samples subjected to two-step routes was superior to those treated at a single temperature. Full article

Distortion (1), residual stresses and hot cracks can facilitate significant decreases in quality characteristics of casting products. Their reduction by a suitable component design (2) and process control is therefore desirable. In the casting process, these characteristics are assumed as a result of the combination of solidification shrinkage paired with the local self-feeding and the geometric constraints imposed on the component by the mold. In gravity die casting (3) of aluminum (4) with thermally well conducting and rigid metal molds, the control of solidification through a localized adjustment of the heat balance (5) appears to be a suitable approach to minimize these effects. The development of an experimental setup for the assessment of the interdependencies of the alloy, casting geometry and cooling are described in this work. A first series of experiments with A356 aluminum alloy and the introduction to the different methods of evaluation are presented. Furthermore, an approach to improve the understanding of the underlying mechanisms is outlined. Full article

An effective strategy to produce grooves on carbon steel substrates by nanosecond laser radiation is proposed. The aim is to increase the productivity of grooves creation. In this study, two different modes of laser treatment are compared. The first mode focuses on the evaporation of material, while the second focuses on the formation of melted material and its removal by the action of pressure vapors produced by evaporated material. Within some ranges of processing parameters, the shape of the groove can be linearly controlled. The dependence of the groove depth also has a logarithmic nature when the number of passes is increased. Using the liquid phase mode in some ranges of parameters can reduce the amount of evaporated material in comparison with standard techniques in which the material is removed in the form of gas, and fine dust is emitted. Full article

Carbide precipitation in martensitic low alloyed steels contributes to the mechanical properties through precipitation hardening. A high number density of carbides is desired to maximize the hardening effect, which is achieved through the precipitation of carbides on the dislocations in the martensitic structure. In this study, the nucleation, growth, and coarsening of vanadium and molybdenum carbides during aging at 600 °C for periods up to four weeks were investigated. The work covers characterization with atom probe tomography, which showed that the nucleation of V and Mo rich MC/M₂C carbides takes place on dislocations. The growth of these carbides proceeds by the diffusion of elements to the dislocations, which has been modeled using Dictra software, confirming the rate of the reaction as well as the depletion of carbide formers in the matrix. For longer aging times, particle coarsening will decrease the number density of particles with a transition from dislocation-based carbides to separate rounded carbides. Full article

The cold spray process is governed by the impact of high velocity feedstock particles onto a substrate without melting. Hence, the bulk material properties are retained. However, it is challenging to achieve good adhesion strength. The adhesion strength depends on factors such as the cold spray process parameters, substrate conditions, coating/substrate interactions at the interface and feedstock material properties. This review examines fundamental studies concerning the adhesion mechanisms of cold spray technology and considers the effect of cold spray input parameters such as temperature, stand-off-distance, pressure, process gas, spray angle, and traverse speed of the cold spray torch on the bonding mechanism and adhesion strength. Furthermore, the effects of substrate conditions such as temperature, hardness, roughness and material on the adhesion mechanism are highlighted. The effect of feedstock properties, such as feed rate, shape and size are summarized. Understanding the effect of these parameters is necessary to obtain the optimal input parameters that enable the best interfacial properties for a range of coating/substrate material combinations. It is expected that feedstock of spherical morphology and small particle size (<15 μm) provides optimal interfacial properties when deposited onto a mirror-finished substrate surface using high pressure cold spray. Deep insights into each parameter exposes the uncovered potential of cold spray as an additive manufacturing method. Full article

New High Entropy Alloys based on the CoCrFe₂Ni₂ system have been developed by adding up to 10 at. % of Cu, Mo, and Cu + Mo in different amounts. These alloys showed a single face-centred cubic (FCC) structure after homogenization at 1200 °C. In order to evaluate their thermal stability, aging heat treatments at 500, 700, and 900 °C for 8 h were applied to study the possible precipitation phenomena. In the alloys where only Cu or Mo was added, we found the precipitation of an FCC Cu-rich phase or the µ phase rich in Mo, respectively, in agreement with some of the results previously shown in the literature. Nevertheless, we have observed that when both elements are present, Cu precipitation does not occur, and the formation of the Mo-rich phase is inhibited (or delayed). This is a surprising result as Cu and Mo have a positive enthalpy of mixing, being immiscible in a binary system, while added together they improve the stability of this system and maintain a single FCC crystal structure from medium to high temperatures Full article

Hot-stamped products are widely used for the body-in-white of an automobile as they are lightweight and improve crashworthiness. A hot-stamping process using planar compression was developed to strengthen corners of ultra-high strength parts by local thickening and hardening. In this process, the corners are thickened by compressing the blank in the planar direction with the upper and lower dies while blocking the movement of both edges with stoppers in the latter stage of forming. Thickening of the corners largely heightens the strength of the formed parts. Not only the thickness but also the hardness of the corner was increased by large plastic deformation and die quenching. For a hot hat-shaped part, a 30% increase in thickness and a 530 HV20 hardness around the corners were attained. The bending rigidity and strength of the formed parts thickened by 30% in the corners increased by 25% and 20%, respectively. In addition, the improvements of the part shape accuracy and the sidewall quenchability were obtained. Full article

The microstructure, phase formation, thermal stability and soft magnetic properties of melt-spun high entropy alloys (HEAs) Fe₂₇Co₂₇Ni₂₇Si_10−xB₉La_x with various La substitutions for Si (x = 0, 0.2, 0.4, 0.6, 0.8, and 1) were investigated in this work. The Fe₂₇Co₂₇Ni₂₇Si_10−xB₉La_0.6 alloy shows superior soft magnetic properties with low coercivity H_c of ~7.1 A/m and high saturation magnetization B_s of 1.07 T. The content of La has an important effect on the primary crystallization temperature (T_x1) and the secondary crystallization temperature (T_x2) of the alloys. After annealing at relatively low temperature, the saturation magnetization of the alloy increases and the microstructure with a small amount of body-centered cubic (BCC) phase embedded in amorphous matrix is observed. Increasing the annealing temperature reduces the magnetization due to the transformation of BCC phase into face-centered cubic (FCC) phase. Full article

The development of high-temperature heavy-duty turbine disk materials is critical for improving the overall efficiency of combined cycle power plants. An alloy development strategy to this end involves superalloys strengthened by ‘compact’ γ′-γ″ coprecipitates. Compact morphology of coprecipitates consists of a cuboidal γ′ precipitate such that γ″ discs coat its six {001} faces. The present work is an attempt to investigate the microstructure and creep behavior of a fully aged alloy exhibiting compact coprecipitates. We conducted heat treatments, detailed microstructural characterization, and creep testing at 1200 °F (649 °C) on an IN718-variant alloy. Our results indicate that aged IN718-27 samples exhibit a relatively uniform distribution of compact coprecipitates, irrespective of the cooling rate. However, the alloy ruptured at low strains during creep tests at 1200 °F (649 °C). At 100 ksi (689 MPa) load, the alloy fails around 0.1% strain, and 75 ksi (517 MPa) loading causes rupture at 0.3% strain. We also report extensive intergranular failure in all the tested samples, which is attributed to cracking along grain boundary precipitates. The results suggest that while the compact coprecipitates are indeed thermally stable during thermomechanical processing, the microstructure of the alloy needs to be optimized for better creep strength and rupture life. Full article

It has been proven that through targeted quenching and partitioning (Q & P), medium manganese steels can exhibit excellent mechanical properties combining very high strength and ductility. In order to apply the potential of these steels in industrial press hardening and to avoid high scrap rates, it is of utmost importance to determine a robust process window for Q & P. Hence, an intensive study of dilatometry experiments was carried out to identify the influence of quenching temperature (T_Q) and partitioning time (t_p) on phase transformations, phase stabilities, and the mechanical properties of a lean medium manganese steel. For this purpose, additional scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), and energy dispersive X-ray spectroscopy (EDX) examinations as well as tensile testing were performed. Based on the dilatometry data, an adjustment of the Koistinen–Marburger (K-M) equation for medium manganese steel was developed. The results show that a retained austenite content of 12–21% in combination with a low-phase fraction of untempered secondary martensite (max. 20%) leads to excellent mechanical properties with a tensile strength higher than 1500 MPa and a total elongation of 18%, whereas an exceeding secondary martensite phase fraction results in brittle failure. The optimum retained austenite content was adjusted for T_Q between 130 °C and 150 °C by means of an adapted partitioning. Full article

Incremental Sheet Forming (ISF) is emerging as one of the popular dieless forming processes for the small-sized batch production of sheet metal components. However, the parts formed by the ISF process suffer from poor surface finish, geometric inaccuracy, and non-uniform thinning, which leads to poor part characteristics. Hammering, on the other hand, plays an important role in relieving residual stresses, and thus enhances the material properties through a change in grain structure. A few studies based on shot peening, one of the types of hammering operation, revealed that shot peening can produce nanostructure surfaces with different characteristics. This paper introduces a novel process, named the Incremental Sheet Hammering (ISH) process, i.e., integration of incremental sheet forming (ISF) process and hammering to improve the efficacy of the ISF process. Controlled hammering in the ISF process causes an alternating motion at the tool-sheet interface in the local deformation zone. This motion leads to enhanced material flow and subsequent improvement in the surface finish. Typical toolpath strategies are incorporated to impart the tool movement. The mechanics of the process is further explored through explicit-dynamic numerical models and experimental investigations on 1 mm thick AA1050 sheets. The varying wall angle truncated cone (VWATC) and constant wall angle truncated cone (CWATC) test geometries are identified to compare the ISF and ISH processes. The results indicate that the formability is improved in terms of wall angle, forming depth and forming limits. Further, ISF and ISH processes are compared based on the numerical and experimental results. The indicative statistical analysis is performed which shows that the ISH process would lead to an overall 10.99% improvement in the quality of the parts primarily in the surface finish and forming forces. Full article

With its excellent property combinations and ability to specifically adjust tailor-made microstructures, steel is still the world’s most important engineering and construction material. To fulfill ever-increasing demands and tighter tolerances in today’s steel industry, steel research remains indispensable. The continuous material development leads to more and more complex microstructures, which is especially true for steel designs that include bainitic structures. This poses new challenges for the classification and quantification of these microstructures. Machine learning (ML) based microstructure classification offers exciting potentials in this context. This paper is concerned with the automated, objective, and reproducible classification of the carbon-rich second phase objects in multi-phase steels by using machine learning techniques. For successful applications of ML-based classifications, a holistic approach combining computer science expertise and material science domain knowledge is necessary. Seven microstructure classes are considered: pearlite, martensite, and the bainitic subclasses degenerate pearlite, debris of cementite, incomplete transformation product, and upper and lower bainite, which can all be present simultaneously in one micrograph. Based on SEM images, textural features (Haralick parameters and local binary pattern) and morphological parameters are calculated and classified with a support vector machine. Of all second phase objects, 82.9% are classified correctly. Regarding the total area of these objects, 89.2% are classified correctly. The reported classification can be the basis for an improved, sophisticated microstructure quantification, enabling process–microstructure–property correlations to be established and thereby forming the backbone of further, microstructure-centered material development. Full article

The atomic structure of medium-range order in metallic glasses is investigated by using molecular dynamics (MD) simulations. Glass formation processes were simulated by rapid cooling from liquid phases of a model binary alloy system of different-sized elements. Two types of short-range order of atomic clusters with the five-fold symmetry are found in glassy phases: icosahedral clusters (I-clusters) formed around the smaller-sized atoms and Frank–Kasper clusters (i.e., Z14, Z15, and Z16 clusters (Z-clusters)) formed around the bigger-sized atoms. Both types of clusters (I-and Z-clusters) are observed even in liquid phases and the population of them goes up as the temperature goes down. A considerable atomic size difference between alloying elements would enhance the formation of both the I- and Z-clusters. In glassy phases, the I- and Z-clusters are mutually connected to form a complicated network, and the network structure becomes denser as the structural relaxation goes on. In the network, the medium-range order is mainly constructed by the volume sharing type connection between I- and Z-clusters. Following Nelson’s disclination theory, the network structure can be understood as a random network of Z-clusters, which is complimentarily surrounded by another type of network formed by I-clusters. Full article

The deformation structures formed in an Al-0.1Mg single-phase aluminium alloy have been studied during plane strain compression (PSC) down to liquid nitrogen temperature, following prior equal channel angular extrusion (ECAE) to a strain of ten. Under constant deformation conditions a steady state was approached irrespective of the temperature, where the rate of grain refinement stagnated and a minimum grain size was reached which could not be further reduced. A 98% reduction at 77 K (−196 °C) only transformed the ECAE processed submicron grain structure into a microstructure with thin ribbon grains, where a nanoscale high angle boundary (HAB) spacing was only approached in the sheet normal direction. It is shown that the minimum grain size achievable in severe deformation processing is controlled by a balance between the rate of compression of the HAB structure and dynamic recovery. The required boundary migration rate to maintain a constant boundary spacing is found far higher than can be justified from conventional diffusion-controlled grain growth and at low temperatures, a constant boundary spacing can only be maintained by invoking an athermal mechanism and is considered to be dominated by the operation of grain boundary dislocations. Full article

In several industrial processes, metallic materials suffer from chlorine- and sulfur-induced high-temperature corrosion. In previous studies, several steels have been tested at laboratory scale in a simulated gas atmosphere of a pyrolysis process of anthropogenic resources. In this paper, we propose a model on the course of corrosion in a H₂S and HCl-containing atmosphere for N10276, which contains, besides iron, chromium, and nickel, also molybdenum as main alloying element. Bearing in mind the impact of the main alloying elements, as well as thermodynamic considerations and kinetic effects, the corrosion behavior of N10276 in a H₂S and HCl-containing atmosphere at 480 °C and 680 °C can be explained. In addition, the corrosion behavior of N10276 is compared with earlier tested Fe-Cr-Ni alloys and differences in the corrosion behavior are stated within this paper. Full article

In order to meet the requirement of high-quality ingots, the vibrating electrode technique in the electroslag remelting (ESR) process has been proposed. Non-metallic inclusions in ingots may cause serious defects and deteriorate mechanical properties of final products. Moreover, the dimension, number and distribution of non-metallic inclusions should be strictly controlled during the ESR process in order to produce high-quality ingots. A transient 2-D coupled model is established to analyze the motion behavior of inclusions in the lab-scale ESR process with a vibrating electrode, especially under the influence of the vibration frequency, current, slag layer thickness, and filling ratio, as well as type and diameter of inclusions. Simulation model of inclusions motion behavior is established based on the Euler-Lagrange approach. The continuous phase including metal and slag, is calculated based on the volume of fluid (VOF) method, and the trajectory of inclusions is tracked with the discrete phase model (DPM). The vibrating electrode is simulated by the user-defined function and dynamic mesh. The results show that when the electrode vibration frequency is 0.25 Hz or 1 Hz, the inclusions will gather on one side of the slag layer. When it increases from 0.25 Hz to 1 Hz, the removal ratio of 10 μm and 50 μm inclusions increases by 5% and 4.1%, respectively. When the current increases from 1200 A to 1800 A, the flow following property of inclusions in the slag layer becomes worse. The removal ratio of inclusions reaches the maximum value of 92% with the current of 1500 A. The thickness of slag layer mainly affects the position of inclusions entering the liquid-metal pool. As the slag layer thickens, the inclusions removal ratio increases gradually from 82.73% to 85.91%. As the filling ratio increases, the flow following property of inclusions in the slag layer is enhanced. The removal ratio of 10 μm inclusions increases from 94.82% to 97%. However, for inclusions with a diameter of 50 μm, the maximum removal ratio is 96.04% with a filling ratio of 0.46. The distribution of 50 μm inclusions is significantly different, while the distribution of 10 μm inclusions is almost similar. Because of the influence of a vibrating electrode, 10 μm ${\mathrm{Al}}_2{\mathrm{O}}_3$ and $\mathrm{MnO}$ have a similar removal ratios of 81.33% and 82.81%, respectively. Full article

In this study, hot rolling trials were conducted on a twin-roll cast and homogenized magnesium alloy Mg-6.8Y-2.5Zn (WZ73). The WZ73 contains long period stacking ordered (LPSO) structures due to the ratio of Y and Zn content. Microstructural and texture evolution depending on the different strain and strain rates were investigated, and the resulting mechanical properties were also considered. Therefore, samples were quenched in water directly after hot rolling. The results revealed that the rolling parameters significantly influence dynamic recrystallization (DRX), while continuous and twin-induced dynamic recrystallization are assumed to be the main DRX mechanisms. It was also found that high strains and strain rates are required to proceed the DRX. The resulting textures revealed that the non-basal slip of <$a$>-dislocations and <$c+a$>-dislocations is activated during hot rolling. Hot rolling results in increased strength and ductility compared to the initial twin-roll cast and homogenized state. Full article

The refractory HEAs block material was prepared by powder sintering, using an equal atomic proportion of mixed TiZrNbMoV and NbTiAlTaV metal powder raw materials. The phase was analyzed, using an XRD. The microstructure of the specimen was observed, employing a scanning electron microscope, and the compressive strength of the specimen was measured, using an electronic universal testing machine. The results showed that the bulk cubic alloy structure was obtained by sintering at 1300 °C and 30 MPa for 4 h, and a small amount of complex metal compounds were contained. According to the pore distribution, the formed microstructure can be divided into dense and porous zones. At a compression rate of 10⁻⁴s⁻¹, the yield strengths of TiZrNbMoV and NbTiAlTaV alloys are 1201 and 700 MPa, respectively. Full article

An effective strategy to strengthen a superalloy processed by selective laser melting (SLM) is proposed. The aim is to increase the yield strength of Inconel 718 fabricated by SLM to beyond 1400 MPa, which has never been achieved before. In this study, various NbC additions (0.0%, 0.5%, 1.0%, and 5.0% by weight) were added in the powder bed of Inconel 718, and two types of post-SLM heat treatments were investigated, i.e., solution heat treated plus aging (STA) and direct aging (DA). With NbC addition, smaller depth of melt pool and finer dendritic cells were obtained. Both STA and DA promoted the precipitations of γ′ and γ″. STA eliminated the cellular dendrites and induced grain growth while DA retained the as-built cellular dendrites, grain size, and nano-carbide from NbC addition, rendering a significant 326.2 MPa increase in yield strength. In this work, 0.5% NbC addition exhibited a record-high yield strength of 1461 MPa and ultimate tensile strength of 1575 MPa for Inconel 718 processed by laser manufacturing process according to literature data to-date. Full article

Modern industry requires different advanced metallic alloys with specific properties since conventional steels cannot cover all requirements. Aluminium alloys are becoming more popular, due to their low weight, high corrosion resistance, and relatively high strength. They possess respectable electrical conductivity, and their application extends to the energy sector. There is a high demand in joining aluminium alloys with other metals, such as steels, copper, and titanium. The joining of two or more metals is challenging, due to formation of the intermetallic compound (IMC) layer with excessive brittleness. High differences in the thermophysical properties cause distortions, cracking, improper dilution, and numerous weld imperfections, having an adverse effect on strength. Laser beam as a high concentration energy source is an alternative welding method for highly conductive metals, with significant improvement in productivity, compared to conventional joining processes. It may provide lower heat input and reduce the thickness of the IMC layer. The laser beam can be combined with arc-forming hybrid processes for wider control over thermal cycle. Apart from the IMC layer thickness, there are many other factors that have a strong effect on the weld integrity; their optimisation and innovation is a key to successfully delivering high-quality joints. Full article

The aim of the present work was to investigate the effect of anodization on the fatigue and corrosion-fatigue behavior of the AZ31B magnesium alloy. Samples were anodized in constant current density mode at 20 mA cm⁻² for 5 min at room temperature, in an environmentally friendly electrolyte consisting of a mixture of sodium hydroxide and sodium silicate. Fatigue tests were conducted in air and in phosphate buffer solution (PBS) at room temperature in the tension-tension mode, at a frequency of 5 Hz and stress ratio of 0.1. S-N curves were obtained for polished and anodized samples. Fracture surface morphology was examined by optical stereo-microscopy and scanning electron microscopy. Results indicated that the fatigue limit was reduced approximately 60% at 10⁶ cycles for the anodized specimens, either for the fatigue tests conducted in air or PBS solution. Anodization had a remarkable effect on the fatigue behavior of the AZ31B alloy. The effect of the corrosive environment, in turn, was not significant. Full article

In this work, the influence of thermal (TT), mechanical, and thermomechanical (TMT) treatments using the ultrasonic nanocrystal surface modification (UNSM) on the corrosion protection properties of Inconel 718 was studied, correlating the changes in the electrochemical properties with the promoted microstructure. The UNSM treatment had a grain refinement effect on the top surface, reducing the grain size from 11.5 to 7.4 µm for the first 10 µm in depth. The high grain boundary density, due to the grain refinement, enabled a faster growth of the passive film. The impedance showed a decrease in the charge transfer resistance by three orders of magnitude, from 10⁶ to 10³ Ω cm² for as-received to 1000 °C, as the TT temperature crossed the solvus of the γ′/γ″ and approached the solvus of the δ-phase. The UNSM treatment lowered the pitting corrosion susceptibility, increasing the charge transfer resistance and decreasing the effective capacitance of the double layer, leading to the thickest passive film with 6.8 nm. Full article

Using the ab initio calculations, we study the lattice distortion of HfNbTaTiVC₅, HfNbTaTiZrC₅ and MoNbTaTiVC₅ high-entropy carbide (HEC) ceramics. Results indicate that the Bader atomic radius and charge transfer in HECs is very close to those from binary carbide. The degree of lattice distortion strongly depends on the alloying element. The Bader atomic radius can excellently describe the lattice distortion in HEC. Further, the corresponding atomic radius and formation enthalpy of binary carbides may be indicators to predict the single-phase HECs. Full article

The element distribution and the microstructures of directionally solidified ingots of Ti-45Al-8Nb and Ti-46Al-8Nb alloys were studied by scanning electron microscope (SEM) and electron probe microanalyzer (EPMA) equipped with wavelength-dispersive X-ray spectroscope (WDS). At high solidification rates, e.g., more than 50 μm/s, the ingot solidified in columnar β dendrites, while at low solidification rates, e.g., less than 30 μm/s, the solidification path changed from initial β solidification to L + β→α peritectic solidification, forming cellular dendrites with the β phase matrix surrounded by the α phase. The difference of Ti content in dendritic arms and interdendritic regions was not pronounced. The composition segregation was mainly caused by the mutual conversion of Al and Nb contents. Therefore, it was difficult to distinguish the variation of Ti in microstructure by EPMA-WDS map and line profiles. The composition of the peritectic α phase was different from that of the α phase transformed directly from the β phase. The Al content of the former was about 1 at% higher than that of the latter, while the Nb content was about 1 at% lower. The change of solidification path in the final solidified part resulted from the more severe segregation caused by slow solidification. Full article

This work compares the degradation of Mg and Mg-Ca0.3 alloy when they are exposed for 14 days to Hank’s solution at 37 °C. A combination of immersion test, electrochemical techniques (PDP, EIS, EN), and surface characterization methods (SEM-EDS, XRD, and XPS) were carried out. The pH change over time, the lower mass loss (≈20%), and the lower concentration of the released Mg²⁺ ions (≈3.6 times), as well as the lower level of the surface degradation, allowed to consider the positive effect of Ca, presenting Mg-Ca0.3 alloy with lower electrochemical activity than that of Mg. The positive effect of Ca may be due to the formed layer characteristics on the alloy surface, which impedes the cathodic hydrogen evolution and Mg-ions release. The electroless deposited Ag-nano-particles (Ag-NPs) on Mg-Ca0.3 surface were characterized by SEM-EDS, XRD, UV-Vis, and contact angle. The agar-diffusion test was used to compare the growth of Staphylococcus aureus and Escherichia coli bacteria on Mg-Ca0.3 in the presence of Ag-NPs deposits in different size. Zeta-potential of the bacteria was negative, with respect to pH of the Mueller-Hinton culture broth. The greater antibacterial effect of S. aureus was attributed to its more negative zeta-potential, attracting more released Ag⁺ ions. Full article

The ferrite fraction and phase distribution of duplex steels depend strongly on the temperature evolution during hot deformation and are correlated to different mechanical behaviors during hot deformation as well as cold deformation. Therefore, the control of microstructure evolution during hot forming is relevant for target-oriented material design. In flow stress modelling for hot forming, the influence of microstructure beyond the ferrite fraction is often neglected. In the present work, a new method is demonstrated to also consider the influence of grain size in flow stress modelling. For this purpose, different initial microstructures with different ferrite fractions and phase distribution were tested in compression tests at 1100 °C and 0.1 s⁻¹. The microstructure was analyzed before and after forming and it was observed that the differences in ferrite fractions vanished during the compression tests. Those microstructure data were used in a model including a rule of mixture and Hall–Petch relationship to extract the single-phase flow curves of ferrite and austenite. Based on the flow stress of the single phases, in combination with ferrite fraction and individual grain size, the flow curves of the different material conditions were calculated and the concurrent influence of ferrite fraction and phase distance on the mechanical behavior was discussed. Full article

The aim of this study concerns the effect of multi-pass shielded metal arc welding (SMAW) on the corrosion behavior of CW6MC cast nickel alloy. Using optical and SEM techniques the welded joint is analyzed. Vickers microhardness mapping and potentiodynamic polarization in NaCl and H₂SO₄ solutions are also evaluated. Both the Laves phase and NbC-type carbides are identified in the base metal (BM) and weld metal (WM) regions. The main microstructural difference observed between these regions is the morphology aspect and fineness of the dendritic arrays. The welding process promotes the finer columnar grains formation with refined intermetallic particles in the WM than equiaxed grains of the BM, which in turn results in higher microhardness values in the former region. However, no substantial changes were observed in the corrosion behavior between the BM and WM regions, considering both acid and saline media. Nevertheless, during the multi-pass SMAW process, some non-metallic micrometric inclusions (Mo and S-rich regions) can be constituted to occur in the WM region. This is associated with a significant drop in the corrosion performance of this region when the electrochemical tests are evaluated. Full article

The battery performance of electric vehicles depends on the density and capacity of the battery; thus, the battery cells must be assembled in as many layers as possible. Electric vehicle batteries are typically composed of several cells which form modules connected by busbars, with dozens of modules manufactured as battery packs. The ultrasonic metal welding (UMW) technology is applied to such multilayered foil welding. This study analyzed UMW to ensure the weldability of multilayered Cu foils and a Ni-plated Cu strip in lithium-ion battery cells through various approaches. In UMW, the effect of the alignment on weld production and quality were examined through the energy and mechanical performance of the weld by conducting comparative experiments on the alignment of the horn and anvil. Additionally, the effects of UMW process parameters, such as the welding pressure, amplitude, and welding time, were statistically analyzed. The weldability evaluation and characteristic analysis were performed based on these variables. Furthermore, the cross-sectional shapes and microstructure behavior of the Ni layers were analyzed based on the weld quality. Full article

This work examined the influence of dual incorporation of MoO₂ and SiO₂ on the corrosion behavior of pure titanium treated via plasma electrolytic oxidation (PEO). To achieve this purpose, pure titanium substrate was treated via PEO in an alkaline-molybdate electrolyte without and with SiO₂ nanoparticles. The microstructural observation revealed that the addition of SiO₂ nanoparticles into the electrolyte during PEO helped to seal the structural defects in the PEO coating so that a rougher, thicker, and denser coating rich in SiO₂ was successfully obtained. From the electrochemical measurements in a 3.5 wt.% NaCl solution, the TiO₂-MoO₂-SiO₂ hybrid coating exhibited a higher corrosion resistance than the TiO₂-MoO₂ coating which was attributed to the sealing effect by stable SiO₂ nanoparticles. Full article

High specific strength characteristics make magnesium alloys widely demanded in many industrial applications such as aviation, astronautics, military, automotive, bio-medicine, energy, etc. However, the high chemical reactivity of magnesium alloys significantly limits their applicability in aggressive environments. Therefore, the development of effective technologies for corrosion protection is an urgent task to ensure the use of magnesium-containing structures in various fields of application. The present paper is aimed to provide a short review of recent achievements in corrosion protection of magnesium alloys, both surface treatments and coatings, with particular focus on Mg-Al-Mn-Ce, Mg-Al-Zn-Mn and Mg-Zn-Zr alloys, because of their wide application in the transport industry. Recent progress was made during the last decade in the development of protective coatings (metals, ceramics, organic/polymer, both single layers and multilayer systems) fabricated by different deposition techniques such as anodization, physical vapour deposition, laser processes and plasma electrolytic oxidation. Full article

The effects of anodized titanium (Ti) with a potential hydrogen fluoride (HF) acid pretreatment through cathodization on the formation of nano-porous Ti dioxide (TiO₂) layer were characterized using field-emission scanning electron microscopy, grazing incidence X-ray diffractometer, and contact angle goniometer. The biocompatibility was determined by 3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyltetrazolium bromide (MTT) test. Analytical results found that a well-aligned nano-porous structure was formed on the anodized Ti surface with HF pretreatment concentration above 0.5%. Microstructure of the nano-porous Ti dioxide surface generated by anodization with HF pretreatment was composed of anatase and rutile phases, while the anodized Ti sample with HF pretreatment concentration of 0.5% presented excellent hydrophilicity surface. An in-vitro biocompatibility also indicated that osteoblast cells grown on the surface of the anodized Ti sample with HF pretreatment increased with the increase of culture time. The filopodia of osteoblast cells not only adhered flat, but also tightly grabbed the nano-porous structure for promoting cell adhesion and proliferation. Therefore, the anodized Ti with HF pretreatment can form a functionalized surface with great biocompatibility for biomedical applications, particularly for dental implants. Full article

High-current pulsed electron-beam (PEB) treatment was applied as a surface finishing procedure for Ti–35Nb–7Zr–5Ta (TNZT) alloy produced by electron beam melting (EBM). According to the XRD results the TNZT alloy samples before and after the PEB treatment have shown mainly the single body-centered cubic (bcc) β-phase microstructures. The crystallite size, dislocation density, and microstrain remain unchanged after the PEB treatment. The investigation of the texture coefficient at the different grazing angle revealed the evolution of the crystallite orientations at the re-melted zone formed at the top of the bulk samples after the PEB treatment. The top-view SEM micrographs of the TNZT samples treated by PEB exhibited the bcc β-phase grains with an average size of ~85 μm. TEM analysis of as-manufactured TNZT alloy revealed the presence of the equiaxed β-grains with the fine dispersion of nanocrystalline α and NbTi4 phases together with β-Ti twins. Meanwhile, the β phase regions free of α phase precipitation are observed in the microstructure after the PEB irradiation. Nanoindentation tests revealed that the surface mechanical properties of the melted zone were slightly improved. However, the elastic modulus and microhardness in the heat-affected zone and the deeper regions of the sample were not changed after the treatment. Moreover, the TNZT alloy in the bulk region manufactured by EBM displayed no significant change in the corrosion resistance after the PEB treatment. Hence, it can be concluded that the PEB irradiation is a viable approach to improve the surface topography of EBM-manufactured TNZT alloy, while the most important mechanical parameters remain unchanged. Full article

Uranium-Molybdenum alloy has been a promising option in the production of metallic nuclear fuels, where the introduction of Molybdenum enhances mechanical properties, corrosion resistance, and dimensional stability of fuel components. Meanwhile, few potential options for molecular dynamics simulations of U and its alloys have been reported due to the difficulty in the description of the directional effects within atomic interactions, mainly induced by itinerant f-electron behaviors. In the present study, a new angular dependent potential formalism proposed by the author’s group has been further applied to the description of the U-Mo systems, which has achieved a moderately well reproduction of macroscopic properties such as lattice constants and elastic constants of reference phases. Moreover, the potential has been further improved to more accurately describe the threshold displacement energy surface at intermediate and short atomic distances. Simulations of primary radiation damage in solid solutions of the U-Mo system have also been carried out and an uplift in the residual defect population has been observed when the Mo content decreases to around 5 wt.%, which corroborates the negative role of local Mo depletion in mitigation of irradiation damage and consequent swelling behavior. Full article

The application of metals in biological systems has been a rapidly growing branch of science. Vanadium has been investigated and reported as an anticancer agent. Melanoma is the most aggressive type of skin cancer, the incidence of which has been increasing annually worldwide. It is of paramount importance to identify novel pharmacological agents for melanoma treatment. Herein, a systematic review of publications including “Melanoma and Vanadium” was performed. Nine vanadium articles in several melanoma cells lines such as human A375, human CN-mel and murine B16F10, as well as in vivo studies, are described. Vanadium-based compounds with anticancer activity against melanoma include: (1) oxidovanadium(IV); (2) XMenes; (3) vanadium pentoxide, (4) oxidovanadium(IV) pyridinonate compounds; (5) vanadate; (6) polysaccharides vanadium(IV/V) complexes; (7) mixed-metal binuclear ruthenium(II)–vanadium(IV) complexes; (8) pyridoxal-based oxidovanadium(IV) complexes and (9) functionalized nanoparticles of yttrium vanadate doped with europium. Vanadium compounds and/or vanadium materials show potential anticancer activities that may be used as a useful approach to treat melanoma. Full article

The degradation behavior and biocompatibility of pure molybdenum (Mo) were investigated. Dissolution of powder metallurgically manufactured and commercially available Mo was investigated by ion concentration measurement after immersion in modified Kokubo’s SBF (c-SBF-Ca) for 28 days at 37 °C and pH 7.4. Degradation layers and corrosion attack were examined with optical microscopy and REM/EDX analysis. Furthermore, potentiodynamic polarization measurements were conducted. Mo gradually dissolves in modified SBF releasing molybdate anions (MoO₄²⁻). The dissolution rate after 28 days is 10 µm/y for both materials and dissolution accelerates over time. A non-passivating, uniform and slowly soluble degradation product layer is observed. Additionally, apoptosis and necrosis assays with Mo ion extracts and colonization tests with human endothelial (HCAEC) and smooth muscle cell lines (HCASMC) on Mo substrates were performed. No adverse effects on cell viability were observed for concentrations expected from the dissolution of implants with typical geometries and substrates were densely colonized by both cell lines. Furthermore, Mo does not trigger thrombogenic or inflammatory responses. In combination with its favorable mechanical properties and the renal excretion of bio-available molybdate ions, Mo may be an alternative to established bioresorbable metals. Full article

As is well known, corrosion of steel reinforcement deteriorates the steel–concrete interface and causes concrete cracking, degrading significantly the bond strength. Several experimental studies have investigated the magnitude of residual bond strength due to corrosion, which affects either the function of corrosion-damaged steel bars or the surface crack width in concrete. As a result, linear and exponential correlation relationships have been proposed in order to predict the bond loss due to corrosion. Based on the results of an ongoing experimental campaign on the degradation of bond strength of RC specimens, combined with comparable outcomes from existing literature, this manuscript summarizes a database, comparing with the recommendations of Model Code 2010, to analyze and interpret the corrosion effect on the bond loss and highlights some points that need improvement in the current regulations. As indicated, the density of transverse reinforcement (stirrups spacing) has intense impact on the resulting bond loss due to corrosion. Hence, in order to quantify this aspect, the present manuscript introduces a discretization of confinement levels of RC elements, depending on the stirrups spacing. Based on this, regression analyses of data were conducted to extract fitting curves of bond loss, taking into account the amount of transverse reinforcement and predictive zones of residual bond strength in relationship to either corrosion penetration or surface crack width. Furthermore, the outcomes demonstrate that the corrosion penetration depth is an appropriate assessment tool to correlate the residual bond strength with the corrosion level, whereas the surface crack width on concrete is not yet an effective index, since there is a plethora of factors affecting the crack width. Due to this, more research is needed to improve the current level of knowledge on the surface crack width and link it with the corrosion damage of the steel bar and the residual bond strength due to corrosion. Full article

As biocompatible metallic materials, titanium and its alloys have been widely used in the orthopedic field due to their superior strength, low density, and ease of processing. However, further improvement in biological response is still required for rapid osseointegration. Here, various Ti surface-treatment technologies were applied: hydroxyapatite blasting, sand blasting and acid etching, anodic oxidation, and micro-arc oxidation. The surface characteristics of specimens subjected to these techniques were analyzed in terms of structure, elemental composition, and wettability. The adhesion strength of the coating layer was also assessed for the coated specimens. Biocompatibility was compared via tests of in vitro attachment and proliferation of pre-osteoblast cells. Full article

The importance of taking into account directional solidification of grains formed during 3D printing is determined by a substantial influence of their crystallographic orientation on the mechanical properties of a loaded material. This issue is studied in the present study using molecular dynamics simulations. The compression of an FCC single crystal of aluminum bronze was performed along the <111> axis. A Ni single crystal, which is characterized by higher stacking fault energy (SFE) than aluminum bronze, was also considered. It was found that the first dislocations started to move earlier in the material with lower SFE, in which the slip of two Shockley partials was observed. In the case of the material with higher SFE, the slip of a full dislocation occurred via successive splitting of its segments into partial dislocations. Regardless of the SFE value, the deformation was primarily occurred by means of the formation of dislocation complexes involved stair-rod dislocations and partial dislocations on adjacent slip planes. Hardening and softening segments of the calculated stress–strain curve were shown to correspond to the periods of hindering of dislocations at dislocation pileups and dislocation movement between them. The simulation results well agree with the experimental findings. Full article

Titanium alloys have been considered as unique materials for many years. Even their microstructure and operational properties have been well known and described in details, the new technologies introduced—e.g., 3D printing—have restored the need for further research in this area. It is understood that martensitic transformation is usually applied in heat treatment of hardenable alloys (e.g., Fe alloys), but in the case of titanium alloys, it also occurs during the thermomechanical processing or advanced additive manufacturing. The paper summarizes previous knowledge on martensite formation and decomposition processes in two-phase titanium alloys. It emphasizes their important role in microstructure development during conventional and modern industrial processing. Full article

Literature has suggested metallic nanomaterials (NMs) for a multitude of applications in cosmetic products, either as active ingredients or excipients. Alike most high-paced industrial sectors, cosmetology continues to capitalize on its unique properties/functions (e.g., as UV-filters, colorants, etc.), adding value to a wide range of products. However, as a result of their nano-scale, NMs do not always conform with the handling guidelines of their bulk counterparts, nor do conventional analytical methods account for their complex physicochemical and biological interactions. Among others, metallic nanoparticles have attracted the interest of many over the years due to their unique features, but possible precautions should be considered because of their bio-persistent nature. As a result, it is prevalent to consider a nano-specific framework, to regulate the use of NMs and the production of nano-enhanced cosmetics. To address this, we provide insight into the NMs that are currently used in the EU market, with a focus on metallic NMs, while analyzing the underlying legislation and relevant Opinions of the Scientific Committee on Consumer Safety (SCCS), from a scientific and commercial perspective. Even though the current Cosmetics Regulation (EU Regulation No 1223/2009) already entails specific provisions on NMs, cosmetic products incorporating unauthorized NMs have been repeatedly commercialized in the European Union. Considering the potential risks of NMs if they are mishandled, we provide an analysis of the risk assessment, as stated in Article 16 of the Cosmetics Regulation, to serve as a guideline for the future growth of nano-enhanced products. Based on the limited integration of metallic NMs along with multiple non-metallic NPs into cosmetic products, the attention of the community is directed towards coordinating efforts on the integration of metallic NMs into cosmetics. Full article

Infrastructures and industrial buildings are commonly exposed to aggressive environments and damaged by corrosion. In prestressed reinforced concrete structures, the potential risks of corrosion could be severe since reinforcements are already subjected to high amounts of stress and, consequently, their load-bearing capacity could abruptly decrease. In recent years, some experimental studies have been conducted to explore the flexural behavior of corroded pretensioned reinforced concrete (PRC) beams, investigating several aspects of residual structural performance. Although many studies have been done in this area, there is no concise paper reviewing the state-of-the-art research. Accordingly, the main objective of this paper is to provide a review of the available experimental tests for residual capacity assessment of corroded PRC beams. Based on the state-of-the-art review, a degradation law for the flexural strength of corroded PRC beams is suggested. Full article

Rapid progress in material science and nanotechnology has led to the development of the shape memory alloys (SMA) and the shape memory polymers (SMP) based functional multilayered structures that, due to their capability to achieve the properties not feasible by most natural materials, have attracted a significant attention from the scientific community. These shape memory materials can sustain large deformations, which can be recovered once the appropriate value of an external stimulus is applied. Moreover, the SMAs and SMPs can be reprogrammed to meet several desired functional properties. As a result, SMAs and SMPs multilayered structures benefit from the unprecedented physical and material properties such as the shape memory effect, superelasticity, large displacement actuation, changeable mechanical properties, and the high energy density. They hold promises in the design of advanced functional micro- and nano-electro-mechanical systems (MEMS/NEMS). In this review, we discuss the recent understanding and progress in the fields of the SMAs and SMPs. Particular attention will be given to the existing challenges, critical issues, limitations, and achievements in the preparation and characterization of the SMPs and NiTi-based SMAs thin films, and their heterostructures for MEMS/NEMS applications including both experimental and computational approaches. Examples of the recent MEMS/NEMS devices utilizing the unique properties of SMAs and SMPs such as micropumps, microsensors or tunable metamaterial resonators are highlighted. In addition, we also introduce the prospective future research directions in the fields of SMAs and SMPs for the nanotechnology applications. Full article

The corrosion behavior of AZ31B Mg alloy exposed to Ringer’s, phosphate-buffered saline (PBS), Hank’s, and simulated body fluid (SBF) solutions for 4 days was investigated using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, weight loss, and surface characterization. Changes in corrosion rates with immersion time determined by weight loss measurements were compared with EIS data to determine the possibility of obtaining quantitative electrochemical information. In addition, changes in the protective properties of the corrosion product layer calculated from the EIS parameters were evaluated as a function of their surface chemical composition as determined by X-ray photoelectron spectroscopy (XPS) and visual observations of the corroded specimen’s surface. Apparent Stern–Geary coefficients for the AZ31B Mg alloy in each test solution were calculated using the relationship between i_corr from weight loss measurements and the EIS data (both R_p and R_t). This provided experimental reference B′ values that may be used as a useful tool in independent investigations to improve the accuracy of corrosion rates of AZ31B Mg alloy in simulated body solutions. Full article

This study aims to establish the effects of equal channel angular pressing (ECAP) processing on the corrosion behavior and hardness values of the AZ31 Mg alloy. The AZ31 billets were processed through ECAP successfully at 250 °C and their microstructural evolution was studied using optical and field emission scanning electron microscopy. The corrosion resistance of the AZ31 alloy was studied before and after processing through ECAP. The homogeneity of the hardness distribution was studied using both sections cut parallel and perpendicular to the extrusion direction. ECAP processing resulted in highly deformed central regions with elongated grains aligned parallel to the extrusion direction, whereas the peripheral regions showed an ultra-fine-grain recrystallized structure. After processing, small ultra-fine secondary particles were found to be homogeneously dispersed alongside the grain boundaries of the α-Mg matrix. Regarding the corrosion properties, measurements showed that ECAP processing through 1-P and 2-Bc resulted in decreasing their corrosion rate to 67.7% and 78.3%, respectively, of their as-annealed counterpart’s. The corrosion resistance of the ECAPed Mg alloy increased with the number of processing passes. This was due to the refinement of the grain size of the α-Mg matrix and secondary phases till ultra-fine size, caused by the accumulation of strain during processing. On the other hand, ECAP processing through 2-Bc resulted in increasing the Vickers hardness values by 132% and 71.8% at the peripheral and central areas, respectively, compared to the as-annealed counterpart. Full article

To prevent a premature failure, absorbable magnesium implants must possess an adequate mechanical stability. Among many ways to improve the mechanical properties of magnesium is by particle reinforcement, such as using carbon nanofiber (CNF). This work reports an experimental design for optimum materials and processing of CNF-reinforced Mg–Zn composites based on a two-level factorial design. Four factors were analyzed: percentage of CNF, compaction pressure, sintering temperature, and sintering time, for three recorded responses: elastic modulus, hardness, and weight loss. Based on the two-level factorial design, mechanical properties and degradation resistance of the composites reach its optimum at a composition of 2 wt % CNF, 400 MPa of compaction pressure, and 500 °C of sintering temperature. The analysis of variance reveals a significant effect of all variables (p < 0.0500) except for the sintering time (p > 0.0500). The elastic modulus and hardness reach their highest values at 4685 MPa and 60 Hv, respectively. The minimum and maximum weight loss after three days of immersion in PBS are recorded at 54% and 100%, respectively. This work concludes the percentage of CNF, compaction pressure, and sintering temperature as the main factors affecting the optimum elastic modulus, hardness, and degradation resistance of CNF-reinforced Mg–Zn composites. Full article

The purpose of our study is to compare the behavior of two reprocessed dental alloys (NiCr and CoCr) at different temperatures considering the idea that food and drinks in the oral cavity create various compositions at different pH levels; the novelty is the investigation of temperature effect on corrosion parameters and ion release of dental alloys. Electrochemical stability was studied together with morphology, elemental composition and ions release determination. The results obtained are in good concordance: electrochemistry studies reveal that the corrosion rate is increasing by increasing the temperature. From SEM coupled with EDS, the oxide film formed on the surface of the alloys is stable at low temperatures and a trend to break after 310K. ICP-MS results evidence that in accordance with increasing temperature, the quantities of ions released from the alloys immersed in artificial saliva also increase, though they still remain small, less than 20 ppm. Full article

In the process of welding zinc-coated steel, zinc vapor causes serious porosity defects. The porosity defect is an important indicator of the quality of welds and degrades the durability and productivity of the weld. Therefore, this study proposes a deep neural network (DNN)-based non-destructive testing method that can detect and predict porosity defects in real-time, based on welding voltage signal, without requiring additional device in gas metal arc welding (GMAW) process. To this end, a galvannealed hot-rolled high-strength steel sheet applied to automotive parts was used to measure process signals in real-time. Then, feature variables were extracted through preprocessing, and correlation between the feature variables and weld porosity was analyzed. The proposed DNN based framework outperformed the artificial neural network (ANN) model by 15% or more. Finally, an experiment was conducted by using the developed porosity detection and prediction system to evaluate its field application. Full article