Inclusion and Functionalization of Polymers with Cyclodextrins: Current Applications and Future Prospects
Abstract
:1. Introduction
2. Polymers as Ternary Complex Constituents
3. Networks of Polymers and Cyclodextrins
4. Molecularly Imprinted Polymers (MIPs) with Cyclodextrins
5. Current Applications of Polymers and CD Networks
Polymer | Application | Ref. | |
---|---|---|---|
β- and γ-CDs linked with chitosan | Bitter-masking of caffeine solutions and bitter natural extracts | [37] | |
β-CD with one of the following crosslinking agents: epichlorohydrin, diphenyl carbonate, or hexamethylene diisocyanate and propargyl-β-CD with 1,3-bis(azidomethyl) benzene | Debittering agents by adsorption of narangin, limonin and caffeine | [38] | |
β-CD and epichlorohydrin | Environmental purposes: detoxification of wastewater, color removal, concentration and purification of solutions | [19] | |
Delivery of Lavandula angustifolia essential oil used as ambient odors | [39] | ||
Retention of aroma compounds of Mentha piperita esential oil | [40] | ||
Adsorption of pesticides from water | [41] | ||
Removal of Cu2+ from aqueous solutionss | [42] | ||
β-CD and anionic and cationic acrylamide | Enhancement of oil recovery | [22] | |
Chemically cross-linked and grafted cyclodextrins | Drug release from hydrogels | [28] | |
α-, β- and γ-CDs functionalized with acrylic groups | Aqueous nanogels | [43] | |
β-CD polymer/tungsten carbide | Adsorption of rutin | [26] | |
β-CD, acrylic acid, N,N'-methylenebisacrylamide | Hydrogel for the removal of heavy metal ions | [44] | |
Monomethacrylated β-CD copolymerized with N-isopropylacrylamide | Drug delivery | [21] | |
Oligosaccharide γ-CD with dibasic acid dichlorides | Adsorption of polychlorobiphenyl contaminants in oil | [45] | |
β-CD-citric acid | Drug delivery of ciprofloxacin (an antibiotic) and prednisolone (an anti-inflammatory drug) | [46] | |
β-CD-dextran polymers | Drug delivery | [47] | |
HPγ-CD polymer and sulfobutylether-β-CD with epichlorohydrin | Adsorption of ionizable oxytetracycline antibiotics | [48] | |
Phosphorous-containing β-CD polymers | 1-adamantyl acetic acid, or with divalent cations, such as Ca2+ | [49] | |
CD crosslinked with 4,4'-methylenebis(phenyl isocyanate) | Removal of patulin from apple juice | [50] | |
Glycidyl methacrylate alone or in combination with β-CD | Incorporation of insecticide in cotton textiles | [51] | |
α-CD-polymer gels with various poly(ethylene oxide) (PEO)-based copolymers | Delivery of vancomycin for the treatment of bone infections | [52] | |
From β-CD and sulfobutylether-β-CD with epichlorohydrin | Solubilization of repaglinide (hypoglycemic agent) | [53] | |
β-CD-ionic liquid polymer with 1-benzylimidazole and crosslinked using toluenediisocyanate | Sorption capacity and high removal towards phenols and arsenic(V) | [54] | |
Carboxymethyl-hydroxypropyl-β-CD polymer-modified Fe3O4 magnetic particles (CM-HP-β-CDCP-MNPs) | Magnetic solid phase extraction of rutin | [55] | |
Crosslinked polyvinyl alcohol/glutaraldehyde (PVA/GA) membranes with β-CD | Textile liquid waste processing | [56] | |
PCCA thin film modified with β-CD polymer | Capping cavity for the selective detection of paraoxon-ethyl and parathion-ethyl chemical agents | [57] |
6. Conclusions
Acknowledgments
Conflicts of Interest
References
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Folch-Cano, C.; Yazdani-Pedram, M.; Olea-Azar, C. Inclusion and Functionalization of Polymers with Cyclodextrins: Current Applications and Future Prospects. Molecules 2014, 19, 14066-14079. https://doi.org/10.3390/molecules190914066
Folch-Cano C, Yazdani-Pedram M, Olea-Azar C. Inclusion and Functionalization of Polymers with Cyclodextrins: Current Applications and Future Prospects. Molecules. 2014; 19(9):14066-14079. https://doi.org/10.3390/molecules190914066
Chicago/Turabian StyleFolch-Cano, Christian, Mehrdad Yazdani-Pedram, and Claudio Olea-Azar. 2014. "Inclusion and Functionalization of Polymers with Cyclodextrins: Current Applications and Future Prospects" Molecules 19, no. 9: 14066-14079. https://doi.org/10.3390/molecules190914066