Synthesis of Binderless ZK-4 Zeolite Microspheres at High Temperature
Abstract
:1. Introduction
2. Methodology
2.1. Preparation of the ZK-4 Zeolite Microspheres
2.2. Characterization of Zeosils
2.3. VOC Adsorption Measurements
2.3.1. Experimental Measurements
2.3.2. CB–GCMC Simulation
3. Results and Discussion
3.1. XRD Analysis
3.2. n-Hexane Adsorption Analysis
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Sample Availability: Samples of the compounds of ZK-4 beads are available from the authors. |
Boiling Point (°C) | Vapor Pressure at 25 °C a (KPa) | Molar Volume at 25 °C (L·mol−1) | Kinetic Diameter b (Å) | |
---|---|---|---|---|
n-Hexane | 69 | ≈ 20.0 | 0.13198 | 4.3 |
150 °C, 24 h | 160 °C, 24 h | 170 °C, 24 h | 180 °C, 24 h | |
---|---|---|---|---|
SBET (m²·g−1) | 766 | 773 | 805 | 795 |
Vmicro (cm3·g−1) | 0.28 | 0.28 | 0.29 | 0.29 |
Vmeso (cm3·g−1) | 0.09 | 0.16 | 0.29 | 0.31 |
Mesoporous diameter (nm) | 40–50 | 40–50 | 40–50 | 40–50 |
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Fawaz, E.G.; Salam, D.A.; Nouali, H.; Deroche, I.; Rigolet, S.; Lebeau, B.; Daou, T.J. Synthesis of Binderless ZK-4 Zeolite Microspheres at High Temperature. Molecules 2018, 23, 2647. https://doi.org/10.3390/molecules23102647
Fawaz EG, Salam DA, Nouali H, Deroche I, Rigolet S, Lebeau B, Daou TJ. Synthesis of Binderless ZK-4 Zeolite Microspheres at High Temperature. Molecules. 2018; 23(10):2647. https://doi.org/10.3390/molecules23102647
Chicago/Turabian StyleFawaz, Elyssa G., Darine A. Salam, Habiba Nouali, Irena Deroche, Severinne Rigolet, Benedicte Lebeau, and T. Jean Daou. 2018. "Synthesis of Binderless ZK-4 Zeolite Microspheres at High Temperature" Molecules 23, no. 10: 2647. https://doi.org/10.3390/molecules23102647