Next Article in Journal
Esterification and hydrolysis under microwave irradiation
Previous Article in Journal
Correction: Kotali, A. et al. 7-Hydroxy-8-acetylcoumarin N-1-(Carboxymethyl)pyridinium Chloride Hydrazone. Molbank 2008, M571.
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Molbank
Volume 2006
Issue 3
10.3390/M476
molbank-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles thumb_up
...
Endorse textsms
...
Comment
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Short Note

Ethyl 1-(4-chlorophenyl)-5,6-dimethyl-7,8a-diphenyl-4,5,6,8a-tetrahydro-1H-[1,2,4] triazolo[4,3-c][1,3]diazine-3-carboxylate

by
A. Boudina
*,
A. Baouid
and
A. Hasnaoui
Laboratoire de Chimie des Substances Naturelles et des Hétérocycles, Faculté des Sciences-Semlalia, Université Cadi Ayyad, B.P 2390 Marrakech, Maroc
*
Author to whom correspondence should be addressed.
Molbank 2006, 2006(3), M476; https://doi.org/10.3390/M476
Submission received: 15 July 2005 / Accepted: 26 September 2005 / Published: 31 March 2006
Versions Notes

Molbank 2006 m476 i001
Compound 1 [1] (200 mg, 0.41 mmol) was refluxed in dimethylsulfoxide for 30 minutes. After cooling, the solvent was removed by evaporation under reduced pressure. The residue obtained was purified by chromatography on silica gel column (eluent: hexane/ethyl acetate 90/10), then the isolated product was recrystallized from ethanol to give 2 (130 mg, 65%).
Melting point: 130-132°C (Ethanol).
MS (m/z, %): 487 ([M+H]+, 100%).
1H-NMR (CDCl3, 250 MHz): δ= 1.11 (d, J = 6.90 Hz, 3H,CH3-C-5), 1.44 (t, J = 6.90 Hz, 3H, CH3-CH2-O), 2.58 (s, 3H, N-CH3), 4.41 (q, J = 6.90 Hz, 2H, CH3-CH2-O), 5.63 (s, 1H, H-C-8), 5.65 (q, J = 6.90 Hz, 1H, H-C-5), 6.80-7.70 (m, 14H, Ar-H).
13C-NMR and DEPT (CDCl3, 62.5 MHz): δ= 14.21, 19.07 (CH3-CH2-O, CH3-C-5,), 41.59 (N-CH3), 61.86 (CH3-CH2-O), 68.13 (C-5), 85.60 (C-8a), 101.33 (C-8).

Supplementary materials

Supplementary File 1Supplementary File 2Supplementary File 3

References:

  1. Baouid, A.; Benharref, A.; Hasnaoui, A.; Lavergne, J.-P. Bull. Soc. Chim. Belg. 1994, 103(12), 743.
  • Sample Availability: Available from MDPI.

Share and Cite

MDPI and ACS Style

Boudina, A.; Baouid, A.; Hasnaoui, A. Ethyl 1-(4-chlorophenyl)-5,6-dimethyl-7,8a-diphenyl-4,5,6,8a-tetrahydro-1H-[1,2,4] triazolo[4,3-c][1,3]diazine-3-carboxylate. Molbank 2006, 2006, M476. https://doi.org/10.3390/M476

AMA Style

Boudina A, Baouid A, Hasnaoui A. Ethyl 1-(4-chlorophenyl)-5,6-dimethyl-7,8a-diphenyl-4,5,6,8a-tetrahydro-1H-[1,2,4] triazolo[4,3-c][1,3]diazine-3-carboxylate. Molbank. 2006; 2006(3):M476. https://doi.org/10.3390/M476

Chicago/Turabian Style

Boudina, A., A. Baouid, and A. Hasnaoui. 2006. "Ethyl 1-(4-chlorophenyl)-5,6-dimethyl-7,8a-diphenyl-4,5,6,8a-tetrahydro-1H-[1,2,4] triazolo[4,3-c][1,3]diazine-3-carboxylate" Molbank 2006, no. 3: M476. https://doi.org/10.3390/M476

APA Style

Boudina, A., Baouid, A., & Hasnaoui, A. (2006). Ethyl 1-(4-chlorophenyl)-5,6-dimethyl-7,8a-diphenyl-4,5,6,8a-tetrahydro-1H-[1,2,4] triazolo[4,3-c][1,3]diazine-3-carboxylate. Molbank, 2006(3), M476. https://doi.org/10.3390/M476

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop