Influence of Chemical Extraction on Rheological Behavior, Viscoelastic Properties and Functional Characteristics of Natural Heteropolysaccharide/Protein Polymer from Durio zibethinus Seed
Abstract
:1. Introduction
2. Results and Discussion
2.1. Extraction Yield
2.2. Viscosity
2.3. Protein Content
2.4. Solubility
2.5. Elastic Modulus (G′) and Viscous Modulus (G″)
3. Experimental Section
3.1. Materials and Methods
3.2. Chemical Extraction
3.3. Analytical Tests
3.3.1. Extraction Yield
3.3.2. Measurement of Protein Content
3.3.3. Solubility Measurement
3.3.4. Determination of Apparent Viscosity
3.3.5. Dynamic Rheological Measurements
3.4. Experimental Analysis
4. Conclusions
Acknowledgments
- Sample Availability: Samples of durian seed gum are available from the authors.
References
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Regression coefficient | Extraction Yield (%) | Viscosity (mPa.s) | Protein Content (%) | Elastic modulus G′ (Pa) | Viscous modulus G″ (Pa) | Solubility (%) |
---|---|---|---|---|---|---|
b0 | 45.021 | 15.800 | 1.0133 | 0.000190 | 0.45255 | 56.401 |
b1 | 0.318 | 0.165 | – | 0.000002 | – | −0.235 |
b2 | −1.623 | 3.493 | −0.8273 | 0.000034 | −0.02514 | 0.415 |
b3 | −2.527 | −1.704 | 0.5260 | – | −0.01420 | −1.487 |
b12 | −0.001 | −0.001 | – | – | – | 0.001 |
b22 | 0.515 | −0.216 | 0.0455 | – | – | – |
b32 | 0.041 | 0.024 | −0.0074 | – | 0.00010 | 0.018 |
b12 | −0.029 | – | – | −0.000000 | – | – |
b13 | 0.004 | – | – | – | – | 0.002 |
b23 | – | – | – | – | 0.00049 | – |
R2 | 0.988 | 0.879 | 0.952 | 0.763 | 0.882 | 0.975 |
p value | 0.000 * | 0.005 * | 0.000 * | 0.048 * | 0.000 * | 0.001 * |
Lack of fit (p value) | 0.122 | 0.827 | 0.765 | 0.676 | 0.000 * | 0.622 |
Independent variable terms | Extraction Yield (%) | Viscosity (mPa.s) | Protein content (%) | Solubility (%) | Elastic modulus (G′, Pas) | Viscous modulus (G″, Pas) | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
p | F-ratio | p | F-ratio | p | F-ratio | p | F-ratio | p | F-ratio | p | F-ratio | ||
Main effects | x1 | 0.024 | 8.22 | 0.018 | 8.84 | – | – | 0.001 | 29.76 | 0.025 | 6.677 | – | – |
x2 | 0.301 * | 1.24 | 0.003 | 17.58 | 0.000 | 48.34 | 0.010 | 11.41 | 0.011 | 9.302 | 0.000 | 40.602 | |
x3 | 0.057 * | 5.16 | 0.001 | 27.95 | 0.000 | 35.10 | 0.000 | 42.38 | – | – | 0.000 | 35.784 | |
Quadratic effects | x11 | 0.028 | 7.64 | 0.019 | 8.532 | – | – | 0.001 | 22.33 | – | – | – | – |
x22 | 0.000 | 40.43 | 0.003 | 17.93 | 0.000 | 39.05 | – | – | – | – | – | – | |
x33 | 0.019 | 9.13 | 0.001 | 30.70 | 0.000 | 45.45 | 0.000 | 40.04 | – | – | 0.002 | 17.859 | |
Interaction effects | x12 | 0.001 | 31.99 | – | – | – | – | – | – | 0.029 | 6.340 | – | – |
x13 | 0.027 | 7.70 | – | – | – | – | – | – | – | – | – | – | |
x23 | – | – | – | – | – | – | 0.049 | 5.39 | – | – | 0.000 | 29.246 |
Variable | Independent variable levels | ||||
---|---|---|---|---|---|
Independent Variables | Low | Center | High | Axial (−α) | Axial (+α) |
Decolorizing time (x1, 60 min–180 min) | 60 | 120 | 180 | 22 | 218 |
Soaking time (x2, 4 h–12 h) | 4 | 8 | 12 | 1.5 | 14.5 |
Soaking temperature (x3, 25 °C–55 °C) | 25 | 40 | 55 | 15.5 | 64.5 |
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Amid, B.T.; Mirhosseini, H. Influence of Chemical Extraction on Rheological Behavior, Viscoelastic Properties and Functional Characteristics of Natural Heteropolysaccharide/Protein Polymer from Durio zibethinus Seed. Int. J. Mol. Sci. 2012, 13, 14871-14888. https://doi.org/10.3390/ijms131114871
Amid BT, Mirhosseini H. Influence of Chemical Extraction on Rheological Behavior, Viscoelastic Properties and Functional Characteristics of Natural Heteropolysaccharide/Protein Polymer from Durio zibethinus Seed. International Journal of Molecular Sciences. 2012; 13(11):14871-14888. https://doi.org/10.3390/ijms131114871
Chicago/Turabian StyleAmid, Bahareh Tabatabaee, and Hamed Mirhosseini. 2012. "Influence of Chemical Extraction on Rheological Behavior, Viscoelastic Properties and Functional Characteristics of Natural Heteropolysaccharide/Protein Polymer from Durio zibethinus Seed" International Journal of Molecular Sciences 13, no. 11: 14871-14888. https://doi.org/10.3390/ijms131114871