Manganese(III) Acetate-mediated Oxidative Cyclization of a-Methylstyrene and trans-Stilbene with b-Ketosulfones
Abstract
:1. Introduction
2. Results and Discussion
Entry | Product | Yields a |
---|---|---|
1 | 92% | |
2 | 61% | |
3 | 89% | |
4 | 88% | |
5 | 65% |
Entry | β-ketosulfone/alkene | Product/Yields a | |
---|---|---|---|
1 | 1/α-methylstyrene | /43% | |
2 | 2/α-methylstyrene | /34% | |
3 | 3/α-methylstyrene | /35% | |
4 | 4/α-methylstyrene | /51% | |
5 | 5/α-methylstyrene | /45% | |
6 | 1/ trans-stilbene | /21% | /12% |
7 | 2/ trans-stilbene | /13% | /10% |
8 | 3/ trans-stilbene | /12% | /5% |
9 | 4/ trans-stilbene | /25% | /13% |
10 | 5/ trans-stilbene | /23% |
3. Experimental
3.1. General
3.2. General Procedure for the Synthesis of β-Ketosulfones 1–5
3.3. General Procedure for the Synthesis of Dihydrofurans 6–10
3.4. General Procedure for the Synthesis of Dihydrofurans 11–15 and Cyclopropanes 16–19
3.5. X-ray Structure Determination of Compounds 16
4. Conclusions
Acknowledgments
References
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Bouhlel, A.; Curti, C.; Tabelé, C.; Vanelle, P. Manganese(III) Acetate-mediated Oxidative Cyclization of a-Methylstyrene and trans-Stilbene with b-Ketosulfones. Molecules 2013, 18, 4293-4307. https://doi.org/10.3390/molecules18044293
Bouhlel A, Curti C, Tabelé C, Vanelle P. Manganese(III) Acetate-mediated Oxidative Cyclization of a-Methylstyrene and trans-Stilbene with b-Ketosulfones. Molecules. 2013; 18(4):4293-4307. https://doi.org/10.3390/molecules18044293
Chicago/Turabian StyleBouhlel, Ahlem, Christophe Curti, Clémence Tabelé, and Patrice Vanelle. 2013. "Manganese(III) Acetate-mediated Oxidative Cyclization of a-Methylstyrene and trans-Stilbene with b-Ketosulfones" Molecules 18, no. 4: 4293-4307. https://doi.org/10.3390/molecules18044293