Simple Rules for Complex Near-Glass-Transition Phenomena in Medium-Sized Schiff Bases
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. Materials
3.2. Differential Scanning Calorimetry
3.3. X-ray Diffraction Studies
3.4. Fourier Transform Infrared Spectroscopy
3.5. Broadband Dielectric Spectroscopy under Ambient Pressure
3.6. Broadband Dielectric Spetroscopy under High-Pressure Conditions
3.7. Density Functional Theory Calculations
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Parameter | Compound 1 | Compound 2 |
---|---|---|
M (g∙mol−1) | 398 | 444 |
Tg from DSC (K) | ~263 | ~304 |
Tg from BDS (K) | 262 ± 1 | 302 ± 1 |
mp | 82 ± 2 | 83 ± 2 |
Ea (kJ∙mol−1) | 23 ± 1 | 23 ± 1 |
Eg (kJ∙mol−1) | 25 | 20 |
dTg/dp (K∙GPa−1) | 230 ± 2 | 246 ± 2 |
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Nowok, A.; Cieślik, W.; Grelska, J.; Jurkiewicz, K.; Makieieva, N.; Kupka, T.; Alemán, J.; Musioł, R.; Pawlus, S. Simple Rules for Complex Near-Glass-Transition Phenomena in Medium-Sized Schiff Bases. Int. J. Mol. Sci. 2022, 23, 5185. https://doi.org/10.3390/ijms23095185
Nowok A, Cieślik W, Grelska J, Jurkiewicz K, Makieieva N, Kupka T, Alemán J, Musioł R, Pawlus S. Simple Rules for Complex Near-Glass-Transition Phenomena in Medium-Sized Schiff Bases. International Journal of Molecular Sciences. 2022; 23(9):5185. https://doi.org/10.3390/ijms23095185
Chicago/Turabian StyleNowok, Andrzej, Wioleta Cieślik, Joanna Grelska, Karolina Jurkiewicz, Natalina Makieieva, Teobald Kupka, José Alemán, Robert Musioł, and Sebastian Pawlus. 2022. "Simple Rules for Complex Near-Glass-Transition Phenomena in Medium-Sized Schiff Bases" International Journal of Molecular Sciences 23, no. 9: 5185. https://doi.org/10.3390/ijms23095185