Metal-Organic Frameworks as Versatile Heterogeneous Solid Catalysts for Henry Reactions
Abstract
:1. Introduction
2. Metal Nodes as Active Sites
2.1. Co Metal Nodes as Active Sites
2.2. Cd Metal Nodes as Active Sites
2.3. Zn Metal Nodes as Active Sites
2.4. Cu Metal Nodes as Active Sites
2.5. Sm Metal Nodes as Active Sites
3. MOFs as Organocatalysts for the Henry Reaction
3.1. MOFs with Primary Amine Sites
3.2. MOFs with Secondary Amine Sites
3.3. MOFs with Amide Sites
3.4. MOFs with Urea Sites
4. Conclusions and Summary
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
Sample Availability
References
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MOF | Active Site | T (°C), Solvent | TON | Ref. |
---|---|---|---|---|
Co2(bdda)1.5(OAc)1·5H2O | Co | 70, water | 27.7 | 30 |
[Cd2(Cu(salen))(DMF)3]·DMF·3H2O | Cd/Cu | 45, methanol | 70 | 31 |
Cd3(CuL)8·(DMF)6·(H2O)8·(NMe2)2 | Cd/Cu | 60, methanol | 86 | 32 |
{Cd2(Lglu)2(bpe)3(H2O)}·2H2O | Cd | RT, methanol a | 35.6 | 33 |
[Zn3(TCPB)2·2H2O]·2H2O·4DMF | Zn | 70, neat b | 8 | 34 |
[Zn2(hfipbb)2(4-bpdh)].(DMF)0.5 | Zn | 60, methanol | 32.3 | 35 |
[Cu3(pdtc)L2(H2O)3].2DMF.10H2O | Cu | 70, neat | 5.9 | 36 |
HKUST-1 | Cu | 100, toluene | 5.6 | 37 |
NbO type-Cu MOF | Cu | 50, neat | 13.4 | 38 |
Cu-BTC | Cu | 70, neat b | 4 | 39 |
HP-MOF | Cu | - | - | 40 |
HKUST-1@MMS | Cu | 75, water b | 18.2 | 41 |
MOF-MB II | Cu | RT, ethanol b | 19.8 | 42 |
[Sm(L1)2]n·1n(HCONH2)H·2n(HCONH2) | Sm | 70, water | 23.8 | 43 |
MIL-101-NH2 NiBDP-OH NH2-Tb-MOF | NH2 | 80, toluene | 9.4 | 44 |
OH | 100, 2-butanol | 2.0 | 46 | |
NH2 | 90, neat | 6.7 | 47 | |
MIL-101-NHR Cu-amide MOF | NHR | RT, toluene | 100 | 49 |
NHCOR | 75, water | 42 | 50 | |
Zn-MOF-DABCO Zn-amide MOF Cu-urea MOF UiO-67-urea | NHR | 60, neat | 48 | 51 |
NHCOR | 70, methanol | 32 | 53 | |
NHCONH | 60, methanol | 55 | 57 | |
NHCONH | RT, THF | 14 | 58 | |
UiO-68-urea | NHCONH | RT, THF | 18 | 59 |
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Cirujano, F.G.; Luque, R.; Dhakshinamoorthy, A. Metal-Organic Frameworks as Versatile Heterogeneous Solid Catalysts for Henry Reactions. Molecules 2021, 26, 1445. https://doi.org/10.3390/molecules26051445
Cirujano FG, Luque R, Dhakshinamoorthy A. Metal-Organic Frameworks as Versatile Heterogeneous Solid Catalysts for Henry Reactions. Molecules. 2021; 26(5):1445. https://doi.org/10.3390/molecules26051445
Chicago/Turabian StyleCirujano, Francisco G., Rafael Luque, and Amarajothi Dhakshinamoorthy. 2021. "Metal-Organic Frameworks as Versatile Heterogeneous Solid Catalysts for Henry Reactions" Molecules 26, no. 5: 1445. https://doi.org/10.3390/molecules26051445