Relationship between Antioxidant Activity and Ligand Basicity in the Dipicolinate Series of Oxovanadium(IV) and Dioxovanadium(V) Complexes
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Chemical Formula | C18H15N2O7V |
---|---|
Formula weight/g·mol−1 | 422.26 |
Crystal system | monoclinic |
Space group | P21/c |
a/Å | 11.7061(9) |
b/Å | 10.6882(5) |
c/Å | 15.3271(11) |
α/° | 90 |
β/° | 111.967(8) |
γ/° | 90 |
V/Å3 | 1778.5(2) |
Z | 2 |
T/K | 295(2) |
λMo/Å | 0.71073 |
ρcalc/g·cm–3 | 1.577 |
F(000) | 864 |
µ/mm−1 | 0.603 |
θ range/° | 3.35–25.00 |
Completeness θ/% | 99.8 |
Reflections collected | 11911 |
Reflections unique | 3121 [Rint = 0.0525] |
Data/restraints/parameters | 3121/3/262 |
Goodness of fit on F2 | 1.058 |
Final R1 value (I > 2σ(I)) | 0.0468 |
Final wR2 value (I > 2σ(I)) | 0.0992 |
Final R1 value (all data) | 0.0655 |
Final wR2 value (all data) | 0.1069 |
CCDC number | 2087422 |
D–H···A | d(D–H) [Å] | d(H···A) [Å] | d(D⋯A) (Å) | ∠D–H⋯A (°) |
---|---|---|---|---|
O1W–H1WA···O12 i | 0.95(2) | 1.91(2) | 2.811(3) | 158(4) |
O1W–H1WB···O13 | 0.95(2) | 1.91(2) | 2.826(3) | 161(4) |
N21–H21···O1W | 0.87(3) | 1.86(3) | 2.699(4) | 161(4) |
C3–H3···O9 ii | 0.93 | 2.40 | 3.330(4) | 177 |
C5–H5···O9 iii | 0.93 | 2.38 | 3.250(4) | 157 |
C26–H26···O11 i | 0.93 | 2.35 | 3.135(4) | 142 |
C28–H28···O1W | 0.93 | 2.44 | 3.345(4) | 165 |
C29–H29···O14 | 0.93 | 2.58 | 3.389(5) | 145 |
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Drzeżdżon, J.; Pawlak, M.; Matyka, N.; Sikorski, A.; Gawdzik, B.; Jacewicz, D. Relationship between Antioxidant Activity and Ligand Basicity in the Dipicolinate Series of Oxovanadium(IV) and Dioxovanadium(V) Complexes. Int. J. Mol. Sci. 2021, 22, 9886. https://doi.org/10.3390/ijms22189886
Drzeżdżon J, Pawlak M, Matyka N, Sikorski A, Gawdzik B, Jacewicz D. Relationship between Antioxidant Activity and Ligand Basicity in the Dipicolinate Series of Oxovanadium(IV) and Dioxovanadium(V) Complexes. International Journal of Molecular Sciences. 2021; 22(18):9886. https://doi.org/10.3390/ijms22189886
Chicago/Turabian StyleDrzeżdżon, Joanna, Marta Pawlak, Natalia Matyka, Artur Sikorski, Barbara Gawdzik, and Dagmara Jacewicz. 2021. "Relationship between Antioxidant Activity and Ligand Basicity in the Dipicolinate Series of Oxovanadium(IV) and Dioxovanadium(V) Complexes" International Journal of Molecular Sciences 22, no. 18: 9886. https://doi.org/10.3390/ijms22189886