The Identification of New Triterpenoids in Eucalyptus globulus Wood
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. Sampling
3.2. Extraction
3.3. Analysis
3.4. Chemicals
4. Conclusions
Author Contributions
Funding
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
Appendix A
MW | [M-CH3]+ | [M-TMSOOCH]+ | [M-TMSO]+ | [M-TMSOH]+ | [M-TMSOH-TMSOOCH]+ | [TMSOCH2]+ | |||
---|---|---|---|---|---|---|---|---|---|
Skeleton | TMS | [TMS]+ | [M-15]+ | [M-118]+ | [M-89]+ | [M-90]+ | [M-118-90]+ | ||
Hederagenin (1) | Oleane | 688 | 73 | 673 | 570 | 599 | 598 | 480 | 103 |
23-hydroxybetulinic acid (2) | Lupane | 688 | 73 | 673 | 570 | 599 | 598 | 480 | 103 |
Maslinic acid (3) | Oleane | 688 | 73 | 673 | 570 | 599 | 598 | 480 | 103 |
Corosolic acid (4) | Ursane | 688 | 73 | 673 | 570 | 599 | 598 | 480 | 103 |
Arjunolic acid (5) | Oleane | 776 | 73 | 761 | 658 | 687 | 686 | 568 | 103 |
Asiatic acid (6) | Ursane | 776 | 73 | 761 | 658 | 687 | 686 | 568 | 103 |
Caulophyllogenin (7) | Oleane | 776 | 73 | 761 | 658 | 687 | 686 | 568 | 103 |
Madecassic acid (8) | Ursane | 864 | 73 | 849 | 746 | 775 | 774 | 656 | 103 |
Skeleton | [M-ABC*]+ | [M-DEC*]+ Do not appear | [M-DEC*-TMSOH*y]+. | [M-ABC* -TMSOOCH]+ | [M-TMSOH-TMSOOCH]+ | [M-ABC*-70 mu]+ | [CH2OTMS]+ | |
---|---|---|---|---|---|---|---|---|
Hederagenin (1) | Oleane | 320+. | 368+. | 278+. (when y = 1) | 203+ | 480+. | 133+ | 103+ |
Maslinic acid (3) | Oleane | 320+. | 368+. | 277+ (when + H) | 203+ | 481+ | 133+ | 103+ |
Corosolic acid (4) | Ursane | 320+. | 368+. | 277+ (when + H) | 203+ | 480+. | 133+ | 103+ |
Arjunolic acid (5) | Oleane | 320+. | 456+. | 276+. (when y = 2) | 203+ | 568+. | - | 103+ |
Asiatic acid (6) | Ursane | 320+. | 456+. | 276+. (when y = 2) | 203+ | - | - | 103+ |
Caulophyllogenin (7) | Oleane | 318+. | 456+. | 275+ (when y = 2) | 201+ | 568+. | 131+ | 103+ |
Madecassic acid (8) | Ursane | 320+. | 545+ | - | 203+ | 567+ | 133+ | 103+ |
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Compound | Skeleton | R1 | R2 | R3 | R4 | R5 | R6 | MW | MW TMS |
---|---|---|---|---|---|---|---|---|---|
Hederagenin (1) | A | H | CH2OTMS | CH3 | H | H | H | 472 | 688 |
(4α)-23-hydroxybetulinic acid (2) | B | H | CH2OTMS | - | - | - | - | 472 | 688 |
Maslinic acid (3) | A | OTMS | CH3 | CH3 | H | H | H | 472 | 688 |
Corosolic acid (4) | A | OTMS | CH3 | H | CH3 | H | H | 472 | 688 |
Arjunolic acid (5) | A | OTMS | CH2OTMS | CH3 | H | H | H | 488 | 776 |
Asiatic acid (6) | A | OTMS | CH2OTMS | H | CH3 | H | H | 488 | 776 |
Caulophyllogenin (7) | A | H | CH2OTMS | CH3 | H | OTMS | H | 488 | 776 |
Madecassic acid (8) | A | OTMS | CH2OTMS | H | CH3 | H | OTMS | 504 | 864 |
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Lourenço, A.; Marques, A.V.; Gominho, J. The Identification of New Triterpenoids in Eucalyptus globulus Wood. Molecules 2021, 26, 3495. https://doi.org/10.3390/molecules26123495
Lourenço A, Marques AV, Gominho J. The Identification of New Triterpenoids in Eucalyptus globulus Wood. Molecules. 2021; 26(12):3495. https://doi.org/10.3390/molecules26123495
Chicago/Turabian StyleLourenço, Ana, António Velez Marques, and Jorge Gominho. 2021. "The Identification of New Triterpenoids in Eucalyptus globulus Wood" Molecules 26, no. 12: 3495. https://doi.org/10.3390/molecules26123495