Removal of Cu(II) Contamination from Aqueous Solution by Ethylenediamine@β-Zeolite Composite
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Characterization
2.3. Batch Experiments
3. Results and Discussion
3.1. Effect of pH on Cu(II) Removal
3.2. Removal Kinetics
3.3. Thermodynamic Estimation
3.4. Removal Isotherms
3.5. Removal Mechanism
3.6. Regeneration
3.7. Effect of Coexisting Ions
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Sample Availability
References
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pH | Sample | qe (mg/g) | Pseudo-First Order | Pseudo-Second Order | ||
---|---|---|---|---|---|---|
qe1(mg/g) | R12 | qe2(mg/g) | R22 | |||
5.10 | β-zeolite | 0.00272 | 0.001939 | 0.8259 | 0.002636 | 0.9992 |
5.10 | EDA@β-zeolite | 0.00454 | 0.000694 | 0.8711 | 0.004515 | 0.9999 |
6.10 | β-zeolite | 0.00645 | 0.001462 | 0.7267 | 0.006412 | 0.9999 |
6.10 | EDA@β-zeolite | 0.00821 | 0.000726 | 0.8992 | 0.008203 | 0.9999 |
pH | Sample | Parameters | R12 | |
---|---|---|---|---|
5.10 | β-zeolite | Ka1 = 0.0010 | Ca1 = 0.0001 | 0.9432 |
Ka2 = 0.0004 | Ca2 = 0.0005 | 0.9748 | ||
Ka3 = 2 × 10−5 | Ca3 = 0.0024 | 0.7126 | ||
5.10 | EDA@β-zeolite | Kb1 = 0.0007 | Cb1 = 0.0042 | 0.9893 |
Kb2 = 0.0001 | Cb2 = 0.0050 | 0.9958 | ||
Kb3 = 2 × 10−5 | Cb3 = 0.0056 | 0.4200 | ||
6.10 | β-zeolite | Kc1 = 0.0012 | Cc1 = 0.0040 | 0.9605 |
Kc2 = 0.0002 | Cc2 = 0.0053 | 0.9378 | ||
Kc3 = 1 × 10−5 | Cc3 = 0.0062 | 0.5071 | ||
6.10 | EDA@β-zeolite | Kd1 = 0.0004 | Cd1 = 0.0069 | 0.9786 |
Kd2 = 0.0001 | Cd2 = 0.0074 | 0.9980 | ||
Kd3 = 3 × 10−5 | Cd3 = 0.0079 | 0.6320 |
pH | T (K) | Sample | Ln Kd = A Ce + B | Thermodynamic Data | ||||
---|---|---|---|---|---|---|---|---|
A | B | R | ΔG0 (kJ/mol) | ΔH0 (kJ/mol) | ΔS0 (J/mol·K) | |||
5.10 | 298 | β-zeolite | −2194.71 | 2.92 | 0.9924 | −1.0716 | 0.1994 | 4.2649 |
5.10 | 298 | EDA@β-zeolite | −3944.03 | 3.39 | 0.9465 | −1.2208 | 0.3622 | 5.3123 |
5.10 | 318 | β-zeolite | −3233.53 | 3.18 | 0.9501 | −1.1569 | 0.1994 | |
5.10 | 318 | EDA@β-zeolite | −5381.72 | 3.77 | 0.9122 | −1.3271 | 0.3357 | |
6.10 | 298 | β-zeolite | −1885.44 | 3.21 | 0.9850 | −1.1663 | 0.3338 | 5.0339 |
6.10 | 298 | EDA@β-zeolite | −3418.45 | 3.58 | 0.9272 | −1.2754 | 0.4147 | 5.6715 |
6.10 | 318 | β-zeolite | −4138.52 | 3.55 | 0.9782 | −1.2670 | 0.3086 | |
6.10 | 318 | EDA@β-zeolite | −5032.34 | 4.01 | 0.9091 | −1.3888 | 0.3864 |
Element | β-Zeolite | Cu(II)-Loaded β-Zeolite (pH = 5.10) | Cu(II)-Loaded β-Zeolite (pH = 6.10) | Assignments | ||||||
---|---|---|---|---|---|---|---|---|---|---|
BE (eV) | FWHM | Area (%) | BE (eV) | FWHM | Area (%) | BE (eV) | FWHM | Area (%) | ||
O 1S | 532.10 | 1.14 | 37.26 | 532.15 | 1.14 | 37.75 | 532.16 | 1.14 | 46.42 | Si-O-Al |
532.55 | 1.01 | 28.83 | 532.58 | 1.01 | 38.37 | 532.62 | 1.01 | 42.43 | -OH | |
533.01 | 1.03 | 33.91 | 533.05 | 1.03 | 42.14 | 533.07 | 1.03 | 11.15 | water |
Element | EDA@β-zeolite | Cu(II)-Loaded EDA@β-Zeolite (pH = 5.10) | Cu(II)-Loaded EDA@β-Zeolite (pH = 6.10) | Assignments | ||||||
---|---|---|---|---|---|---|---|---|---|---|
BE(eV) | FWHM | Area(%) | BE(eV) | FWHM | Area(%) | BE(eV) | FWHM | Area(%) | ||
O 1S | 531.54 | 1.14 | 32.94 | 531.86 | 1.14 | 35.47 | 531.97 | 1.14 | 35.88 | Si-O-Al |
532.05 | 1.01 | 37.86 | 532.27 | 1.01 | 24.72 | 532.48 | 1.01 | 38.31 | -OH | |
532.58 | 1.03 | 29.20 | 532.74 | 1.03 | 39.81 | 532.91 | 1.03 | 25.81 | water | |
N 1S | 399.66 | 1.72 | 23.42 | 399.99 | 1.72 | 67.45 | 400.18 | 1.72 | 72.35 | -NH |
401.79 | 2.56 | 76.58 | 401.87 | 2.56 | 32.55 | 401.91 | 2.56 | 27.65 | -NH2 |
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Liu, P.; Ruan, H.; Li, T.; Chen, J.; Ma, F.; Pan, D.; Wu, W. Removal of Cu(II) Contamination from Aqueous Solution by Ethylenediamine@β-Zeolite Composite. Molecules 2021, 26, 978. https://doi.org/10.3390/molecules26040978
Liu P, Ruan H, Li T, Chen J, Ma F, Pan D, Wu W. Removal of Cu(II) Contamination from Aqueous Solution by Ethylenediamine@β-Zeolite Composite. Molecules. 2021; 26(4):978. https://doi.org/10.3390/molecules26040978
Chicago/Turabian StyleLiu, Peng, Hui Ruan, Tiantian Li, Jiaqi Chen, Fuqiu Ma, Duoqiang Pan, and Wangsuo Wu. 2021. "Removal of Cu(II) Contamination from Aqueous Solution by Ethylenediamine@β-Zeolite Composite" Molecules 26, no. 4: 978. https://doi.org/10.3390/molecules26040978