Strategic Design and Synthesis of Ferrocene Linked Porous Organic Frameworks toward Tunable CO2 Capture and Energy Storage
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis and Molecular Characterization of FEC-CHO, PBDT, and FEC-POPs
2.2. CO2 Uptake of FEC-Mel and FEC-PBDT POPs
2.3. Electrochemical Analysis of FEC-POPs
3. Materials and Methods
3.1. Materials
3.2. Synthesis of Ferrocenecarboxaldehyde (FEC-CHO)
3.3. Synthesis of 6,6′-(1,4-Phenylene)bis(1,3,5-Triazine-2,4-Diamine) (PBDT)
3.4. Synthesis of FEC-Mel POP
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Material | Surface Area (m2 g−1) | Capacitance | References |
---|---|---|---|
FEC-Mel POP | 556 | 53 F g−1/0.5 A g−1 | This work |
FEC-PBDT POP | 428 | 82 F g−1/0.5 A g−1 | This work |
TBN-Py-CMP | 473 | 31 F g−1/0.5 A g−1 | [67] |
CoPc-CMP | - | 13.7 F g−1/1.0 A g–1 | [65] |
Py-BSU CMP | 42 | 38 F g−1/0.5 A g−1 | [69] |
POSS-F-POIP | 452 | 36.2 F g−1/0.5 A g−1 | [68] |
TPE-FFC-CMP | 8 | 4.8 F g−1/0.5 A g−1 | [64] |
Py-FFC-CMP | 50 | 5.07 F g−1/0.5 A g−1 | [64] |
C1-CMP-1 | 608 | 31 F g−1 at 20 mV s𢈒1 | [66] |
Py-PDT POP | 76 | 28 F g−1/0.5 A g−1 | [21] |
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Mousa, A.O.; Chuang, C.-H.; Kuo, S.-W.; Mohamed, M.G. Strategic Design and Synthesis of Ferrocene Linked Porous Organic Frameworks toward Tunable CO2 Capture and Energy Storage. Int. J. Mol. Sci. 2023, 24, 12371. https://doi.org/10.3390/ijms241512371
Mousa AO, Chuang C-H, Kuo S-W, Mohamed MG. Strategic Design and Synthesis of Ferrocene Linked Porous Organic Frameworks toward Tunable CO2 Capture and Energy Storage. International Journal of Molecular Sciences. 2023; 24(15):12371. https://doi.org/10.3390/ijms241512371
Chicago/Turabian StyleMousa, Aya Osama, Cheng-Hsin Chuang, Shiao-Wei Kuo, and Mohamed Gamal Mohamed. 2023. "Strategic Design and Synthesis of Ferrocene Linked Porous Organic Frameworks toward Tunable CO2 Capture and Energy Storage" International Journal of Molecular Sciences 24, no. 15: 12371. https://doi.org/10.3390/ijms241512371