Lewis Acid-Induced Dinitrogen Cleavage in an Anionic Side-on End-on Bound Dinitrogen Diniobium Hydride Complex
Abstract
:1. Introduction
2. Results
2.1. Reaction with 9-BBN
2.2. Reactions with ZnMe2 and AlMe3
3. Conclusions
4. Materials and Methods
4.1. General Information
4.2. Synthesis of 2-Na
4.3. Synthesis of 2-Na-15N
4.4. Synthesis of 4
4.5. Reaction of 2-Na with 9-BBN
4.6. Reaction of 2-K-15N with 9-BBN
4.7. Reaction of 3-Na with ZnMe2
4.8. Synthesis of 5
4.9. Reaction of 2-Na with AlMe3
4.10. Reaction of 2-K-15N with AlMe3
4.11. X-ray Crystallography
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
Sample Availability
References
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Suzuki, N.; Ishida, Y.; Kawaguchi, H. Lewis Acid-Induced Dinitrogen Cleavage in an Anionic Side-on End-on Bound Dinitrogen Diniobium Hydride Complex. Molecules 2022, 27, 5553. https://doi.org/10.3390/molecules27175553
Suzuki N, Ishida Y, Kawaguchi H. Lewis Acid-Induced Dinitrogen Cleavage in an Anionic Side-on End-on Bound Dinitrogen Diniobium Hydride Complex. Molecules. 2022; 27(17):5553. https://doi.org/10.3390/molecules27175553
Chicago/Turabian StyleSuzuki, Naofumi, Yutaka Ishida, and Hiroyuki Kawaguchi. 2022. "Lewis Acid-Induced Dinitrogen Cleavage in an Anionic Side-on End-on Bound Dinitrogen Diniobium Hydride Complex" Molecules 27, no. 17: 5553. https://doi.org/10.3390/molecules27175553