Preparation of Modified Polycarboxylate by Pyrrolidone for Using as a Dispersant in Cobalt Blue Nano-Pigment Slurry
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterizations of PAI and PAIN
2.2. Determination of the Optimum Wet Grinding Condition for Preparing CoAl2O4 Nano-Pigment Slurry
2.3. Characterization and Performance of CoAl2O4 Nano-Pigment Slurry
2.4. Research on the Dispersion Stability Mechanism of PAIN on CoAl2O4 Nano-Pigment Slurry
3. Materials and Methods
3.1. Materials
3.2. Synthesis of PAIN
3.3. Structural Characterizations of PAIN
3.4. Preparations of CoAl2O4 Nano-Pigment Slurry [4]
3.5. Performance Characterizations of CoAl2O4 Nano-Pigment Slurry
3.6. Dispersion Stability Mechanism Study of PAIN on CoAl2O4 Nano-Pigment Slurry
3.6.1. QCM Measurements
3.6.2. Adsorption Capacity Measurements of PAIN on CoAl2O4
3.6.3. Zeta Potential Measurements
3.6.4. XPS Measurements
3.6.5. FT–IR Measurements
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Dispersant | C% | H% | N% | Pyrrolidone Ligand Content (mmol/g) | Mw | Mn | PDI |
---|---|---|---|---|---|---|---|
PAI | 44.51 | 4.23 | 0 | -- | 43,890 | 12,590 | 3.5 |
PAIN1 | 43.21 | 5.53 | 2.64 | 1.89 | 42,830 | 15,130 | 2.8 |
PAIN2 | 47.78 | 6.41 | 4.43 | 3.16 | 27,620 | 13,150 | 2.1 |
PAIN3 | 43.10 | 7.51 | 4.73 | 3.38 | 14,240 | 6470 | 2.2 |
Dispersant | a/D90 (nm) | V (nm/s) | D (nm) | X (nm) |
---|---|---|---|---|
None | 1887 | 5428 | 5428 | 481 |
PAI | 293 | 131 | 131 | 1221 |
PAIN2 | 83 | 11 | 11 | 2295 |
Dispersant | Langmuir | Freundlich | ||||
---|---|---|---|---|---|---|
As (mg/m2) | K1 (mg/L) | R2 | n | Kf | R2 | |
PAI | 2.9 | 2.752 | 0.969 | 7.207 | 2.051 | 0.857 |
PAIN2 | 3.8 | 2.021 | 0.983 | 5.712 | 1.726 | 0.917 |
Dispersant | Molar Ratio of AA, IA and NVP (n1:n2:n3) | Additive Amount of APS (wt%) | Temperature (°C) | Reaction Time (h) |
---|---|---|---|---|
PAI | 1:1:0 | 3 | 85 | 8 |
PAIN1 | 1:1:0.5 | 1 | 85 | 6 |
PAIN2 | 1:1:1 | 1 | 80 | 6 |
PAIN3 | 1:1:2 | 1 | 80 | 6 |
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Tang, Q.; Yang, R.; Li, J.; Zhou, M.; Yang, D. Preparation of Modified Polycarboxylate by Pyrrolidone for Using as a Dispersant in Cobalt Blue Nano-Pigment Slurry. Molecules 2024, 29, 3940. https://doi.org/10.3390/molecules29163940
Tang Q, Yang R, Li J, Zhou M, Yang D. Preparation of Modified Polycarboxylate by Pyrrolidone for Using as a Dispersant in Cobalt Blue Nano-Pigment Slurry. Molecules. 2024; 29(16):3940. https://doi.org/10.3390/molecules29163940
Chicago/Turabian StyleTang, Qianqian, Rong Yang, Jinnuo Li, Mingsong Zhou, and Dongjie Yang. 2024. "Preparation of Modified Polycarboxylate by Pyrrolidone for Using as a Dispersant in Cobalt Blue Nano-Pigment Slurry" Molecules 29, no. 16: 3940. https://doi.org/10.3390/molecules29163940