Understanding the Mechanism of Action of Triazine-Phosphonate Derivatives as Flame Retardants for Cotton Fabric
Abstract
:1. Introduction
2. Results and Discussion
2.1. Fabric Treatment
2.2. Thermal Decomposition of Fabrics Treated with TPN1 and TPN3: Investigation of Chemical Components in both Gas and Solid Phases
2.2.1. Functional Groups Observed on the Surface of Treated Fabrics before thermal Decomposition
2.2.2. Gas Products Released during Thermal Decomposition
2.2.3. Information on Char: Functional Groups Observed by ATR-IR
2.2.4. 31P solid State NMR of Treated Fabrics
2.3. Predicted Energy Required Fragmenting TPN1 and TPN3 at Different Positions
2.4. Plausible Explanation for Thermal Degradation of TPN1 and TPN3
3. Experimental Section
3.1. Materials
3.2. Synthesis
3.2.1. Synthesis of TPN1
3.2.2. Synthesis of TPN3
3.3. Fabric Treatment
3.4. Instrumentation
3.4.1. ATR-IR and TGA/FTIR
3.4.2. 31P Solid State NMR
3.5. BDE
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Nguyen, M.M.; Al-Abdul-Wahid, M.S.; Fontenot, K.R.; Graves, E.E.; Chang, S.; Condon, B.D.; Grimm, C.C.; Lorigan, G.A. Understanding the Mechanism of Action of Triazine-Phosphonate Derivatives as Flame Retardants for Cotton Fabric. Molecules 2015, 20, 11236-11256. https://doi.org/10.3390/molecules200611236
Nguyen MM, Al-Abdul-Wahid MS, Fontenot KR, Graves EE, Chang S, Condon BD, Grimm CC, Lorigan GA. Understanding the Mechanism of Action of Triazine-Phosphonate Derivatives as Flame Retardants for Cotton Fabric. Molecules. 2015; 20(6):11236-11256. https://doi.org/10.3390/molecules200611236
Chicago/Turabian StyleNguyen, Monique M., M. Sameer Al-Abdul-Wahid, Krystal R. Fontenot, Elena E. Graves, SeChin Chang, Brian D. Condon, Casey C. Grimm, and Gary A. Lorigan. 2015. "Understanding the Mechanism of Action of Triazine-Phosphonate Derivatives as Flame Retardants for Cotton Fabric" Molecules 20, no. 6: 11236-11256. https://doi.org/10.3390/molecules200611236