Study of the Synchrotron Photoionization Oxidation of Alpha-Angelica Lactone (AAL) Initiated by O(3P) at 298, 550, and 700 K
Abstract
:1. Introduction
2. Results and Discussion
2.1. Product Identification
2.2. Branching Fractions
2.3. Reaction Pathways for the Primary Products
3. Methods
Computational Methods
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Compound | m/z | 298 K | 550 K | 700 K |
---|---|---|---|---|
ketene | 42 | 47.2 ± 14.6 | 39.5 ± 13.4 | 39.7 ± 12.2 |
acetaldehyde | 44 | 5.6 ± 2.1 | 9.3 ± 4.2 | 15.9 ± 7.1 |
methyl vinyl ketone | 70 | 34.6 ± 12.6 | 26.7 ± 10.7 | 19.7 ± 7.6 |
methylglyoxal | 72 | 11.1 ± 3.9 | 7.4 ± 3.6 | 4.7 ± 2.2 |
dimethylglyoxal | 86 | - | 3.5 ± 1.4 | 3.4 ± 2.0 |
5-methyl-2,4-furandione | 114 | 2.2 ± 1.5 | 1.0 ± 0.5 | - |
Total (C balanced) | 101 ± 19.9 | 87.3 ± 18.1 | 83.4 ± 16.3 |
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Rezaei, G.; Meloni, G. Study of the Synchrotron Photoionization Oxidation of Alpha-Angelica Lactone (AAL) Initiated by O(3P) at 298, 550, and 700 K. Molecules 2021, 26, 4070. https://doi.org/10.3390/molecules26134070
Rezaei G, Meloni G. Study of the Synchrotron Photoionization Oxidation of Alpha-Angelica Lactone (AAL) Initiated by O(3P) at 298, 550, and 700 K. Molecules. 2021; 26(13):4070. https://doi.org/10.3390/molecules26134070
Chicago/Turabian StyleRezaei, Golbon, and Giovanni Meloni. 2021. "Study of the Synchrotron Photoionization Oxidation of Alpha-Angelica Lactone (AAL) Initiated by O(3P) at 298, 550, and 700 K" Molecules 26, no. 13: 4070. https://doi.org/10.3390/molecules26134070