Synthesis and Performance Analysis of Green Water and Oil-Repellent Finishing Agent with Di-Short Fluorocarbon Chain
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis of Finishing Agent Fluorine-Containing Polymer with Short Chain
2.1.1. Synthesis of Intermediate 2,3-Bisoctafluoropentyloxy-1-propanol (OFPA)
2.1.2. Synthesis of Monomer 2,3-Bisoctafluoropentyloxy-1-acrylate (OFAE)
2.1.3. Fourier Transform Infrared Spectra Analysis of Water-Repellent Fabric Finishing Agent (OFAE-SA-BA)
2.2. XPS Analysis
2.3. Gel Permeation Chromatography (GPC) Analysis
2.4. Thermal Degradation Property
2.5. Particle Size and Stability of Fabric Finishing Agent
2.6. Surface Morphology of Cotton Fibers
2.7. Evaluation of Hydrophobicity Property
2.8. Durability of Water-Repellency
2.9. Whiteness
3. Materials and Methods
3.1. Materials
3.2. Synthesis of Finishing Agent Fluorine-Containing Polymer with Short Chains
3.2.1. Synthesis of Intermediate 2,3-Bisoctafluoropentyloxy-1-propanol (OFPA)
3.2.2. Synthesis of Monomer 2,3-Bisoctafluoropentyloxy-1-acrylate (OFAE)
3.2.3. Synthesis of Water- and Oil-Repellent Fabric Finishing Agent Octafluoropentyloxy Polyacrylate (OFAE-SA-BA)
3.3. Treatment of Cotton Fabrics
3.4. Characterization
3.4.1. NMR Spectroscopy
3.4.2. Fourier Transform Infrared Spectra (FT-IR) Analysis
3.4.3. Mass Spectrum Analysis
3.4.4. Particle Size Analysis
3.4.5. X-ray Photoelectron Spectroscopy (XPS)
3.4.6. Gel Permeation Chromatography (GPC)
3.4.7. Thermogravimetry Analysis (TGA)
3.4.8. Scanning Electron Microscope (SEM) Analysis
3.4.9. Hydrophobicity Test
3.4.10. Whiteness Test
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Samples | Atomic (%) | ||
---|---|---|---|
C | O | F | |
Pristine fabric | 73.47 | 25.67 | — |
Treated fabric | 66.27 | 13.48 | 20.26 |
Sample | Mn | Mw | PDI (Mw/Mn) |
---|---|---|---|
OFAE-SA-BA | 345,246 | 363,618 | 1.05 |
Washing Times | Contact Angle/° | Moisture-Resistance Rating | Oil-Repellency Rating |
---|---|---|---|
0 | 156.7 ± 2.57 | 4 | 4 |
5 | 148.9 ± 2.02 | 4 | 4 |
10 | 145.2 ± 0.98 | 4 | 4 |
15 | 143.1 ± 1.87 | 4 | 3 |
20 | 140.4 ± 1.23 | 3 | 3 |
25 | 139.9 ± 0.88 | 3 | 3 |
30 | 139.8 ± 1.02 | 3 | 3 |
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Li, Y.; Luo, Y.; Wang, Q.; Zou, W.; Zheng, W.; Ma, X.; Yang, H. Synthesis and Performance Analysis of Green Water and Oil-Repellent Finishing Agent with Di-Short Fluorocarbon Chain. Molecules 2023, 28, 3369. https://doi.org/10.3390/molecules28083369
Li Y, Luo Y, Wang Q, Zou W, Zheng W, Ma X, Yang H. Synthesis and Performance Analysis of Green Water and Oil-Repellent Finishing Agent with Di-Short Fluorocarbon Chain. Molecules. 2023; 28(8):3369. https://doi.org/10.3390/molecules28083369
Chicago/Turabian StyleLi, Yanli, Yi Luo, Qinqin Wang, Wei Zou, Wenjiang Zheng, Xiaoyan Ma, and Hu Yang. 2023. "Synthesis and Performance Analysis of Green Water and Oil-Repellent Finishing Agent with Di-Short Fluorocarbon Chain" Molecules 28, no. 8: 3369. https://doi.org/10.3390/molecules28083369