Biodegradable Acid-Based Fe2MnO4 Nanoparticles for Water Remediation
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization
2.2. Adsorption Analysis
2.2.1. Effect of the Amount of CA/MF-NC on the RE (%) for MB Dye
2.2.2. Effect of Time on the RE (%) of CA/MF-NC for MB Dye
2.2.3. Effect of pH on the RE (%) of CA/MF-NC for MB Dye
2.2.4. Effect of MB Concentration on the RE (%) of CA/MF-NC for MB Dye
2.2.5. Effect of Temperature on the RE (%) of CA/MF-NC for MB Dye and Associated Thermodynamics
2.2.6. Adsorption Isotherm Analysis
Langmuir Isotherm
Freundlich Isotherm
2.2.7. Reusability Testing
2.2.8. Performance Evaluation and Comparative Analysis
3. Chemicals and Preparation
3.1. Chemicals
3.2. Synthesis of CA/MF-NC
3.3. Development of the MB Stock Solution
3.4. Instrumentation and Characterization
3.5. Adsorption Analysis
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Order | Temperature, (K) | ∆G° | ∆H° | ∆S° |
---|---|---|---|---|
1. | 303 | −9.838 | −90.288 | −0.265 |
2. | 313 | −7.251 | ||
3. | 323 | −4.529 |
Order | Temperature, (K) | Langmuir Isotherm | Freundlich Isotherm | |||||
---|---|---|---|---|---|---|---|---|
Qmax, (mg/g) | β (L/mg) | RL | R2 | KF (mg/g) (L/mg)1/n | N | R2 | ||
1. | 303 | 18.587 | 0.895 | 0.100 | 0.992 | 9.939 | 4.135 | 0.985 |
2. | 313 | 14.124 | 1.407 | 0.066 | 0.997 | 7.133 | 4.370 | 0.935 |
3. | 323 | 13.140 | 0.746 | 0.118 | 0.998 | 5.830 | 3.976 | 0.933 |
Order | Temperature, °C | Reuse Cycle | ||||
---|---|---|---|---|---|---|
First | Second | Third | Forth | Fifth | ||
1. | 100 | 84 | 73 | 62 | 56 | 43 |
2. | 200 | 90 | 77 | 66 | 59 | 48 |
3. | 300 | 86 | 71 | 61 | 54 | 47 |
4. | 400 | 78 | 64 | 56 | 50 | 43 |
Order | Adsorbent | Adsorbent Dose (g/L) | Contact Time (min) | Solution pH | Temperature (°C) | Initial Concentration (mg/L) | Equilibrium Adsorption Capacity (mg/g) | Removal Efficiency (%) | PC (L/g) | Ref. |
---|---|---|---|---|---|---|---|---|---|---|
1. | MnFe2O4/BC | 3.0 | 45.0 | 7.0 | 27.0 | 10.0 | 3.3 | 99.4 | 52.6 | [32] |
2. | Ag-Ag2O/ZrO2/GL | 2.0 | 30.0 | 7.0 | 27.0 | 10.0 | 4.9 | 99.0 | 50.6 | [34] |
3. | CuO | 2.5 | 30.0 | 6.0 | 22.0 | 25.0 | 5.5 | 54.7 | 0.5 | [35] |
4. | Haloxylon recurvum plant stems | 4.0 | 40.0 | 8.0 | 25.0 | 20.0 | 4.8 | 96.4 | 6.7 | [36] |
5. | Solanum tuberosum plant leaves | 2.0 | 24.0 | 7.0 | 30.0 | 10.0 | 3.9 | 79.0 | 1.9 | [37] |
6. | Fe2O3-SnO2/BC | 2.0 | 90.0 | 7.0 | 27.0 | 10.0 | 4.9 | 97.9 | 23.9 | [38] |
7. | MF NPs | 2.0 | 75.0 | 7.0 | 27.0 | 10.0 | 2.8 | 55.5 | 20.7 | Present study |
8. | CA/MF-NC | 2.0 | 75.0 | 7.0 | 27.0 | 10.0 | 5.0 | 99.2 | 64.9 |
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Ahmad, R.; Alzahrani, E.A.; Dwivedi, P.; Hafeez, S.; Deswal, J.; Fatima, B.; Siddiqui, S.I.; Oh, S. Biodegradable Acid-Based Fe2MnO4 Nanoparticles for Water Remediation. Molecules 2024, 29, 3867. https://doi.org/10.3390/molecules29163867
Ahmad R, Alzahrani EA, Dwivedi P, Hafeez S, Deswal J, Fatima B, Siddiqui SI, Oh S. Biodegradable Acid-Based Fe2MnO4 Nanoparticles for Water Remediation. Molecules. 2024; 29(16):3867. https://doi.org/10.3390/molecules29163867
Chicago/Turabian StyleAhmad, Rabia, Elham A. Alzahrani, Poonam Dwivedi, Sumbul Hafeez, Jyoti Deswal, Bushra Fatima, Sharf Ilahi Siddiqui, and Seungdae Oh. 2024. "Biodegradable Acid-Based Fe2MnO4 Nanoparticles for Water Remediation" Molecules 29, no. 16: 3867. https://doi.org/10.3390/molecules29163867