Coordination Modes and Different Hapticities for Fullerene Organometallic Complexes
Abstract
:1. Introduction
2. The Possibilities of Hapticity
- ﹣ η1 hapticity with the metal atom directly above any carbon atom (an σ bond is expected);
- ﹣ η2 hapticity; this may be (6,6) or (6,5) type, although the last of these is not common;
- ﹣ η3 hapticity; the metal atom linked to three carbon atoms, theoretically this could be on either a six or five-member ring;
- ﹣ η4 hapticity, the metal atom linked to four carbon atoms;
- ﹣ η5 hapticity, metal atom linked directly above the center of a five-member ring;
- ﹣ η6 hapticity, metal atom linked directly above the center of a six-member ring.
3. η1 Hapticity
4. η2 Hapticity
5. η3 and η4 Hapticities
6. η5 Hapticity
7. η6 Hapticity
9. Conclusions
Acknowledgements
References and Notes
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Soto, D.; Salcedo, R. Coordination Modes and Different Hapticities for Fullerene Organometallic Complexes. Molecules 2012, 17, 7151-7168. https://doi.org/10.3390/molecules17067151
Soto D, Salcedo R. Coordination Modes and Different Hapticities for Fullerene Organometallic Complexes. Molecules. 2012; 17(6):7151-7168. https://doi.org/10.3390/molecules17067151
Chicago/Turabian StyleSoto, Delia, and Roberto Salcedo. 2012. "Coordination Modes and Different Hapticities for Fullerene Organometallic Complexes" Molecules 17, no. 6: 7151-7168. https://doi.org/10.3390/molecules17067151