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Molecules, Volume 11, Issue 4

April 2006 - 10 articles

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Articles (10)

  • Article
  • Open Access
21 Citations
10,894 Views
11 Pages

Catalytic Properties of the Dioxomolybdenum Siloxide MoO2(OSiPh3)2 and its 2,2'-Bipyridine Adduct MoO2(OSiPh3)2(bpy)

  • Sofia M. Bruno,
  • Bernardo Monteiro,
  • Maria Salete Balula,
  • Catarina Lourenço,
  • Anabela A. Valente,
  • Martyn Pillinger,
  • Paulo Ribeiro-Claro and
  • Isabel S. Gonçalves

12 April 2006

The tetrahedral triphenylsiloxy complex MoO2(OSiPh3)2 (1) and its Lewis baseadduct with 2,2'-bipyridine, MoO2(OSiPh3)2(bpy) (2), were prepared and characterised byIR/Raman spectroscopy, and thermogravimetric analysis. Both compounds catalyse theepoxi...

  • Article
  • Open Access
39 Citations
14,725 Views
9 Pages

10 April 2006

Esterifications of carboxylic acids with equimolar amount of alcohols could beefficiently catalyzed by ZrOCl2·8H2O. Acrylate esters were obtained in good yields undersolvent-free conditions at ambient temperature. The esterification of other carboxyl...

  • Article
  • Open Access
24 Citations
13,404 Views
7 Pages

Microwave Assisted Synthesis of N-Arylheterocyclic Substituted-4-aminoquinazoline Derivatives

  • Gang Liu,
  • Song Yang,
  • Baoan Song,
  • Wei Xue,
  • Deyu Hu,
  • Linhong Jin and
  • Ping Lu

10 April 2006

A simple, efficient, and general method has been developed for the synthesis of various N-aryl heterocylic substituted-4-aminoquinazoline compounds from 4-chloro- quinazoline and aryl heterocyclic amines under microwave irradiation using 2-propanol a...

  • Article
  • Open Access
5 Citations
11,677 Views
7 Pages

Reactions of (Benzamidomethyl)triethylammonium Chloride with Some Inorganic Nucleophiles in Aqueous Media

  • Emil Popovski,
  • Jane Bogdanov,
  • Metodija Najdoski and
  • Evamarie Hey-Hawkins

10 April 2006

A variety of benzamidomethyl derivatives were prepared in water under alkaline conditions (pH>9) via reaction of (benzamidomethyl)triethylammonium chloride (1) with different inorganic nucleophiles. Reaction of 1 with hydroxylamine did not give the e...

  • Article
  • Open Access
73 Citations
17,809 Views
12 Pages

10 April 2006

The synthesis of three substituted 6,7-dihydroxy-4-quinazolineamines: tandutinib (1), erlotinib (2) and gefitinib (3) in improved yields is reported. The intermediates were characterized by NMR and the purities determined by HPLC.

  • Article
  • Open Access
12 Citations
19,289 Views
13 Pages

A Java Chemical Structure Editor Supporting the Modular Chemical Descriptor Language (MCDL)

  • Sergei V. Trepalin,
  • Alexander V. Yarkov,
  • Igor V. Pletnev and
  • Andrei A. Gakh

29 March 2006

A compact Modular Chemical Descriptor Language (MCDL) chemical structure editor (Java applet) is described. The small size (approximately 200 KB) of the applet allows its use to display and edit chemical structures in various Internet applications. T...

  • Article
  • Open Access
62 Citations
12,056 Views
15 Pages

Substituted Pyrazinecarboxamides: Synthesis and Biological Evaluation

  • Martin Dolezal,
  • Lukas Palek,
  • Jarmila Vinsova,
  • Vladimir Buchta,
  • Josef Jampilek and
  • Katarina Kralova

29 March 2006

Condensation of the corresponding chlorides of some substituted pyrazine-2-carboxylic acids (pyrazine-2-carboxylic acid, 6-chloropyrazine-2-carboxylic acid, 5-tert-butylpyrazine-2-carboxylic acid or 5-tert-butyl-6-chloropyrazine-2-carboxylic acid) wi...

  • Communication
  • Open Access
35 Citations
9,195 Views
6 Pages

29 March 2006

Nine known and one new ent-kaurene diterpenoid were isolated from the acetone extract of Sideritis stricta Boiss & Heldr. The new compound, identified as ent-1β-hydroxy-7α-acetyl-15β,16β-epoxykaurane (1) by IR, 1D and 2D NMR techniques and mass s...

  • Article
  • Open Access
17 Citations
67,315 Views
7 Pages

27 March 2006

2,6-Dichloro-9-thiabicyclo[3.3.1]nonane, easily available by an improved condensation of sulfur dichloride, sulfuryl chloride, and 1,5-cyclooctadiene, is a well- behaved scaffold for the nucleophilic substitution of azides and cyanides via neighborin...

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Molecules - ISSN 1420-3049