Adsorption of Malachite Green with Sodium Dodecylbenzene Sulfonate Modified Sepiolite: Characterization, Adsorption Performance and Regeneration
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of Organically Modified Sepiolite
2.3. Characterization
2.4. Adsorption Test
2.5. Acid Regeneration Test
3. Results and Discussion
3.1. Optimization of the Modification Process
3.2. Characterization of Modified Sepiolite
3.3. Impact of the Operation Condition of Adsorption Performance
3.4. Adsorption Thermodynamics and Adsorption Kinetics
3.5. Regeneration of Organic Sepiolite Adsorbent
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Temperature (°C) | Regression Equation | b (L/mg) | ||
---|---|---|---|---|
25 | Ce/qe = 0.0039 Ce + 0.001 | 0.9976 | 256.4 | 3.9 |
35 | Ce/qe = 0.00375 Ce + 0.0008 | 0.9998 | 266.7 | 4.7 |
45 | Ce/qe = 0.0037 Ce + 0.0007 | 0.9997 | 270.3 | 5.3 |
55 | Ce/qe = 0.0036 Ce + 0.0006 | 0.9993 | 277.8 | 6.1 |
Temperature (°C) | Regression Equation | |||
---|---|---|---|---|
25 | ln qe = 0.1409 ln Ce + 5.2632 | 0.9172 | 193.098 | 7.097 |
35 | ln qe = 0.146 Ce + 5.2901 | 0.8506 | 198.383 | 6.849 |
45 | ln qe = 0.1351 Ce + 5.3297 | 0.7075 | 206.376 | 7.402 |
55 | ln qe = 0.1439 Ce + 5.3458 | 0.6952 | 209.726 | 6.949 |
Adsorbent | Experimental Conditions | qm, (mg/g) | Ref. |
---|---|---|---|
Fe3O4@AMCA-MIL53(Al) | C0: 25–400 mg/L; pH 6.8; T: 45 °C; m: 20 mg | 329.61 | (Alqadami et al., 2018) [25] |
MIL-53(Al)-NH2 | C0: 5 mg/L; T: 35 °C; m: 10 mg | 164.9 | (Li et al., 2015) [18] |
This work | C0: 500 mg/L; T: 45 °C; m: 10 mg | 270.3 |
Temperature (K) | |||||
---|---|---|---|---|---|
318 | 3.90 | 1423.19 | 11.50 | −37.46 | 153.96 |
328 | 4.69 | 1710.56 | 11.50 | −39.14 | 154.39 |
338 | 5.29 | 1928.86 | 11.50 | −40.67 | 154.35 |
348 | 6 | 2189.52 | 11.50 | −42.24 | 154.42 |
C0 (mg/L) | Quasi-First-Order Reaction Kinetics Model | Quasi-Secondary Reaction Kinetics Model | Intraparticle Diffusion Model | |||||
---|---|---|---|---|---|---|---|---|
(mg/g) | (1/min) | (mg/g) | (1/min) | (1/min) | ||||
100 | 2.72 | 0.6 × 10−3 | 0.8319 | 49.75 | 0.947 × 10−4 | 1 | 0.0339 | 0.9027 |
200 | 13.05 | 15 × 10−3 | 0.8183 | 103.09 | 0.895 × 10−4 | 0.9999 | 1.2067 | 0.7663 |
300 | 51.04 | 22.2 × 10−3 | 0.9367 | 149.25 | 0.731 × 10−4 | 0.9994 | 0.9196 | 0.6648 |
400 | 145.98 | 21.8 × 10−3 | 0.9872 | 222.22 | 2.109 × 10−3 | 0.9989 | 6.521 | 0.9005 |
500 | 270.10 | 23.2 × 10−3 | 0.9809 | 277.78 | 2.197 × 10−3 | 0.9974 | 9.4062 | 0.9356 |
Temperature (°C) | Quasi-First-Order Reaction Kinetics Model | Quasi-Secondary Reaction Kinetics Model | Intraparticle Diffusion Model | |||||
---|---|---|---|---|---|---|---|---|
(mg/g) | (1/min) | (mg/g) | (1/min) | (1/min) | ||||
25 | 51.04 | 22.2 × 10−3 | 0.9367 | 149.25 | 7.3 × 10−4 | 0.9994 | 0.9196 | 0.6648 |
35 | 149.01 | 24.3 × 10−3 | 0.8840 | 151.51 | 2 × 10−3 | 0.9999 | 1.1494 | 0.7108 |
45 | 149.11 | 24.8 × 10−3 | 0.8950 | 152.67 | 2.7 × 10−3 | 1 | 1.4461 | 0.7542 |
55 | 149.23 | 26.7 × 10−3 | 0.9092 | 153.85 | 3.5 × 10−3 | 1 | 3.0565 | 0.8563 |
HCl Concentration (mol/L) | Decolorization Ratio (%) |
---|---|
0 | 27.14 |
0.05 | 33.64 |
0.1 | 50.34 |
0.2 | 73.56 |
0.3 | 60.28 |
0.5 | 40.38 |
1.0 | 30.88 |
Numbers of Regeneration | Decolorization Ratio (%) |
---|---|
0 | 99.34 |
1 | 73.56 |
2 | 62.08 |
4 | 48.56 |
6 | 18.15 |
8 | 10.58 |
10 | 10.05 |
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Yu, J.; Zhang, L.; Liu, B. Adsorption of Malachite Green with Sodium Dodecylbenzene Sulfonate Modified Sepiolite: Characterization, Adsorption Performance and Regeneration. Int. J. Environ. Res. Public Health 2019, 16, 3297. https://doi.org/10.3390/ijerph16183297
Yu J, Zhang L, Liu B. Adsorption of Malachite Green with Sodium Dodecylbenzene Sulfonate Modified Sepiolite: Characterization, Adsorption Performance and Regeneration. International Journal of Environmental Research and Public Health. 2019; 16(18):3297. https://doi.org/10.3390/ijerph16183297
Chicago/Turabian StyleYu, Jian, Lirong Zhang, and Bin Liu. 2019. "Adsorption of Malachite Green with Sodium Dodecylbenzene Sulfonate Modified Sepiolite: Characterization, Adsorption Performance and Regeneration" International Journal of Environmental Research and Public Health 16, no. 18: 3297. https://doi.org/10.3390/ijerph16183297