Investigation into the Synergistic Effect of the Zinc Peroxide/Peroxymonosulfate Double-Oxidation System for the Efficient Degradation of Tetracycline
Abstract
:1. Introduction
2. Experimental Section
2.1. Chemicals
2.2. Synthesis of ZnO2 Particles
2.3. Characterizations
2.4. Catalytic Degradation Experiment
3. Results and Discussion
3.1. Characterizations of ZnO2
3.2. Degradation Performance of ZnO2/PMS Double-Oxidation System
3.2.1. Effects of PMS and ZnO2 Dosages
3.2.2. Effects of Temperature and Initial Solution pH
3.2.3. Adaptability of ZnO2/PMS Double-Oxidation System
3.3. Mechanism Analysis
3.3.1. Quenching Experiments
3.3.2. Intermediate Identification and TC Degradation Pathway Investigation
3.3.3. Activation Pathway Study
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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PMS-Based Systems | PMS Dosage (g/L) | Catalyst Dosage (g/L) | Concentration of TC (mg/L) | Reaction Time (min) | Degradation Rate (%) | Reference |
---|---|---|---|---|---|---|
ZnO2 + PMS | 0.3 | 0.1 | 50 | 60 | 80.2 | This work |
Goethite/biochar composite + PMS | 0.62 | 0.1 | 30 | 60 | ~73% | [42] |
MoS2/biochar + PMS | 0.62 | 0.5 | 20 | 120 | 78% | [43] |
Piggery sludge-derived magnetic biochar + PMS | 0.2 | 0.5 | 10 | 120 | 77.23% | [44] |
Ferromanganese oxide + PMS | 0.4 | 0.4 | 50 | 80 | ~79% | [45] |
Mn(II)-doped MoS2@ alumina + PMS + light | 0.4 | 1.9 | 20 | 60 | 82.4 | [46] |
ZIF-8/PAN-derived porous carbon + PMS | 0.5 | 0.5 | 50 | 120 | 85.1% | [47] |
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Li, S.; Zhang, Y.; Ding, S.; Li, X.; Wang, W.; Dong, N.; Nie, M.; Chen, P. Investigation into the Synergistic Effect of the Zinc Peroxide/Peroxymonosulfate Double-Oxidation System for the Efficient Degradation of Tetracycline. Molecules 2024, 29, 4120. https://doi.org/10.3390/molecules29174120
Li S, Zhang Y, Ding S, Li X, Wang W, Dong N, Nie M, Chen P. Investigation into the Synergistic Effect of the Zinc Peroxide/Peroxymonosulfate Double-Oxidation System for the Efficient Degradation of Tetracycline. Molecules. 2024; 29(17):4120. https://doi.org/10.3390/molecules29174120
Chicago/Turabian StyleLi, Shefeng, Yong Zhang, Siyu Ding, Xuli Li, Wei Wang, Ningning Dong, Miaomiao Nie, and Pei Chen. 2024. "Investigation into the Synergistic Effect of the Zinc Peroxide/Peroxymonosulfate Double-Oxidation System for the Efficient Degradation of Tetracycline" Molecules 29, no. 17: 4120. https://doi.org/10.3390/molecules29174120