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Article

Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6

by
Xiao-Pei Guan
1,*,
Hong Yan
2,
Jian-Guang Sun
1 and
Yong-Zhong Yu
1
1
Current address: Department of Chemistry, The City College of CUNY, Convent Avenue at 138th Street, New York, NY 10031, USA
2
Current address: Department of Chemistry and Environmental Engineering, Beijing Polytechnic University, Beijing 100022, P. R. China
*
Author to whom correspondence should be addressed.
Molecules 1999, 4(3), 69-72; https://doi.org/10.3390/40300069
Submission received: 12 May 1998 / Accepted: 5 March 1999 / Published: 16 March 1999
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Abstract

Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane (1) with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H,5H-diimidazolinium[4,5-b:4',5'-e]pyrazine dinitrate (2).
Keywords: Oxidative cleavage; hexabenzylhexaazaisowurtzitane; iminium cation Oxidative cleavage; hexabenzylhexaazaisowurtzitane; iminium cation

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MDPI and ACS Style

Guan, X.-P.; Yan, H.; Sun, J.-G.; Yu, Y.-Z. Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6. Molecules 1999, 4, 69-72. https://doi.org/10.3390/40300069

AMA Style

Guan X-P, Yan H, Sun J-G, Yu Y-Z. Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6. Molecules. 1999; 4(3):69-72. https://doi.org/10.3390/40300069

Chicago/Turabian Style

Guan, Xiao-Pei, Hong Yan, Jian-Guang Sun, and Yong-Zhong Yu. 1999. "Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6" Molecules 4, no. 3: 69-72. https://doi.org/10.3390/40300069

APA Style

Guan, X.-P., Yan, H., Sun, J.-G., & Yu, Y.-Z. (1999). Novel Carbon-Carbon Bond Oxidative Cleavage of Hexabenzylhexaazaisowurtzitane by n-BuONO and (NH4)2Ce(NO3)6. Molecules, 4(3), 69-72. https://doi.org/10.3390/40300069

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