Construction of a Luminescent Cadmium-Based Metal–Organic Framework for Highly Selective Discrimination of Ferric Ions
Abstract
:1. Introduction
2. Results and Discussion
2.1. Crystal Structure Description of {[Me2NH2]2[CdBPTC]·6H2O}n (CdBPTC)
2.2. Framework Stability
2.3. Luminescent and Sensing Properties
2.3.1. Fluorescence Detection of Metal Ions
2.3.2. Fluorescence-Sensing Mechanism of the CdBPTC Probe
3. Materials and Methods
3.1. Chemicals and Reagents
3.2. Apparatus
3.3. Synthesis of {[Me2NH2]2[CdBPTC]·6H2O}n
3.4. Determination of the Crystal Structures
3.5. Sensing Experiment
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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Compound | CdBPTC |
---|---|
Empirical formula | C16H6CdO8 |
Formula weight | 438.61 |
Temperature (K) | 100.15 |
Crystal system | Tetragonal |
Space group | I41cd |
a/Å | 20.07520 (10) |
c/Å | 36.7826 (3) |
Volume (Å3) | 14,823.89 (19) |
Z | 16 |
ρcalc (g·cm−3) | 0.786 |
μ (mm−1) | 4.897 |
F (000) | 3424.0 |
Independent reflections | 5869 [Rint = 0.0332] |
Data/restraints/parameters | 5869/25/215 |
Goodness of fit on F2 | 1.087 |
R1 [I ≥ 2σ(I)] a | 0.0399 |
wR2 [all data] b | 0.1365 |
Flack parameter | 0.478 (16) |
CCDC number | 2,112,156 |
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Xu, L.-L.; Zhang, Q.-F.; Wang, D.; Wu, G.-W.; Cai, H. Construction of a Luminescent Cadmium-Based Metal–Organic Framework for Highly Selective Discrimination of Ferric Ions. Molecules 2021, 26, 6847. https://doi.org/10.3390/molecules26226847
Xu L-L, Zhang Q-F, Wang D, Wu G-W, Cai H. Construction of a Luminescent Cadmium-Based Metal–Organic Framework for Highly Selective Discrimination of Ferric Ions. Molecules. 2021; 26(22):6847. https://doi.org/10.3390/molecules26226847
Chicago/Turabian StyleXu, Li-Li, Qiu-Feng Zhang, Dong Wang, Guang-Wei Wu, and Hong Cai. 2021. "Construction of a Luminescent Cadmium-Based Metal–Organic Framework for Highly Selective Discrimination of Ferric Ions" Molecules 26, no. 22: 6847. https://doi.org/10.3390/molecules26226847