Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller
Abstract
:1. Introduction
2. Experimental
2.1. Materials and Chemicals
2.2. Preparation of Poly(o-anisidine)
2.3. Preparation of MMT/POA Clay Nanocomposite
3. Result and Discussion
3.1. FTIR Spectroscopy Studies
3.2. UV–Visible Absorption of POA and MMT/POA Clay Nanocomposites
3.3. Scanning-Electron-Microscopy (SEM) Analysis
3.4. TGA/DSC Evaluation of Pure POA and MMT/POA Clay Nanocomposites
3.5. Horizontal Burning Test
3.6. Cone-calorimeter Test
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sr. No. | Monomer Poly(o-anisidine) | APS (Ammonium Persulphate) | DDPA | MMT Clay | % of Filler in Composite |
---|---|---|---|---|---|
1 | 0.0255 g | 0.456 g | 0.002555 g | 0 g | 0% |
2 | 0.0255 g | 0.456 g | 0.002555 g | 0.00051 g | 2% |
3 | 0.0255 g | 0.456 g | 0.002555 g | 0.000102 g | 4% |
4 | 0.0255 g | 0.456 g | 0.002555 g | 0.00153 g | 6% |
5 | 0.0255 g | 0.456 g | 0.002555 g | 0.00204 g | 8% |
6 | 0.0255 g | 0.456 g | 0.002555 g | 0.00306 g | 12% |
Nanocomposite | POA | 2% | 4% | 6% | 8% | 12% |
---|---|---|---|---|---|---|
Burning Time/73 mm | 16 | 25 | 33 | 47 | 58 | 75 |
HBR (mm/s) | 24 | 22 | 19 | 15 | 11 | 7 |
Samples | Effective Heat of Combustion, MJ kg−1 | Time to Ignition, ting/s | Flame-Out Time, s | Mean CO2 Yield, kg kg−1 | Average Mass Loss Rate (MLR), avg/g s−1 m−2 | Total Heat Release (THR), MJ m−2 |
---|---|---|---|---|---|---|
POA | 27.4 | 11 | 486 | 2.3 | 25.4 | 131.5 |
2% MMT/POA | 29.6 | 10 | 541 | 2.3 | 29.5 | 134.6 |
4% MMT/POA | 31.8 | 17 | 606 | 2.4 | 35.6 | 137.4 |
6% MMT/POA | 34.2 | 24 | 649 | 2.4 | 39.8 | 140.7 |
8% MMT/POA | 33.5 | 19 | 681 | 2.3 | 28.4 | 139.4 |
12% MMT/POA | 32.7 | 13 | 723 | 2.2 | 17.6 | 136.7 |
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Ahmad, M.N.; Nadeem, S.; Javed, M.; Iqbal, S.; Hassan, S.u.; Aljazzar, S.O.; Elkaeed, E.B.; Pashameah, R.A.; Alzahrani, E.; Farouk, A.-E.; et al. Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller. Molecules 2022, 27, 5477. https://doi.org/10.3390/molecules27175477
Ahmad MN, Nadeem S, Javed M, Iqbal S, Hassan Su, Aljazzar SO, Elkaeed EB, Pashameah RA, Alzahrani E, Farouk A-E, et al. Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller. Molecules. 2022; 27(17):5477. https://doi.org/10.3390/molecules27175477
Chicago/Turabian StyleAhmad, Mirza Nadeem, Sohail Nadeem, Mohsin Javed, Shahid Iqbal, Sadaf ul Hassan, Samar O. Aljazzar, Eslam B. Elkaeed, Rami Adel Pashameah, Eman Alzahrani, Abd-ElAziem Farouk, and et al. 2022. "Improving the Thermal Behavior and Flame-Retardant Properties of Poly(o-anisidine)/MMT Nanocomposites Incorporated with Poly(o-anisidine) and Clay Nanofiller" Molecules 27, no. 17: 5477. https://doi.org/10.3390/molecules27175477