Constructing Morphologically Tunable Copper Oxide-Based Nanomaterials on Cu Wire with/without the Deposition of Manganese Oxide as Bifunctional Materials for Glucose Sensing and Supercapacitors
Abstract
:1. Introduction
2. Materials and Methods
2.1. Reagents
2.2. Synthesis of Morphologically Tunable Copper Oxide and Heterostructured Mn-Cu Bimetallic Oxide-Based Nanomaterials on Cu Wire
2.3. Apparatus
3. Results
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
- Bennett, J.E.; Stevens, G.A.; Mathers, C.D.; Bonita, R.; Rehm, J.; Kruk, M.E.; Riley, L.M.; Dain, K.; Kengne, A.P.; Chalkidou, K. NCD Countdown 2030: Worldwide trends in non-communicable disease mortality and progress towards Sustainable Development Goal target 3.4. Lancet 2018, 392, 1072–1088. [Google Scholar] [CrossRef] [Green Version]
- Maamri, A.; El Mostafa, S.B. The Environmental Health Role in Reducing Non Communicable Diseases Through a Healthy Lifestyle. In Disease Prevention and Health Promotion in Developing Countries; Springer: Cham, Switzerland, 2020; pp. 39–59. [Google Scholar]
- Gonzalez, F.J.; Xie, C.; Jiang, C. The role of hypoxia-inducible factors in metabolic diseases. Nat. Rev. Endocrinol. 2019, 15, 21–32. [Google Scholar] [CrossRef] [PubMed]
- Bantug, G.R.; Galluzzi, L.; Kroemer, G.; Hess, C. The spectrum of T cell metabolism in health and disease. Nat. Rev. Immunol. 2018, 18, 19–34. [Google Scholar] [CrossRef] [PubMed]
- Sharma, K.; Arora, A.; Tripathi, S.K. Review of supercapacitors: Materials and devices. J. Energy Storage 2019, 21, 801–825. [Google Scholar]
- Muzaffar, A.; Ahamed, M.B.; Deshmukh, K.; Thirumalai, J. A review on recent advances in hybrid supercapacitors: Design, fabrication and applications. Renew. Sustain. Energy Rev. 2019, 101, 123–145. [Google Scholar] [CrossRef]
- Swain, N.; Mitra, A.; Saravanakumar, B.; Balasingam, S.K.; Mohanty, S.; Nayak, S.K.; Ramadoss, A. Construction of three-dimensional MnO2/Ni network as an efficient electrode material for high performance supercapacitors. Electrochim. Acta 2020, 342, 136041. [Google Scholar] [CrossRef]
- Mao, W.; He, H.; Sun, P.; Ye, Z.; Huang, J. Three-dimensional porous nickel frameworks anchored with cross-linked Ni(OH)2 nanosheets as a highly sensitive nonenzymatic glucose sensor. ACS Appl. Mater. Interfaces 2018, 10, 15088–15095. [Google Scholar] [CrossRef]
- Senthilkumar, V.; Kadumudi, F.B.; Ho, N.T.; Kim, J.-W.; Park, S.; Bae, J.-S.; Choi, W.M.; Cho, S.; Kim, Y.S. NiO nanoarrays of a few atoms thickness on 3D nickel network for enhanced pseudocapacitive electrode applications. J. Power Sources 2016, 303, 363–371. [Google Scholar] [CrossRef]
- Xu, H.; Xia, C.; Wang, S.; Han, F.; Akbari, M.K.; Hai, Z.; Zhuiykov, S. Electrochemical non-enzymatic glucose sensor based on hierarchical 3D Co3O4/Ni heterostructure electrode for pushing sensitivity boundary to a new limit. Sens. Actuators B Chem. 2018, 267, 93–103. [Google Scholar] [CrossRef]
- Li, Z.; Chen, Y.; Xin, Y.; Zhang, Z. Sensitive electrochemical nonenzymatic glucose sensing based on anodized CuO nanowires on three-dimensional porous copper foam. Sci. Rep. 2015, 5, 16115. [Google Scholar] [CrossRef] [Green Version]
- Yu, Y.; Wang, H.; Zhang, H.; Tan, Y.; Wang, Y.; Song, K.; Yang, B.; Yuan, L.; Shen, X.; Hu, X. Blanket-like Co(OH)2/CoOOH/Co3O4/Cu(OH)2 composites on Cu foam for hybrid supercapacitor. Electrochim. Acta 2020, 334, 135559. [Google Scholar] [CrossRef]
- Pan, Q.; Jin, H.; Wang, H.; Yin, G. Flower-like CuO film-electrode for lithium ion batteries and the effect of surface morphology on electrochemical performance. Electrochim. Acta 2007, 53, 951–956. [Google Scholar] [CrossRef]
- Wang, H.; Pan, Q.; Zhao, J.; Yin, G.; Zuo, P. Fabrication of CuO film with network-like architectures through solution-immersion and their application in lithium ion batteries. J. Power Sources 2007, 167, 206–211. [Google Scholar] [CrossRef]
- Fan, M.; Bai, Z.; Zhang, Q.; Ma, C.; Zhou, X.-D.; Qiao, J. Aqueous CO2 reduction on morphology controlled CuxO nanocatalysts at low overpotential. RSC Adv. 2014, 4, 44583–44591. [Google Scholar] [CrossRef]
- Ma, Y.; Wang, H.; Key, J.; Ji, S.; Lv, W.; Wang, R. Control of CuO nanocrystal morphology from ultrathin “willow-leaf” to “flower-shaped” for increased hydrazine oxidation activity. J. Power Sources 2015, 300, 344–350. [Google Scholar] [CrossRef]
- Yang, X.; Qiao, Z.; Liu, F.; Yang, S.; Zhang, L.; Cao, B. In-depth study of electrochemical capacitor performance of MnO2 during phase transition from Ramsdellite-MnO2 to Birnessite-MnO2. Electrochim. Acta 2018, 280, 77–85. [Google Scholar] [CrossRef]
- Chang, H.-W.; Lu, Y.-R.; Chen, J.-L.; Chen, C.-L.; Lee, J.-F.; Chen, J.-M.; Tsai, Y.-C.; Chang, C.-M.; Yeh, P.-H.; Chou, W.-C. Nanoflaky MnO2/functionalized carbon nanotubes for supercapacitors: An in situ X-ray absorption spectroscopic investigation. Nanoscale 2015, 7, 1725–1735. [Google Scholar] [CrossRef]
- Gomathisankar, P.; Hachisuka, K.; Katsumata, H.; Suzuki, T.; Funasaka, K.; Kaneco, S. Enhanced photocatalytic hydrogen production from aqueous methanol solution using ZnO with simultaneous photodeposition of Cu. Int. J. Hydrogen Energy 2013, 38, 11840–11846. [Google Scholar] [CrossRef]
- Czioska, S.; Wang, J.; Zuo, S.; Teng, X.; Chen, Z. Hierarchically structured NiFeOx/CuO nanosheets/nanowires as an efficient electrocatalyst for the oxygen evolution reaction. ChemCatChem 2018, 10, 1005–1011. [Google Scholar] [CrossRef]
- Zeng, J.; Fan, H.; Wang, Y.; Zhang, S.; Xue, J.; Chen, X. Ferromagnetic and microwave absorption properties of copper oxide/cobalt/carbon fiber multilayer film composites. Thin Solid Film. 2012, 520, 5053–5059. [Google Scholar] [CrossRef]
- Singh, D.P.; Ojha, A.K.; Srivastava, O.N. Synthesis of different Cu(OH)2 and CuO (nanowires, rectangles, seed-, belt-, and sheetlike) nanostructures by simple wet chemical route. J. Phys. Chem. C 2009, 113, 3409–3418. [Google Scholar] [CrossRef]
- Anantharaj, S.; Sugime, H.; Noda, S. Ultrafast growth of a Cu (OH)2–CuO nanoneedle array on Cu foil for methanol oxidation electrocatalysis. ACS Appl. Mater. Interfaces 2020, 12, 27327–27338. [Google Scholar] [CrossRef] [PubMed]
- Akhavan, O.; Azimirad, R.; Safa, S.; Hasani, E. CuO/Cu(OH)2 hierarchical nanostructures as bactericidal photocatalysts. J. Mater. Chem. 2011, 21, 9634–9640. [Google Scholar] [CrossRef]
- He, D.; Wang, G.; Liu, G.; Bai, J.; Suo, H.; Zhao, C. Facile route to achieve mesoporous Cu(OH)2 nanorods on copper foam for high-performance supercapacitor electrode. J. Alloy. Compd. 2017, 699, 706–712. [Google Scholar] [CrossRef]
- He, G.; Tian, L.; Cai, Y.; Wu, S.; Su, Y.; Yan, H.; Pu, W.; Zhang, J.; Li, L. Sensitive nonenzymatic electrochemical glucose detection based on hollow porous NiO. Nanoscale Res. Lett. 2018, 13, 3. [Google Scholar] [CrossRef] [Green Version]
- Lin, L.-Y.; Karakocak, B.B.; Kavadiya, S.; Soundappan, T.; Biswas, P. A highly sensitive non-enzymatic glucose sensor based on Cu/Cu2O/CuO ternary composite hollow spheres prepared in a furnace aerosol reactor. Sens. Actuators B Chem. 2018, 259, 745–752. [Google Scholar] [CrossRef]
- Velmurugan, M.; Karikalan, N.; Chen, S.-M. Synthesis and characterizations of biscuit-like copper oxide for the non-enzymatic glucose sensor applications. J. Colloid Interface Sci. 2017, 493, 349–355. [Google Scholar] [CrossRef]
- Figiela, M.; Wysokowski, M.; Galinski, M.; Jesionowski, T.; Stepniak, I. Synthesis and characterization of novel copper oxide-chitosan nanocomposites for non-enzymatic glucose sensing. Sens. Actuators B Chem. 2018, 272, 296–307. [Google Scholar] [CrossRef]
- Kim, K.; Kim, S.; Lee, H.N.; Park, Y.M.; Bae, Y.-S.; Kim, H.-J. Electrochemically derived CuO nanorod from copper-based metal-organic framework for non-enzymatic detection of glucose. Appl. Surf. Sci. 2019, 479, 720–726. [Google Scholar] [CrossRef]
- Vediyappan, V.; Sivakumar, M.; Chen, S.-M.; Lai, Q.; Madhu, R. Nanolayers of carbon protected copper oxide nanocomposite for high performance energy storage and non-enzymatic glucose sensor. J. Alloy. Compd. 2021, 875, 160063. [Google Scholar] [CrossRef]
- Singh, J.; Manna, A.K.; Soni, R. Sunlight driven photocatalysis and non-enzymatic glucose sensing performance of cubic structured CuO thin films. Appl. Surf. Sci. 2020, 530, 147258. [Google Scholar] [CrossRef]
- Ibupoto, Z.H.; Khun, K.; Beni, V.; Liu, X.; Willander, M. Synthesis of novel CuO nanosheets and their non-enzymatic glucose sensing applications. Sensors 2013, 13, 7926–7938. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Hekmat, F.; Ezzati, M.; Shahrokhian, S.; Unalan, H.E. Microwave-assisted decoration of cotton fabrics with Nickel-Cobalt sulfide as a wearable glucose sensing platform. J. Electroanal. Chem. 2021, 890, 115244. [Google Scholar] [CrossRef]
- Jabeen, N.; Xia, Q.; Savilov, S.V.; Aldoshin, S.M.; Yu, Y.; Xia, H. Enhanced pseudocapacitive performance of α-MnO2 by cation preinsertion. ACS Appl. Mater. Interfaces 2016, 8, 33732–33740. [Google Scholar] [CrossRef]
- Wang, X.; Chen, S.; Li, D.; Sun, S.; Peng, Z.; Komarneni, S.; Yang, D. Direct interfacial growth of MnO2 nanostructure on hierarchically porous carbon for high-performance asymmetric supercapacitors. ACS Sustain. Chem. Eng. 2018, 6, 633–641. [Google Scholar] [CrossRef]
- Makgopa, K.; Ejikeme, P.M.; Jafta, C.J.; Raju, K.; Zeiger, M.; Presser, V.; Ozoemena, K.I. A high-rate aqueous symmetric pseudocapacitor based on highly graphitized onion-like carbon/birnessite-type manganese oxide nanohybrids. J. Mater. Chem. A 2015, 3, 3480–3490. [Google Scholar] [CrossRef] [Green Version]
- Chen, H.; Wang, M.Q.; Yu, Y.; Liu, H.; Lu, S.-Y.; Bao, S.-J.; Xu, M. Assembling hollow cobalt sulfide nanocages array on graphene-like manganese dioxide nanosheets for superior electrochemical capacitors. ACS Appl. Mater. Interfaces 2017, 9, 35040–35047. [Google Scholar] [CrossRef]
- Gupta, S.P.; Gosavi, S.W.; Late, D.J.; Qiao, Q.; Walke, P.S. Temperature driven high-performance pseudocapacitor of carbon nano-onions supported urchin like structures of α-MnO2 nanorods. Electrochim. Acta 2020, 354, 136626. [Google Scholar] [CrossRef]
- Jiang, L.; Dong, M.; Dou, Y.; Chen, S.; Liu, P.; Yin, H.; Zhao, H. Manganese oxides transformed from orthorhombic phase to birnessite with enhanced electrochemical performance as supercapacitor electrodes. J. Mater. Chem. A 2020, 8, 3746–3753. [Google Scholar] [CrossRef]
- Ghazal, N.; Madkour, M.; Nazeer, A.A.; Obayya, S.; Mohamed, S.A. Electrochemical capacitive performance of thermally evaporated Al-doped CuI thin films. RSC Adv. 2021, 11, 39262–39269. [Google Scholar] [CrossRef]
Sample | Fitted Results of O 1s XPS Spectra | |
---|---|---|
Oa (%) | Ob (%) | |
Cu-S | 54 | 46 |
Cu-M | 4 | 96 |
Cu-R | 0 | 100 |
Sample | Fitted Results of Cu 2p XPS Spectra | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
Cu 2p3/2 (%) | CuO 2p3/2 (%) | Cu(OH)2 2p3/2 (%) | Sat. 2p3/2 (%) | Sat. 2p3/2 (%) | Cu 2p1/2 (%) | CuO 2p1/2 (%) | Cu(OH)2 2p1/2 (%) | Sat. 2p1/2 (%) | CuO/Cu(OH)2 | |
Cu-S | 38.0 | 12.9 | 4.2 | 4.9 | 4.1 | 18.1 | 7.8 | 3.5 | 6.5 | 2.7 |
Cu-M | 36.6 | 14.1 | 5.7 | 3.5 | 3.6 | 18.2 | 8.0 | 4.9 | 5.4 | 2.1 |
Cu-R | 38.2 | 13.7 | 6.0 | 3.1 | 3.6 | 18.3 | 6.9 | 4.7 | 5.5 | 1.9 |
Sample | Added (mM) | Found by Electrochemical Sensing (mM) | Recovery (%) | RSD (%) |
---|---|---|---|---|
Human serum | 0.48 | 0.44 | 92 | 3.6 |
Human serum | 0.24 | 0.26 | 108 | 3.0 |
Green tea | 0.44 | 0.46 | 105 | 1.4 |
Green tea | 0.22 | 0.21 | 95 | 3.1 |
Sample | Fitted Results of O 1s XPS Spectra | ||
---|---|---|---|
Oa (%) | Ob (%) | Oc (%) | |
MnCu-S | 54 | 25 | 21 |
MnCu-M | 52 | 28 | 20 |
MnCu-R | 42 | 40 | 18 |
Sample | Fitted Results of Mn 2p XPS Spectra | |||||
---|---|---|---|---|---|---|
Mn3+ 2p3/2 (%) | Mn3+ 2p1/2 (%) | Sat. 2p3/2 (%) | Mn4+ 2p3/2 (%) | Mn4+ 2p1/2 (%) | Mn3+/Mn4+ | |
MnCu-S | 44.5 | 12.3 | 0 | 21.7 | 21.5 | 1.3 |
MnCu-M | 43.8 | 14.5 | 0.6 | 20.4 | 20.7 | 1.4 |
MnCu-R | 39.3 | 20.9 | 3.5 | 22.0 | 14.3 | 1.7 |
Sample | Fitted Results of Cu 2p XPS Spectra | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
Cu 2p3/2 (%) | CuO 2p3/2 (%) | Cu(OH)2 2p3/2 (%) | Cu 2p1/2 (%) | CuO 2p1/2 (%) | Cu(OH)2 2p3/2 (%) | Cu 2p (%) | CuO 2p (%) | Cu(OH)2 2p (%) | CuO/Cu(OH)2 | |
MnCu-S | 48.7 | 39.9 | 11.4 | 43.6 | 47.3 | 9.1 | 44.9 | 41.0 | 15.1 | 2.7 |
MnCu-M | 51.1 | 35.8 | 13.1 | 43.3 | 40.1 | 16.6 | 47.3 | 38.0 | 14.7 | 2.6 |
MnCu-R | 68.7 | 21.9 | 9.4 | 55.9 | 24.8 | 19.3 | 64.3 | 22.9 | 12.8 | 1.8 |
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. |
© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Chang, H.-W.; Chen, S.-C.; Chen, P.-W.; Liu, F.-J.; Tsai, Y.-C. Constructing Morphologically Tunable Copper Oxide-Based Nanomaterials on Cu Wire with/without the Deposition of Manganese Oxide as Bifunctional Materials for Glucose Sensing and Supercapacitors. Int. J. Mol. Sci. 2022, 23, 3299. https://doi.org/10.3390/ijms23063299
Chang H-W, Chen S-C, Chen P-W, Liu F-J, Tsai Y-C. Constructing Morphologically Tunable Copper Oxide-Based Nanomaterials on Cu Wire with/without the Deposition of Manganese Oxide as Bifunctional Materials for Glucose Sensing and Supercapacitors. International Journal of Molecular Sciences. 2022; 23(6):3299. https://doi.org/10.3390/ijms23063299
Chicago/Turabian StyleChang, Han-Wei, Song-Chi Chen, Pei-Wei Chen, Feng-Jiin Liu, and Yu-Chen Tsai. 2022. "Constructing Morphologically Tunable Copper Oxide-Based Nanomaterials on Cu Wire with/without the Deposition of Manganese Oxide as Bifunctional Materials for Glucose Sensing and Supercapacitors" International Journal of Molecular Sciences 23, no. 6: 3299. https://doi.org/10.3390/ijms23063299