Research Progress on Propylene Preparation by Propane Dehydrogenation
Abstract
:1. Introduction
2. Catalysts for Anaerobic Dehydrogenation Reaction
2.1. Platinum-Based Catalyst
2.1.1. Improvement of Support
2.1.2. Effect of Additives
2.2. Cr-Based Catalyst
Modification of Supports
2.3. Introduction of Several Propane Anaerobic Dehydrogenation Industrialization Technologies
2.3.1. Catofin Process
2.3.2. Oleflex Process
3. Catalysts for Oxidative Dehydrogenation Reaction
3.1. Chromium-Based Catalysts
3.2. Vanadium-Based Catalysts
3.3. Gallium-Based Catalysts
4. The Process of Chemical Looping Oxidative Dehydrogenation
4.1. Monometallic Active Oxygen Carriers
4.2. Bimetallic or Polymetallic Composite Oxygen Carriers
5. Conclusions and Prospects
- (1)
- The current methods for propylene production are anaerobic and oxidative dehydrogenation. The anaerobic method has been used for many years, but is expensive, due to high equipment and catalyst costs. The oxidative dehydrogenation method is cheaper, but the extent of CO2 influence on the reaction is difficult to control at certain temperatures, and the reaction mechanism is still unclear, resulting in variable product yields.
- (2)
- In contrast, chemical looping oxidative dehydrogenation resolves the drawbacks of the previous methods. Lattice oxygen release can be controlled by appropriate bimetallic or polymetallic oxides, replacing molecular oxygen. This effectively controls the reaction rate of propane dehydrogenation to produce propylene, and improves the conversion of propane with high selectivity for propylene, compared to oxygen-free dehydrogenation and gas oxidant methods.
- (3)
- The future of chemical looping oxidative dehydrogenation for industrial applications requires the development of multi-component coupled composite oxygen carriers with high oxygen loading, extended cycle life, and high propylene yield.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Projects | Process Technology | |
---|---|---|
Catofin Process | Oleflex Process | |
Technology exporter | ABB Lummus | UOP |
Reactor type | Fixed Bed | Moving Bed |
Total number of reactors | 5 | 3~4 |
Catalyst | CrOx/Al2O3 | Pt-Sn/Al2O3 |
Cycle regeneration time | 15~30 min | 2~7 d |
Temperature/°C | 600–700 | 550~620 |
Pressure/Mpa | 0.3~0.5 | 2~3 |
Diluent | - | H2 |
Propane conversion | 48~65 | 80~88 |
Propylene selectivity | 25 | 89~91 |
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Zuo, C.; Su, Q. Research Progress on Propylene Preparation by Propane Dehydrogenation. Molecules 2023, 28, 3594. https://doi.org/10.3390/molecules28083594
Zuo C, Su Q. Research Progress on Propylene Preparation by Propane Dehydrogenation. Molecules. 2023; 28(8):3594. https://doi.org/10.3390/molecules28083594
Chicago/Turabian StyleZuo, Cheng, and Qian Su. 2023. "Research Progress on Propylene Preparation by Propane Dehydrogenation" Molecules 28, no. 8: 3594. https://doi.org/10.3390/molecules28083594