3DG Functionalized Magnetic Solid Phase Extraction Materials for the Efficient Enrichment of Hexamethylenetetramine in Vermicelli
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterizations
2.2. Study of Adsorption Properties
2.3. Validation of Method
2.4. Analysis of the Real Samples
3. Materials and Methods
3.1. Reagents
3.2. Apparatus
3.3. Preparation of Fe3O4@3DG@VTMOS@TMA
3.4. Adsorption Experiments
3.5. MSPE-HPLC Analysis of HMT in Vermicelli Samples
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Sample Availability
References
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Kinetic Model | Adsorption Equation | R2 | Qe (mg/g) |
---|---|---|---|
pseudo-first-order | 0.4693 | 37.75 | |
pseudo-second-order | 0.9982 | 47.76 |
ΔHθ | ΔSθ | ΔGθ (KJ/mol) | R2 | ||
---|---|---|---|---|---|
(KJ/mol) | (J/mol·K) | 293.15 K | 303.15 K | 313.15 K | |
18.79 | 90.03 | −8.80 | −9.38 | −10.68 | 0.9972 |
Temperature (K) | Adsorption Isotherm | |||
---|---|---|---|---|
Freundlich Isotherm Parameters | ||||
Regression Equations | Qmax (mg/g) | KL | R2 | |
293.15 | 1/Qe = 0.02520/Ce + 0.006767 | 147.78 | 0.27 | 0.9942 |
303.15 | 1/Qe = 0.02026/Ce + 0.006184 | 161.71 | 0.31 | 0.9903 |
313.15 | 1/Qe = 0.01602/Ce + 0.005773 | 173.22 | 0.36 | 0.9891 |
Freundlich Isotherm Parameters | ||||
Regression Equations | KF (mg/g) | n | R2 | |
293.15 | lnQe = 0.7794lnCe + 3.3809 | 29.40 | 1.28 | 0.9595 |
303.15 | lnQe = 0.7999lnCe + 3.5967 | 36.48 | 1.25 | 0.9606 |
313.15 | lnQe = 0.8019lnCe + 3.8060 | 44.97 | 1.25 | 0.9654 |
Samples | Spiked Level | |||||
---|---|---|---|---|---|---|
Vermicelli | 8 μg/g | 20 μg/g | 40 μg/g | |||
Recovery (%) | RSD (%) | Recovery (%) | RSD (%) | Recovery (%) | RSD (%) | |
1 | 89.46 | 1.95 | 85.93 | 2.07 | 91.42 | 0.70 |
2 | 87.44 | 1.09 | 86.43 | 1.15 | 92.69 | 0.20 |
3 | 86.24 | 1.64 | 83.24 | 0.56 | 91.19 | 0.43 |
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Liu, M.; Zhu, C.; Li, X.; Wang, F. 3DG Functionalized Magnetic Solid Phase Extraction Materials for the Efficient Enrichment of Hexamethylenetetramine in Vermicelli. Molecules 2022, 27, 1548. https://doi.org/10.3390/molecules27051548
Liu M, Zhu C, Li X, Wang F. 3DG Functionalized Magnetic Solid Phase Extraction Materials for the Efficient Enrichment of Hexamethylenetetramine in Vermicelli. Molecules. 2022; 27(5):1548. https://doi.org/10.3390/molecules27051548
Chicago/Turabian StyleLiu, Min, Chen Zhu, Xiaoyan Li, and Fang Wang. 2022. "3DG Functionalized Magnetic Solid Phase Extraction Materials for the Efficient Enrichment of Hexamethylenetetramine in Vermicelli" Molecules 27, no. 5: 1548. https://doi.org/10.3390/molecules27051548