Removal of Zinc from Aqueous Solutions Using Lamellar Double Hydroxide Materials Impregnated with Cyanex 272: Characterization and Sorption Studies
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Preparation of Sorbents
2.3. Preparation of Impregnated Sorbents
2.4. Characterization of Sorbents
2.5. Methods
2.5.1. Metal Sorption Procedure
2.5.2. Effect of Contact Time
2.5.3. Equilibrium Studies
3. Results and Discussion
3.1. Characterization of the Materials
3.1.1. X-Ray Diffraction Analyses (XRD)
3.1.2. Infrared Spectroscopy (FTIR)
3.1.3. Thermal–Gravimetric Analyses (TGA)
3.2. Sorption Studies
3.2.1. Effect of contact time
3.2.2. Fitting of the Kinetic Data
3.2.3. Equilibrium Studies
3.2.4. Fitting of the isotherm data
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample Availability: Samples of the sorbents: Zn2Al-CO3 and Zn2Al-CO3-cyanex272 are available from the authors. |
Material | a (Å) | c (Å) | d003 (Å) |
---|---|---|---|
Mg2Al-CO3 | 3.030 | 23.106 | 7.702 |
Zn2Al-CO3 | 3.043 | 23.517 | 7.839 |
Mg2Al-CO3-cyanex 272 | 3.004 | 48.000 | 15.99 |
Zn2Al-CO3-cyanex 272 | 3.055 | 49.950 | 16.65 |
Experimental | Pseudo-First Order | Pseudo-Second Order | Elovich | Intraparticular Diffusion | |||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Materials | qexp mg/g | k1 h−1 | qtheo1 mg/g | R2 | k2g/mg.h | qtheo2 mg/g | R2 | Β g/mg | Α mg/g.h | R2 | C mg/g | Kid mg/g.h1/2 | R2 |
Mg2Al-CO3 | 1.6 | 0.48 | 0.76 | 0.787 | 2.28 | 1.69 | 0.999 | 0.11 | 4.83 × 106 | 0.962 | 1.31 | 0.09 | 0.878 |
Mg2Al-CO3-cyanex 272 | 2.8 | 0.63 | 0.96 | 0.789 | 1.62 | 2.79 | 0.997 | 0.32 | 2343.68 | 0.737 | 1.96 | 0.22 | 0.564 |
Zn2Al-CO3 | 6.2 | 0.25 | 5.90 | 0.970 | 0.07 | 7.14 | 0.998 | 1.36 | 5.07 | 0.951 | 1.54 | 1.22 | 0.922 |
Zn2Al-CO3-cyanex 272 | 8.8 | 0.21 | 7.45 | 0.946 | 3 × 10−3 | 8.92 | 0.987 | 0.94 | 154.58 | 0.904 | 3.69 | 0.95 | 0.986 |
Materials | Linear Regression | Langmuir Model | Freundlich Model | |||||
---|---|---|---|---|---|---|---|---|
Kd | R2 | qmax(mg/g) | Kl (L.g−1) | R2 | n | KF (mg1−1/n .g−1.L1/n) | R2 | |
Zn2Al-CO3 | 0.277 | 0.998 | 67.17 | 0.0011 | 0.9978 | 1.3056 | 2.0848 | 0.9887 |
Zn2Al-CO3- cyanex272 | 0.318 | 0.990 | 268.82 | 0.0045 | 0.9900 | 1.5205 | 3.3229 | 0.9611 |
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Boudaoud, N.; Miloudi, H.; Bouazza, D.; Adjdir, M.; Tayeb, A.; Fortuny, A.; Demey, H.; Sastre, A.M. Removal of Zinc from Aqueous Solutions Using Lamellar Double Hydroxide Materials Impregnated with Cyanex 272: Characterization and Sorption Studies. Molecules 2020, 25, 1263. https://doi.org/10.3390/molecules25061263
Boudaoud N, Miloudi H, Bouazza D, Adjdir M, Tayeb A, Fortuny A, Demey H, Sastre AM. Removal of Zinc from Aqueous Solutions Using Lamellar Double Hydroxide Materials Impregnated with Cyanex 272: Characterization and Sorption Studies. Molecules. 2020; 25(6):1263. https://doi.org/10.3390/molecules25061263
Chicago/Turabian StyleBoudaoud, Nacera, Hafida Miloudi, Djamila Bouazza, Mehdi Adjdir, Abdelkader Tayeb, Agustin Fortuny, Hary Demey, and Ana Maria Sastre. 2020. "Removal of Zinc from Aqueous Solutions Using Lamellar Double Hydroxide Materials Impregnated with Cyanex 272: Characterization and Sorption Studies" Molecules 25, no. 6: 1263. https://doi.org/10.3390/molecules25061263