Recent Advances in Synthetic Bioelastomers
Abstract
:1. Introduction
2. Requirements of Degradable Bioelastomers
3. Synthetic Bioelastomers
3.1. Biodegradable Polyurethanes
3.1.1. Biodegradable Soft Segments
3.1.2. Diisocyanates
3.1.3. Biodegradable Chain Extenders
3.1.4. Biodegradation Mechanism and Degradation Rate
3.2. Biodegradable Polyphosphazenes
3.2.1. Aminated PNs
3.2.2. Alkoxy-Substituted PNs
3.3. Network Polyesters Synthesized with Polyatomic Acids and Polyatomic Alcohols
3.3.1. Poly(polyol sebacate)
3.3.2. Poly(diol-citrates)
3.4. Biodegradable Poly(ether ester)
3.5. Poly(ε-caprolactone) Copolymers with Glycolide or Lactide
3.6. Poly(1,3-trimethylene carbonate) and Copolymers
3.7. Poly(ester amide)s
4. Conclusions
Acknowledgments
References
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Synthetic Bioelastomers | Tg (°C) | TS (MPa) | EB(%) | Approx DT | Degradation Products | Referrences | |
---|---|---|---|---|---|---|---|
PUs | −116 – − 41 | 4–60 | 100–950 | wide range | time | α-hydroxy acids, urethane, urea fragments, lysine (for lysine-derived polyisocyanates) | [15] [16] |
PNs | − 105 −91 | Wide range | Wide range | wide range | time | phosphate, ammonium salts, amino acids, and ethanol | [17] [18] |
PGSa | −7 – 46 | >0.5 | >267 | 1 | Glycerol, sebacate | [19,20] | |
POCb | −5 – 10 | Up to 6.7 | 265 ± 10 | variable | Octanediol, citric acid | [21] | |
PDCc | −5 – 10 | Up to 3.14 ± 0.5 | 322 ± 20 | variable | 1,10-decanediol Citric acid | [22] | |
Poly(diol citrates) | − 5 10 | Up to 11.2 | Up to 502% | variable | Citric acid; polyols | [22] | |
PEG/PBT | – | 8 to 23 | 500% to 1300% | wide range | time | PEG and PBT segment | [23,24] |
PGCLd | – | <1 | Up to 250 | >1.5 | Short chain oligomers; glycolic acid; 6-hydroxyhexanoic | [24,25], | |
TMC-DLLA (dry) 50:50 e | 11 | 10 | 570% | <11 | Short chain oligomers; d,l-lactic acid; TMC monomers | [26–28] | |
TMC-DLLA (dry) 20:80f | 33 | 51 | 7 | <11 | Short chain oligomers; d,l-lactic acid; TMC monomers | [26–28] | |
TMC-CL 10:90g | >−17 | 23 | – | >24 | Short chain oligomers; Caproic acid | [26–28] | |
PEAs | variable | variable | variable | wide range | time | Short chain oligomers; diamines,dicarboxylic acids | [29] |
Diisocyanates | Name and Abbreviation |
---|---|
Butane diisocyanate (BDI) | |
Hexamethylene diisocyanate (HDI) | |
Isophorone diisocyanate (IPD) | |
Lysine diisocyanate (LDI) | |
Trimethylhexamethylene diisocyanate (TMDI) |
© 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
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Shi, R.; Chen, D.; Liu, Q.; Wu, Y.; Xu, X.; Zhang, L.; Tian, W. Recent Advances in Synthetic Bioelastomers. Int. J. Mol. Sci. 2009, 10, 4223-4256. https://doi.org/10.3390/ijms10104223
Shi R, Chen D, Liu Q, Wu Y, Xu X, Zhang L, Tian W. Recent Advances in Synthetic Bioelastomers. International Journal of Molecular Sciences. 2009; 10(10):4223-4256. https://doi.org/10.3390/ijms10104223
Chicago/Turabian StyleShi, Rui, Dafu Chen, Quanyong Liu, Yan Wu, Xiaochuan Xu, Liqun Zhang, and Wei Tian. 2009. "Recent Advances in Synthetic Bioelastomers" International Journal of Molecular Sciences 10, no. 10: 4223-4256. https://doi.org/10.3390/ijms10104223