Sugarcane Bagasse as an Efficient Biosorbent for Methylene Blue Removal: Kinetics, Isotherms and Thermodynamics
Abstract
:1. Introduction
2. Materials and Methods
2.1. Collection and Preparation of SCB
2.2. Characterization of SCB
2.3. Analytical Measurements
2.4. Effect of Particle Size and Adsorbent Concentration
2.5. Kinetics Adsorption Experiments
2.6. Isotherm Adsorption Experiments
2.7. Thermodynamic Parameters
3. Results and Discussion
3.1. Charachterization of SCB
3.2. Effect of Particle Size and Adsorbent Concentration
3.3. Kinetics Adsorption Experiments
3.4. Isotherms Adsorption Modeling
3.5. Thermodynamics Studies
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Experimental | Pseudo-First-Order | Pseudo-Second-Order | ||||
---|---|---|---|---|---|---|
qe (mg g−1) | K1 (min−1) | qe,cal (mg g−1) | R2 | K2 (g mg−1 min−1) | qe,cal (mg g−1) | R2 |
4.41 | 0.0080 | 0.7365 | 0.7315 | 0.0518 | 4.4228 | 0.9999 |
Model | Parameters | Temperature | ||
---|---|---|---|---|
15 °C | 30 °C | 45 °C | ||
Experimental | qm (mg g−1) | 9.4094 | 9.4575 | 9.4109 |
Langmuir | qm (mg g−1) | 21.7799 | 27.4314 | 24.3229 |
KL (L mg−1) | 1.0373 | 0.8044 | 0.8626 | |
R2 | 0.9413 | 0.9329 | 0.9163 | |
Freundlich | KF (L mg−1) | 12.1294 | 13.6724 | 12.2655 |
1/n | 0.7653 | 0.8268 | 0.7979 | |
R2 | 0.9103 | 0.9128 | 0.8890 | |
Sips | qm (mg g−1) | 10.2134 | 10.4478 | 9.5644 |
KS | 3.9698 | 4.0111 | 4.2878 | |
βs | 2.0008 | 2.0339 | 2.4233 | |
R2 | 0.9856 | 0.9703 | 0.9798 | |
Toth | qm (mg g−1) | 9.7364 | 9.9577 | 9.7307 |
K | 16.4588 | 19.6479 | 17.2374 | |
t | 4.2907 | 4.5530 | 4.6464 | |
R2 | 0.9547 | 0.9370 | 0.9254 |
Biosorbent | qm (mg g−1) | Reference |
---|---|---|
Betel nut husk | 0.32 | [23] |
Passion fruit peel | 2.17 | [24] |
Banana peel | 4.91 | [23] |
Garlic peel | 82.74 | [25] |
Potato peel | 105.26 | [26] |
Orange peel | 157.20 | [27] |
Watermelon winds | 188.68 | [28] |
Sugarcane bagasse | 9.41 | This work |
Temperature (°C) | ΔG° (kJ mol−1) | ΔH° (kJ mol−1) | ΔS° (J mol−1 K−1) |
---|---|---|---|
15 | −17.12 | 1.93 | 66.04 |
30 | −18.04 | ||
45 | −19.11 |
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Andrade Siqueira, T.C.; Zanette da Silva, I.; Rubio, A.J.; Bergamasco, R.; Gasparotto, F.; Aparecida de Souza Paccola, E.; Ueda Yamaguchi, N. Sugarcane Bagasse as an Efficient Biosorbent for Methylene Blue Removal: Kinetics, Isotherms and Thermodynamics. Int. J. Environ. Res. Public Health 2020, 17, 526. https://doi.org/10.3390/ijerph17020526
Andrade Siqueira TC, Zanette da Silva I, Rubio AJ, Bergamasco R, Gasparotto F, Aparecida de Souza Paccola E, Ueda Yamaguchi N. Sugarcane Bagasse as an Efficient Biosorbent for Methylene Blue Removal: Kinetics, Isotherms and Thermodynamics. International Journal of Environmental Research and Public Health. 2020; 17(2):526. https://doi.org/10.3390/ijerph17020526
Chicago/Turabian StyleAndrade Siqueira, Thaisa Caroline, Isabella Zanette da Silva, Andressa Jenifer Rubio, Rosângela Bergamasco, Francielli Gasparotto, Edneia Aparecida de Souza Paccola, and Natália Ueda Yamaguchi. 2020. "Sugarcane Bagasse as an Efficient Biosorbent for Methylene Blue Removal: Kinetics, Isotherms and Thermodynamics" International Journal of Environmental Research and Public Health 17, no. 2: 526. https://doi.org/10.3390/ijerph17020526