Palladium Supported on Porous Organic Polymer as Heterogeneous and Recyclable Catalyst for Cross Coupling Reaction
Abstract
:1. Introduction
2. Results and Discussion
3. Experimental Section
3.1. Materials
3.2. Synthesis of Pd@AEPOP
3.3. General Procedure for Heck Reaction
3.4. General Procedure for Recycling Experiment
3.5. General Procedure for Suzuki Reaction
3.6. General Procedure for Reduction of Nitroarene
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Entry | Base | Solvent | Temp. | Time (h) | Yield b |
---|---|---|---|---|---|
1 | K2CO3 | DMSO | 90 | 5 | Trace |
2 | K2CO3 | DMF | 90 | 5 | 36 |
3 | K2CO3 | H2O | 90 | 5 | 10 |
4 | K2CO3 | DMF | 90 | 5 | 40 |
5 | Et3N | DMF | 90 | 5 | 55 |
6 | Cs2CO3 | DMF | 90 | 5 | Trace |
7 | Et3N | DMF | 100 | 5 | 63 |
8 | Et3N | DMF | 110 | 5 | 71 |
9 | Et3N | DMF | 120 | 5 | 75 |
10 | Et3N | DMF | 120 | 10 | 95 |
Entry | ArI | R | Yield b |
---|---|---|---|
1 | 4-Me-Ph | Ph | 95 |
2 | Ph | Ph | 99 |
3 | 4-tBu-Ph | Ph | 93 |
4 | 3-Cl-Ph | Ph | 98 |
5 | Ph | COOEt | 98 |
6 | 3-Cl-Ph | COOEt | 99 |
7 | 4-Cl-Ph | COOEt | 99 |
8 | 2-Me-Ph | COOEt | 92 |
9 | 3-Me-Ph | COOEt | 98 |
10 | 4-Me-Ph | COOEt | 99 |
11 | 4-MeO-Ph | COOEt | 99 |
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Shi, G.; Dong, Z. Palladium Supported on Porous Organic Polymer as Heterogeneous and Recyclable Catalyst for Cross Coupling Reaction. Molecules 2022, 27, 4777. https://doi.org/10.3390/molecules27154777
Shi G, Dong Z. Palladium Supported on Porous Organic Polymer as Heterogeneous and Recyclable Catalyst for Cross Coupling Reaction. Molecules. 2022; 27(15):4777. https://doi.org/10.3390/molecules27154777
Chicago/Turabian StyleShi, Guanying, and Zhenhua Dong. 2022. "Palladium Supported on Porous Organic Polymer as Heterogeneous and Recyclable Catalyst for Cross Coupling Reaction" Molecules 27, no. 15: 4777. https://doi.org/10.3390/molecules27154777