Syntheses, Structures, and Characteristics of Three Metal Complexes Constructed Using Hexacarboxylic Acid
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials and Methods
2.2. Synthesis of {[Cd3(L)(H2O)6]·H2O}n (1)
2.3. Synthesis of {[Cu1.5(L)0.5(bimb)1.5]·5H2O·DMF}n (2)
2.4. Synthesis of {[Mn1.5(H3L)(bibp)0.5(H2O)2]·3H2O}n (3)
2.5. X-ray Crystallography
3. Results and Discussion
3.1. Structural Description of 1
3.2. Structural Description of 2
3.3. Structural Description of 3
3.4. PXRD and Thermogravimetric Analysis (TGA)
3.5. Photoluminescent Properties of 1
3.6. Detection of Fe3+ Ions
3.7. Electrochemical Properties
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Compound | 1 | 2 | 3 |
---|---|---|---|
Molecular Formula | C15H26Cd3N6O19 | C57H64N20Cu3O24 | C54H50Mn3N18O34 |
Formula weight | 917.54 | 1593.85 | 1659.94 |
Crystal system | Monoclinic | Monoclinic | Triclinic |
Space group | P21/c | C2/c | P-1 |
a/Å | 9.7574 (3) | 31.421 (3) | 8.234 (2) |
b/Å | 15.1249 (5) | 17.6474 (18) | 10.610 (3) |
c/Å | 18.6267 (6) | 17.2392 (17) | 19.504 (6) |
α/(°) | 90 | 90 | 81.094 (6) |
β/(°) | 95.449 (1) | 117.491 (2) | 87.935 (7) |
γ/(°) | 90 | 90 | 86.408 (7) |
V/nm3 | 2736.50 (15) | 8479.7 (15) | 1679.6 (8) |
Z | 4 | 4 | 1 |
Dc/(g·cm−3) | 2.227 | 1.248 | 1.641 |
F(000) | 1760 | 3260 | 847 |
s | 1.090 | 1.189 | 1.039 |
R1/wR2 [I > 2σ(I)] | 0.0235, 0.0623 | 0.1020, 0.3087 | 0.0682, 0.1824 |
R1/wR2 (all data) | 0.0268, 0.0640 | 0.1684, 0.3611 | 0.1115, 0.2223 |
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Meng, L.; Zhao, L.; Guo, G.; Liu, X.; Liang, Z.; Xiu, J.; Zhou, X. Syntheses, Structures, and Characteristics of Three Metal Complexes Constructed Using Hexacarboxylic Acid. Molecules 2019, 24, 4431. https://doi.org/10.3390/molecules24244431
Meng L, Zhao L, Guo G, Liu X, Liang Z, Xiu J, Zhou X. Syntheses, Structures, and Characteristics of Three Metal Complexes Constructed Using Hexacarboxylic Acid. Molecules. 2019; 24(24):4431. https://doi.org/10.3390/molecules24244431
Chicago/Turabian StyleMeng, Lingshu, Lun Zhao, Guanlin Guo, Xin Liu, Zhijun Liang, Jian Xiu, and Xu Zhou. 2019. "Syntheses, Structures, and Characteristics of Three Metal Complexes Constructed Using Hexacarboxylic Acid" Molecules 24, no. 24: 4431. https://doi.org/10.3390/molecules24244431