Octahedral Rhenium Cluster Complexes with 1,2-Bis(4-pyridyl)ethylene and 1,3-Bis(4-pyridyl)propane as Apical Ligands
Abstract
:1. Introduction
2. Experimental
2.1. Materials and Methods
2.2. Preparation of Trans-[Re6S8(bpe)4Cl2] (1)
2.3. Preparation of Trans-[Re6S8(bpe)4Br2] (2)
2.4. Preparation of Trans-[Re6Se8(bpe)4Cl2] (3)
2.5. Preparation of Trans-[Re6Se8(bpe)4Br2] (4)
2.6. Preparation of Trans-[Re6S8(bpp)4Cl2] (5)
2.7. Preparation of Trans-[Re6S8(bpp)4Br2] (6)
2.8. Preparation of Trans-[Re6Se8(bpp)4Cl2] (7)
2.9. Preparation of Trans-[Re6Se8(bpp)4Br2] (8)
2.10. The X-ray Diffraction (XRD) Analysis
2.11. Calculation Details
3. Results and Discussion
3.1. Synthesis
3.2. Crystal Structures
3.3. Luminescent Properties
3.4. DFT Calculations
3.5. Electrochemistry
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Sample Availability
References
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λem, nm | Φem | τem, μs | |
---|---|---|---|
[Re6S8(bpe)4Cl2] (1) | 710 | <0.005 | 0.57 |
[Re6S8(bpe)4Br2] (2) | 690 | <0.005 | 0.44 |
[Re6Se8(bpe)4Cl2] (3) | 705 | <0.005 | n/a |
[Re6Se8(bpe)4Br2] (4) | 685 | <0.005 | n/a |
[Re6S8(bpp)4Cl2] (5) | 695 (solid) 695 (solution) | 0.04 (solid) 0.05 (solution) | 6.38 (solid) 6.80 (solution) |
[Re6S8(bpp)4Br2] (6) | 685 (solid) 682 (solution) | 0.01 (solid) 0.02 (solution) | 2.30 (solid) 7.10 (solution) |
[Re6Se8(bpp)4Cl2] (7) | 690 (solid) 692 (solution) | 0.02 (solid) 0.02 (solution) | 4.54 (solid) 4.71 (solution) |
[Re6Se8(bpp)4Br2] (8) | 685 (solid) 685 (solution) | 0.005 (solid) 0.02 (solution) | 3.48 (solid) n/a (solution) |
[Re6S8(phpy)4Cl2] | 708 | 0.028 | 4.3 |
[Re6S8(phpy)4Br2] | 715 | 0.013 | 4.5 |
[Re6Se8(phpy)4Cl2] | 708 | 0.015 | 3.8 |
[Re6Se8(phpy)4Br2] | 718 | 0.013 | 4.0 |
[Re6S8(bpy)4Cl2] | 725 | <0.005 | n/a |
[Re6S8(bpy)4Br2] | 730 | <0.005 | n/a |
[Re6Se8(bpy)4Cl2] | 725 | 0.02 | n/a |
[Re6Se8(bpy)4Br2] | 730 | 0.01 | n/a |
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Ulantikov, A.A.; Brylev, K.A.; Sukhikh, T.S.; Mironov, Y.V.; Muravieva, V.K.; Gayfulin, Y.M. Octahedral Rhenium Cluster Complexes with 1,2-Bis(4-pyridyl)ethylene and 1,3-Bis(4-pyridyl)propane as Apical Ligands. Molecules 2022, 27, 7874. https://doi.org/10.3390/molecules27227874
Ulantikov AA, Brylev KA, Sukhikh TS, Mironov YV, Muravieva VK, Gayfulin YM. Octahedral Rhenium Cluster Complexes with 1,2-Bis(4-pyridyl)ethylene and 1,3-Bis(4-pyridyl)propane as Apical Ligands. Molecules. 2022; 27(22):7874. https://doi.org/10.3390/molecules27227874
Chicago/Turabian StyleUlantikov, Anton A., Konstantin A. Brylev, Taisiya S. Sukhikh, Yuri V. Mironov, Viktoria K. Muravieva, and Yakov M. Gayfulin. 2022. "Octahedral Rhenium Cluster Complexes with 1,2-Bis(4-pyridyl)ethylene and 1,3-Bis(4-pyridyl)propane as Apical Ligands" Molecules 27, no. 22: 7874. https://doi.org/10.3390/molecules27227874