Activation of Ethanol Transformation on Copper-Containing SBA-15 and MnSBA-15 Catalysts by the Presence of Oxygen in the Reaction Mixture
Abstract
:1. Introduction
2. Results and Discussion
2.1. Composition and Structure/Texture of Catalysts
2.2. State of Metals
2.3. Acid-Base Properties of Catalysts
2.4. Ethanol Dehydrogenation–FTIR Study in Flow System
2.4.1. The Effect of the Reaction Temperature
2.4.2. The Effect of Oxygen in the Reaction Mixture
2.4.3. Discussion
3. Materials and Methods
3.1. Materials and Chemicals
3.2. Preparation of Catalysts
3.2.1. Synthesis of SBA-15
3.2.2. Synthesis of MnSBA-15
3.2.3. Modification of SBA-15 and MnSBA-15 Supports with Copper
3.3. Catalysts Characterization
3.4. Acidity Measurements
3.5. Ethanol Dehydrogenation–FTIR Study in Flow System
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Entry | Catalyst | wt.% Cu a | wt.% Mn a | BET Surface Area, m2 g–1 | Total Pore Volume, DFT, cm3 g–1 | Average Pore Diameter, DFT, nm |
---|---|---|---|---|---|---|
1. | SBA-15 | – | – | 868 | 1.04 | 10.6 |
2. | Cu-SBA-15 | 2.0 | – | 422 | 0.57 | 9.6 |
3. | MnSBA-15 b | – | 0.50 | 936 | 1.00 | 11.2 |
4. | Cu-MnSBA-15 b | 2.2 | 0.48 | 661 | 0.64 | 10.6 |
Entry | Cu-SBA-15 | gǁ | Aǁ [G] |
---|---|---|---|
1. | fresh sample | 2.385 | 130.5 |
2. | sample after evacuation at 623 K | 2.324 | 150.7 |
and NO ads. |
Entry | Catalyst | Evacuation Temp., K | Number of LAS, μmol g−1 | Pyridine Desorbed at 573 K from LAS,% a |
---|---|---|---|---|
1. | Cu-SBA-15 | 523 | 30.2 | |
573 | 19.2 | 37 | ||
2. | MnSBA-15 b | 523 | 8.8 | |
573 | 4.6 | 48 | ||
3. | Cu-MnSBA-15 b | 523 | 40.6 | |
573 | 32.8 | 19 |
Entry | Catalyst | 2-Propanol Conv., % | Selectivity, % | ||
---|---|---|---|---|---|
Propene | Acetone | Ether | |||
1. | SBA-15 | 1 | traces | - | - |
2. | Cu-SBA-15 | 17 | 66 | 14 | 20 |
3. | Cu-SBA-15-O2 | 18 | 45 | 55 | 0 |
4. | MnSBA-15 a | 8 | 91 | 6 | 3 |
5. | Cu-MnSBA-15 | 15 | 59 | 40 | 1 |
Entry | Catalyst | 2,5-Hexanedione Conv., % | Selectivity, % | ||
---|---|---|---|---|---|
DMF | MCP | MCP/DMF | |||
1. | SBA-15 | 2 | 45 | 55 | 1.2 |
2. | Cu-SBA-15 | 8 | 72 | 28 | 0.4 |
3. | MnSBA-15 | 10 | 5 | 95 | 19.0 |
4. | Cu-MnSBA-15 | 17 | 23 | 77 | 3.3 |
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Sobczak, I.; Wisniewska, J.; Decyk, P.; Trejda, M.; Ziolek, M. Activation of Ethanol Transformation on Copper-Containing SBA-15 and MnSBA-15 Catalysts by the Presence of Oxygen in the Reaction Mixture. Int. J. Mol. Sci. 2023, 24, 2252. https://doi.org/10.3390/ijms24032252
Sobczak I, Wisniewska J, Decyk P, Trejda M, Ziolek M. Activation of Ethanol Transformation on Copper-Containing SBA-15 and MnSBA-15 Catalysts by the Presence of Oxygen in the Reaction Mixture. International Journal of Molecular Sciences. 2023; 24(3):2252. https://doi.org/10.3390/ijms24032252
Chicago/Turabian StyleSobczak, Izabela, Joanna Wisniewska, Piotr Decyk, Maciej Trejda, and Maria Ziolek. 2023. "Activation of Ethanol Transformation on Copper-Containing SBA-15 and MnSBA-15 Catalysts by the Presence of Oxygen in the Reaction Mixture" International Journal of Molecular Sciences 24, no. 3: 2252. https://doi.org/10.3390/ijms24032252