Advancing Antimony(III) Adsorption: Impact of Varied Manganese Oxide Modifications on Iron–Graphene Oxide–Chitosan Composites
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of FM @ GC Composite Materials
2.3. Batch Adsorption Experiment
2.4. Analytical Techniques
3. Results and Discussion
3.1. Characterization
3.1.1. XRD Analysis
3.1.2. FTIR Analysis
3.1.3. SEM Analysis
3.1.4. Adsorption Capacity Analysis
3.2. Influencing Factors
3.2.1. Influence of pH Value
3.2.2. Influence of Mass-to-Volume Ratio
3.2.3. Influence of Initial Solution Concentration
3.2.4. Influence of Adsorption Time
3.2.5. Influence of Coexisting Ions
3.3. Adsorption Characteristics
3.3.1. Adsorption Kinetic
3.3.2. Isothermal Adsorption
3.4. Adsorption Mechanism
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Temperature (°C) | Pseudo First Order | Pseudo Second Order | ||||
---|---|---|---|---|---|---|
Qe (mg/g) | k1 | R2 | Qe (mg/g) | k2 | R2 | |
25 | 1.58 | −0.00039 | 0.9817 | 36.48 | 0.020 | 0.9923 |
Temperature (°C) | Langmuir Model | Freundlich Model | ||||
---|---|---|---|---|---|---|
Qe (mg/g) | KL | R2 | KF | 1/n | R2 | |
25 | 178.89 | 0.0335 | 0.8430 | 24.55 | 0.34 | 0.9306 |
35 | 214.09 | 0.0223 | 0.8205 | 21.91 | 0.38 | 0.9139 |
45 | 226.35 | 0.0238 | 0.8293 | 24.58 | 0.37 | 0.9328 |
Elements | C | Fe | O | Mn | Sb |
---|---|---|---|---|---|
Before adsorption | 22.82 | 34.99 | 39.99 | 0.48 | - |
After adsorption | 18.36 | 55.60 | 19.35 | 1.19 | 5.5 |
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Mo, H.; Shan, H.; Xu, Y.; Liao, H.; Peng, S. Advancing Antimony(III) Adsorption: Impact of Varied Manganese Oxide Modifications on Iron–Graphene Oxide–Chitosan Composites. Molecules 2024, 29, 4021. https://doi.org/10.3390/molecules29174021
Mo H, Shan H, Xu Y, Liao H, Peng S. Advancing Antimony(III) Adsorption: Impact of Varied Manganese Oxide Modifications on Iron–Graphene Oxide–Chitosan Composites. Molecules. 2024; 29(17):4021. https://doi.org/10.3390/molecules29174021
Chicago/Turabian StyleMo, Huinan, Huimei Shan, Yuqiao Xu, Haimin Liao, and Sanxi Peng. 2024. "Advancing Antimony(III) Adsorption: Impact of Varied Manganese Oxide Modifications on Iron–Graphene Oxide–Chitosan Composites" Molecules 29, no. 17: 4021. https://doi.org/10.3390/molecules29174021