Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Tellurides via SH2 Reaction of Aryl Radicals on Tellurium
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. General Information
3.2. General Procedure for Synthesis of Diaryl Tellurides from Arylhydrazine Hydrochlorides and Diaryl Ditellurides under Air
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Sample Availability
References
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Entry | Solvent | Yield of 3a (%) a |
---|---|---|
1 | MeOH | 52 |
2 b | MeOH | 54 |
3 | iPrOH | 58 |
4 | CH3CN | 57 |
5 | AcOEt | 61 |
6 | 1,4-Dioxane | 54 |
7 | Toluene | 57 |
8 | Benzene | 65 |
9 c | Benzene | 72 |
10 d | Benzene | 74 (66) |
11 e | Benzene | 67 |
12 f | Benzene | 56 |
13 d,g | Benzene | 27 |
Entry | Arylhydrazine•HCl 1 | Ditelluride 2 | Product 3 | Yield (%) a | |
---|---|---|---|---|---|
1 | | | | 3a | 74 (66) |
2 | | | | 3b | (42) |
3 | | | | 3c | 37 |
4 | | | | 3d | 52 (41) |
5 | | | | 3e | 52 b (40) |
6 | | | | 3f | 42 (36) |
7 | | | | 3g | 97 (87) |
8 | | | | 3h | 100 (75) |
9 | | | | 3i | 82 (75) |
10 | | | | 3j | 77 (71) |
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Yamamoto, Y.; Sato, F.; Chen, Q.; Kodama, S.; Nomoto, A.; Ogawa, A. Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Tellurides via SH2 Reaction of Aryl Radicals on Tellurium. Molecules 2022, 27, 809. https://doi.org/10.3390/molecules27030809
Yamamoto Y, Sato F, Chen Q, Kodama S, Nomoto A, Ogawa A. Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Tellurides via SH2 Reaction of Aryl Radicals on Tellurium. Molecules. 2022; 27(3):809. https://doi.org/10.3390/molecules27030809
Chicago/Turabian StyleYamamoto, Yuki, Fumiya Sato, Qiqi Chen, Shintaro Kodama, Akihiro Nomoto, and Akiya Ogawa. 2022. "Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Tellurides via SH2 Reaction of Aryl Radicals on Tellurium" Molecules 27, no. 3: 809. https://doi.org/10.3390/molecules27030809