Electrophoretic Deposition of Hydroxyapatite Film Containing Re-Doped MoS2 Nanoparticles
Abstract
:1. Introduction
2. Experimental
2.1. Sample Preparation
2.1.1. Surface Treatment
2.1.2. Titanium Anodization
2.1.3. Electrophoretic Deposition
2.2. Characterization
2.2.1. High-Resolution Scanning Electron Microscopy (HRSEM) and High-Resolution Transmission Electron Microcopy (HRTEM)
2.2.2. X-ray Diffraction (XRD)
2.2.3. Raman Spectroscopy
2.2.4. Zeta Potential Measurements
2.2.5. Tribological Testing
3. Results and Discussion
3.1. SEM Analysis
3.2. Zeta Potential Measurements
3.3. X-ray Diffraction (XRD)
3.4. Raman Spectroscopy
3.5. Tribological Testing
4. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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EPD Films | HA | Portlandite | Brushite | Calcium Pyrophosphate | β-TCP | Re:IF-MoS2 |
---|---|---|---|---|---|---|
Film obtained from solution A | 74.8 wt % | 25 wt % | 0.2 wt % | |||
Film obtained from solution B | 17.2 wt % | 81.3 wt % | 1.5 wt % | |||
Film obtained from solution C | 81.1 wt % | 17.5 wt % | 1.4 wt % | |||
Film obtained from solution A after annealing | 73.6 wt % | 20.4 wt % | 5.9 wt % | 0.1 wt % |
EPD films | HA | Portlandite | Calcium Oxide | Re:IF-MoS2 |
---|---|---|---|---|
Film obtained from solution A without Re:IF-MoS2 (3 h) | 87.8 wt % | 4.6 wt % | 7.6 wt % | |
Film obtained from solution A (2 h) | 82.6 wt % | 7.4 wt % | 9.1 wt % | 0.3 wt % |
Film obtained from solution A (3 h) | 80.4 wt % | 11.3 wt % | 8.0 wt % | 0.3 wt % |
Film obtained from solution A (4 h) | 77.8 wt % | 13.6 wt % | 8.3 wt % | 0.3 wt % |
Tested Film | Initial Coefficient of Friction | Final Coefficient of Friction (after 20 Cycles) | Initial Roughness (μm) |
---|---|---|---|
Titanium after surface treatment | 0.50 ± 0.01 | 0. 60 ± 0.02 | 0.23 ± 0.03 |
Titanium after anodization | 0.15 ± 0.01 | 0.23 ± 0.03 | 0.50 ± 0.05 |
Film of HA with Re:IF-MoS2 NP obtained from solution A on anodized titanium | 0.11 ± 0.01 | 0.13 ± 0.01 | 0.45 ± 0.4 |
Film of HA with Re:IF-MoS2 NP obtained from solution B on anodized titanium | 0.21 ± 0.02 | 0.43 ± 0.08 | 0.37 ± 0.03 |
Film of HA with Re:IF-MoS2 NP obtained from solution C on anodized titanium | 0.37 ± 0.23 | 0.30 ± 0.18 | 0.52 ± 0.02 |
Film of HA with Re:IF-MoS2 NP obtained from solution A on anodized titanium after annealing | 0.12 ± 0.01 | 0.11 ± 0.02 | 0.49 ± 0.7 |
Tested Film | Initial Coefficient of Friction | Final Coefficient of Friction (after 100 Cycles) | Initial Roughness (μm) |
---|---|---|---|
Pure HA film obtained from solution A without NP after 3 h deposition | 0.66 ± 0.08 | 0.78 ± 0.04 | 1.59 ± 0.28 |
HA film with Re:IF-MoS2 NP obtained from solution A after 2 h | 0.75 ± 0.05 | 0.63 ± 0.03 | 0.49 ± 0.05 |
HA film with Re:IF-MoS2 NP obtained from solution A after 3 h | 0.53 ± 0.03 | 0.55 ± 0.04 | 0.57 ± 0.17 |
HA film with Re:IF-MoS2 NP obtained from solution A after 4 h | 0.13 ± 0.01 | 0.12 ± 0.02 | 0.48 ± 0.02 |
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Shalom, H.; Feldman, Y.; Rosentsveig, R.; Pinkas, I.; Kaplan-Ashiri, I.; Moshkovich, A.; Perfilyev, V.; Rapoport, L.; Tenne, R. Electrophoretic Deposition of Hydroxyapatite Film Containing Re-Doped MoS2 Nanoparticles. Int. J. Mol. Sci. 2018, 19, 657. https://doi.org/10.3390/ijms19030657
Shalom H, Feldman Y, Rosentsveig R, Pinkas I, Kaplan-Ashiri I, Moshkovich A, Perfilyev V, Rapoport L, Tenne R. Electrophoretic Deposition of Hydroxyapatite Film Containing Re-Doped MoS2 Nanoparticles. International Journal of Molecular Sciences. 2018; 19(3):657. https://doi.org/10.3390/ijms19030657
Chicago/Turabian StyleShalom, Hila, Yishay Feldman, Rita Rosentsveig, Iddo Pinkas, Ifat Kaplan-Ashiri, Alexey Moshkovich, Vladislav Perfilyev, Lev Rapoport, and Reshef Tenne. 2018. "Electrophoretic Deposition of Hydroxyapatite Film Containing Re-Doped MoS2 Nanoparticles" International Journal of Molecular Sciences 19, no. 3: 657. https://doi.org/10.3390/ijms19030657