Polyvinylidene Fluoride-Based Nanowire-Imprinted Membranes with High Flux for Efficient and Selective Separation of Artemisinin/Artemether
Abstract
:1. Introduction
2. Experimental
2.1. Materials
2.2. Synthetic Experiments
2.2.1. Synthesis of MnO2 Nanowires
2.2.2. Synthesis of Imprinted Polymers
2.2.3. Synthesis of MnO2-Nanowire-Blended Imprinting Membrane
2.3. Flux Test
2.4. Adsorption Experiment
2.4.1. MIPs/NIPs Adsorption
2.4.2. Optimal Concentration
2.4.3. Adsorption Kinetics
2.4.4. Sorption Isotherm
2.4.5. Adsorption Thermodynamics
2.4.6. Adsorption Selectivity
2.4.7. Dynamic Adsorption
2.4.8. HPLC
2.5. Characterization Method
3. Results and Discussions
3.1. Characterization of Nanowire-Based Molecular Imprinting Polymers
3.1.1. SEM, TEM, and Contact Angle Test
3.1.2. FT-IR, TG, and Adsorption Experiment
3.2. Characterization of Membranes
3.2.1. SEM and Physical Drawings
3.2.2. XRD and FT-IR Studies
3.2.3. Analysis of Membrane Pore Size, Membrane Flux, and Contact Angle
3.3. Adsorption Performance
3.3.1. The Best Adsorption Concentration
3.3.2. Adsorption Kinetics
3.3.3. Sorption Isotherm
3.3.4. Thermodynamics of Adsorption
3.4. Adsorption Selectivity
3.5. Dynamic Adsorption
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Blended Imprinted Membrane | m/g | m/g | m/g | m/g | m/g |
---|---|---|---|---|---|
PVDF | PSF | PES | DMSO | MIPs | |
PVDF-MIM | 0.42 | - | - | 5.58 | 0.01 |
PSF-MIM | - | 0.6 | - | 5.40 | 0.01 |
PES-MIM | - | - | 0.6 | 5.40 | 0.01 |
Membrane | Pseudo-First-Order Kinetic Equation | Pseudo-Second-Order Kinetic Equation | |||||
---|---|---|---|---|---|---|---|
qe,cal (mg g−1) | k1 (min−1) | R2 | qe,exp (mg g−1) | qe,cal (mg g−1) | k2 (g mg−1 min−1) | R2 | |
PVDF-MIM | 75.85 | 0.0081 | 0.83 | 70.50 | 70.49 | 0.0821 | 0.99 |
PES-MIM | 40.56 | 0.0017 | 0.80 | 34.60 | 35.10 | 0.0723 | 0.99 |
PSF-MIM | 37.19 | 0.0014 | 0.81 | 31.20 | 31.23 | 0.0560 | 0.99 |
Models | Parameter | PVDF-MIM | PES-MIM | PSF-MIM |
---|---|---|---|---|
Langmuir model | R2 | 0.99 | 0.99 | 0.99 |
KL (L mg−1) | 6.69 × 10−6 | 4.42 × 10−5 | 3.94 × 10−4 | |
qm,cal (mg g−1) | 74.90 | 34.56 | 33.41 | |
Freundich model | R2 | 0.96 | 0.95 | 0.97 |
KF (mg g−1) | 78.87 | 40.02 | 43.66 | |
n | 1.86 | 1.31 | 1.1 |
Membrane | (kJ mol−1) | |||
---|---|---|---|---|
(kJ mol−1) | (kJ mol−1 k−1) | 15 °C | 25 °C | |
PVDF-MIM | −46.72 ± 2.10 | −0.17 ± 0.03 | −2.81 ± 0.3 | −1.32 ± 0.20 |
PES-MIM | −2.53 ± 0.32 | −0.012 ± 0.001 | −0.85 ± 0.25 | −0.85 ± 0.15 |
PSF-MIM | −9.20 ± 1.5 | −0.036 ± 0.004 | −1.31 ± 0.17 | −0.98 ± 0.10 |
q (mg g−1) | Kd (L g−1) | α | |||
---|---|---|---|---|---|
Membrane | ART | ARE | ARE | ARE | |
PVDF-MIM | 70.1 ± 5.5 | 22.0 ± 1.8 | 2.344 ± 0.30 | 0.28 ± 0.02 | 8.37 ± 1.01 |
PES-MIM | 30.3 ± 2.1 | 39.8 ± 2.7 | 0.435 ± 0.09 | 0.661 ± 0.04 | 0.66 ± 0.10 |
PSF-MIM | 29.2 ± 2.5 | 33.1 ± 2.5 | 0.41 ± 0.05 | 0.49 ± 0.03 | 0.84 ± 0.09 |
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Meng, M.; Ren, J.; Zhang, C.; Du, W.; Wang, J. Polyvinylidene Fluoride-Based Nanowire-Imprinted Membranes with High Flux for Efficient and Selective Separation of Artemisinin/Artemether. Molecules 2024, 29, 3868. https://doi.org/10.3390/molecules29163868
Meng M, Ren J, Zhang C, Du W, Wang J. Polyvinylidene Fluoride-Based Nanowire-Imprinted Membranes with High Flux for Efficient and Selective Separation of Artemisinin/Artemether. Molecules. 2024; 29(16):3868. https://doi.org/10.3390/molecules29163868
Chicago/Turabian StyleMeng, Minjia, Jiajia Ren, Chuanxun Zhang, Wanqi Du, and Jixiang Wang. 2024. "Polyvinylidene Fluoride-Based Nanowire-Imprinted Membranes with High Flux for Efficient and Selective Separation of Artemisinin/Artemether" Molecules 29, no. 16: 3868. https://doi.org/10.3390/molecules29163868