1. Introduction
Absorption cooling systems appear to be promising energy-saving technologies if they use residual/available heat or solar energy for their operation [
1]. However, actual absorption equipment with traditional working mixtures has a number of limitations. To overcome the inconvenience and restrictions of traditional working mixtures, one option suggested in the open literature is the use of NH
3/LiNO
3 [
2,
3]. The most attractive aspect of absorption systems using a NH
3/LiNO
3 mixture is that they can be cooled by air because crystallisation does not occur at high condensation temperatures. In addition, systems with a NH
3/LiNO
3 mixture do not require rectification of the refrigerant vapor emitted from the generator because the absorbent is a salt, and these systems can operate at lower activation temperatures compared to ammonia/water (NH
3/H
2O) systems. Nevertheless, former experimental investigations have shown that the major limiting aspect of the NH
3/LiNO
3 mixture is its elevated viscosity, which restricts heat and mass transfer, primarily in the absorber, in comparison to the NH
3/H
2O mixture [
4,
5,
6,
7]. This limitation has motivated studies aimed at enhancing the absorption process with NH
3/LiNO
3 by employing passive techniques [
8,
9,
10]. A comprehensive review of experimental studies involving vapor absorption intensification using passive methods for absorption cooling/heating systems was also recently published [
1].
Absorbers can have various configurations depending on their operation mode, including falling film absorbers, bubble absorbers, spray absorbers, or membrane absorbers. The first two of these configurations are the most commonly used in absorption cooling/heating systems available in the market [
1]. Moreover, various studies have concluded that bubble absorbers contribute to (i) larger heat and mass transfer, (ii) superior interface contact between the refrigerant and weak solution, and (iii) simpler absorber design, compared to those in falling film mode [
11,
12]. This configuration also allows smaller designs for a given system capacity.
Numerical models devoted to studying the absorption process in various designs have been reported to provide a more detailed comprehension of the processes that take place in bubble mode absorbers. However, numerical studies of the absorption process in NH
3/LiNO
3 bubble absorbers and correlations are scarce [
13,
14]. For instance, Infante Ferreira [
13] addressed numerical and experimental studies in a vertical tubular absorber for NH
3/LiNO
3 and NH
3/NaSCN mixtures. The numerical model included Nusselt’s theory and penetration theory to assess the heat and mass transfer parameters. The main result of the study showed that the relationship between the predicted and experimental mass transfer coefficients ranged between 0.64 and 1.60. Moreover, Cerezo et al. [
14] theoretically modelled the absorption phenomenon in a plate heat exchanger (PHE) involving L-type internal corrugations with NH
3/H
2O, NH
3/LiNO
3, and NH
3/NaSCN mixtures. The authors presented a study comparing the performance of the absorber with these three working fluids. Temperatures and thermal load profiles along the absorber were presented for each case study.
Numerical approaches of the bubble absorption process with other working fluids are also available in the literature. Investigations using the conventional working pair of H
2O/LiBr were not included in this literature review because this fluid mixture is commonly used in falling film mode absorbers and requires low vacuum pressure conditions for the absorption process. Moreover, various authors have focused on the absorber performance with NH
3/H
2O as a working fluid in a range of absorber configurations such as vertical tubular bubble absorbers [
15,
16,
17], a plate absorber with offset strip fins (OSF) [
11,
18], a cylindrical bubble absorber [
19], a shell and tubes type bubble absorber [
16], and an L-type plate absorber [
20]. Some of these studies required the use of local heat and mass transfer equations for the vapor and liquid phase, in addition to equations for the vapor bubble diameter, the bubble velocity, and the gas hold-up [
11,
15,
18,
19,
20]. Other absorber modelling studies including the use of mixtures such as ionic liquids [
21] and R22-DMF, R22-DMA, R22-DMETEG, R22-DMEDEG, and R22-NMP [
22,
23] have also been reported in the literature.
In general, studies devoted to detailing the flow characteristics, bubble formation, and rise in bubble absorbers for various working fluids reached several conclusions [
24,
25,
26,
27,
28,
29,
30,
31,
32]: (i) the dominant heat transfer resistance is mainly located in the mixture side; (ii) the mass transfer decreases along the length of the absorber as solution approaches the saturation conditions; and (iii) the vapor phase conditions have an insignificant effect on the absorption process in comparison to effects of solution concentration, temperature, coolant temperature, tube diameter, and length [
11,
16,
18].
The artificial neural network (ANN) design also appears to be an interesting technique for modeling thermal systems. ANNs operate as black-box models and are intended to imitate the biological process of the brain which can be trained to perform an activity. A small number of studies involving the use of ANNs have been published in the open literature [
33,
34,
35,
36]. For instance, Kalogirou [
33] reported various ANN model designs to estimate the capability of renewable energy system configurations. Chow et al. [
37] designed an absorption chiller control system based on an ANN and genetic algorithms. Hernández et al. [
38] used an ANN to predict the performance of a heat transformer system for water purification. Subsequently, Labus et al. [
39] developed an ANN model to simulate the performance of a low-capacity absorption refrigeration machine. Lastly, Alvarez et al. [
40] developed an ANN model to assess the performance parameters of a horizontal falling film absorber with aqueous (lithium, potassium, sodium) nitrate solutions.
Based on the literature review, no validated semi-empirical heat and mass transfer models exist in the open literature to predict the NH3 bubble absorption in an H-type corrugated PHE with NH3/LiNO3 mixture. The present study was part of an R&D project investigating the characterization of the absorption process with NH3/LiNO3. The aim was to improve the information available about the performance of NH3/LiNO3 bubble absorbers and contribute to their technological development. Therefore, this paper aims to provide a description and validation of dimensionless correlations and two different models developed to predict the performance of the NH3 absorption process in a bubble plate absorber. The first model developed is based on discretized heat and mass balances in addition to empirical heat and mass transfer correlations fitted from experimental data, whereas the second model is based on trained artificial neural networks. Initially, each model is assessed and validated individually. Then, a performance comparison between both models is conducted. Finally, the advantages of each model are presented.
3. Results and Discussion
This section presents the correlations proposed, and results from the semi-empirical and ANN models developed to quantify the performance parameters of NH3 bubble absorption with a NH3/LiNO3 mixture. The validation and comparison of both models with experimental data are also reported.
3.1. Heat and Mass Transfer Correlations
This sub-section presents the heat and mass transfer correlations developed and proposed considering the data collected by Amaris [
41] from an experimental study of the H-type PHE absorber. Correlations in Equations (16) and (17) correspond to the solution Nusselt (Nu
Sol) and Sherwood (Sh
Sol) numbers that characterize the absorption process. Validations of these correlations are presented in
Figure 4. Moreover, correlation in Equation (18) refers to the water-side Nusselt number (Nu
Cw) also obtained from the performance of the H-type PHE using water in both the inner and side channels. This means that prior to the experimental investigation of the ammonia absorption process, a preliminary heat transfer experimental study was conducted using water in the inner and side channels. Results from this study are reported Equation (18) and
Figure 5.
The solution Nusselt, Sherwood, and water-side Nusselt numbers were correlated by reducing the mean square error (MSE) when contrasting the correlated and experimentally estimated dimensionless parameters. Variables such as the inlet heat dissipation water temperature, inlet solution temperature, and solution equilibrium temperature were found to have a significant effect on the heat and mass transfer. Therefore, they were included in the correlation to account for these effects [
49].
Figure 4b demonstrates that Equation (16) can adequately estimate 90% of the solution mass transfer coefficient points with relative differences below 15%. Moreover, Equation (17) can estimate 90% of the solution heat transfer coefficient data with relative differences below 15% (see
Figure 4a). These correlations estimate the experimental data with average relative differences of 6.6% and 7.3%, for the heat and mass transfer coefficients, respectively. The fit parameter R
2 for each correlation is shown in
Figure 4. The correlations proposed in Equations (16) and (17) were developed for Reynolds numbers ranging from 10 to 55. In this study, the Prandtl number ranged between 46 and 51, and the Schmidt number in Equation (16) ranged from 5194 to 5947.
Figure 5a,b shows the overall heat transfer coefficient and water-side Nusselt number (Nu
Cw) obtained from the experimental study in the H-type PHE using water in both channels in counter-current configuration and correlated in Equation (15). The black line represents the trend of the results. In these experiments, temperatures were changed in a range from 30 to 60 °C while the mass flow was varied from 50 to 352 kg·h
−1. The correlation proposed in Equation (18) is recommended for a water turbulent flow with a Reynolds number ranging from 400 to 1400. The Prandtl number for the water flow ranged between 4.20 and 4.75.
Figure 5a shows that Equation (18) can satisfactorily estimate 82.4% of the overall water heat transfer coefficient data with relative differences below 2% and an average relative difference of 1.17%.
3.2. Semi-Empirical Model Results
This subsection presents the estimation of the temperatures and concentration at the inlet and outlet of each partial control volume of the PHE using the semi-empirical model (Mod). Modelling of the plate absorber was performed at a mass flow of 40 kg·h
−1 in the solution side. Inlet operating conditions were set as in
Table 2. For comparison purposes, measured inlet and outlet conditions for temperature and solution concentration in the absorber are also depicted.
Simulation results were also contrasted to those from the theoretical model described by Cerezo et al. [
14] (Mod [
14]) at the same conditions. The model described in the literature considers the interface area between the NH
3/H
2O and the ammonia bubble vapour being absorbed. In addition, it employs several correlations reported in the literature from configurations where separated heat and mass transfer processes were considered. Moreover, it also included the correlations reported by Herbine and Perez-Blanco [
15] to estimate the heat transfer between the NH
3/H
2O mixture and the wall.
Figure 6 illustrates the profiles of temperature and concentration along the PHE absorber. Results show that the measured and simulated outlet temperatures and concentrations in the PHE were reasonably close. For instance,
Figure 6a shows that at a heat dissipation temperature of 40 °C at the PHE inlet, the temperature of the solution at the PHE outlet using the present model is 0.5 °C lower than that of the measured value, whereas the outlet temperature obtained with the model described by Cerezo et al. [
14] is 2.2 °C lower. Moreover, at a water temperature equal to 35 °C,
Figure 6d shows an immediate drop in the hot-side temperature when employing the semi-empirical model because of the greater potential for heat transfer due to the larger temperature difference. In this case, the solution-side temperature at the PHE outlet using the present model is 2.3 °C lower than that of the measured value, whereas the outlet temperature obtained with the model described in [
14] is 3.2 °C below the measured value. In addition,
Figure 6a,d shows that the water-side temperatures at the PHE absorber outlet follow a linear trend in both models, however, the present model approach was closer to the measured value.
As regards
Figure 6b,e, the outlet concentration estimated with the model described in [
14] is closer to the measured values in comparison to that of the semi-empirical model. It is then observed that the semi-empirical model tends to overestimate the solution concentration at the PHE absorber outlet, however, errors do not surpass 1.3%. Furthermore,
Figure 6c,f presents the thermal load distribution along the control volumes of the PHE. Results show that both models predicted similar thermal load trends along the PHE, however, the thermal loads at the PHE outlet estimated with the semi-empirical model are closer to those of the measured values.
The total absorption mass flux obtained from the semi-empirical model and that calculated from the experiments present relative differences of 1.4% and 17.6%, at heat dissipation temperatures of 35 and 40 °C, respectively. For the thermal load, these relative differences are around 8.7% and 4.6%, at heat dissipation temperatures of 35 and 40 °C, respectively. Regarding the procedure described in [
14], the relative differences of the total absorption mass flux with respect to the experimental values are around 11.2% and 16.8%, at heat dissipation temperatures of 35 and 40 °C, respectively. For the thermal load, these relative differences are around 16.7% and 24.9%, at heat dissipation temperatures of 35 and 40 °C, respectively.
In general, the estimations of the absorption mass flux and thermal load with the semi-empirical model were sufficiently close to the measured values. Although the liquid–vapor bubble interface area was not considered, approaches achieved were satisfactory.
3.3. Artificial Neural Network Results
In this subsection, the neural network model configuration and results are presented. As mentioned in
Section 2.3, six input parameters at the absorber inlet were selected: absorber pressure (
PSol), solution temperature (
TSol), solution mass flow rate (
ṁSol), solution concentration (
xSol), water-side temperature (
TCw), and water-side flow rate (
VCw). As output parameters, three performance parameters were selected to assess the NH
3 absorption phenomenon: the solution-side heat transfer coefficient (
hSol), the absorption mass flux (
FAB), and the solution-side mass transfer coefficient (
km). The ANN model was designed in three steps: learning, validation, and evaluation of the model. The learning step included training and design of the neural network. Moreover, the back-propagation technique was used for the ANN training. The training process finished when the relative difference between the ANN output data and the measured values (target) corresponded to the tolerance set. Different network designs were tested to obtain the best correlation between the output data and the targets, and the minimum number of neurons. Therefore, each ANN design was assessed using the linear regression coefficient (R
2) and the root mean square error (rmse).
Figure 7 shows the final structure design of the ANN used to assess the H-type plate bubble absorber performance. Training results showed that a neural network employing a hidden layer with five neurons is a suitable structure for a satisfactory prediction of the selected parameters. As a result, a 6-5-3 ANN structure was defined as shown in
Figure 7. Therefore, it consists of six neurons in the input layer, five neurons in the hidden layer, and three neurons in the output layer. When the number of processing neurons was reduced to fewer than five, the linear regression coefficient dropped. In addition, when the number of neurons was increased, no improvement in the linear regression coefficient was obtained. For instance, when the number of processing neurons was set to four, the linear regression coefficient dropped to 0.9096, 0.9429, and 0.8561, for the absorption mass flux, solution heat transfer coefficient, and mass transfer coefficient, respectively. By comparison, when the number of processing neurons was set to six, the linear regression coefficients were 0.9735, 0.9401, and 0.8968, for the absorption mass flux, solution heat transfer coefficient, and mass transfer coefficient, respectively.
Equation (19) was used to predict the selected parameters for the evaluation of the NH
3 absorption process in the H-type PHE. In this equation,
i refers to the inputs (
i = 6),
j refers to the neurons defined in the hidden layer (
j = 5), P
i refers to the input “
i” normalized, IW is the weight matrix in the hidden layer, LW is the weight matrix in the output layer,
b1 and
b2 refer to the bias in hidden and output layers, respectively;
a refers to the output parameters and
o refers to the selected output. For instance,
o = 1 stands for the output a
1 =
FAB,
o = 2 to
km,
o = 3 to
hsol.
Table 3 shows the results from the ANN training process to model the selected parameters which allow assessment of the plate bubble absorber. It contains the weights and biases of the ANN finally resulting from the simulation study. Equations (20) to (25) show a sample of the calculations conducted for the output parameter 1 (
o = 1). Parameter 1 refers to the absorption mass flux (
FAB). Therefore, this output depends on the inputs, the weights, and the biases as shown below:
where
n1,
n2,
n3,
n4, and
n5 are determined from Equations (21) to (25).
The experimental and estimated values using the present model were contrasted to establish the model prediction accuracy.
Figure 8 shows the estimated or correlated data vs experimental data for each output parameter (
FAB,
hsol, and
km). The black lines represent the trends of the results. The results evidenced a satisfactory correlation between the experimental and simulated data. This highlights that the ANN developed is suitable for estimating the selected parameters to assess the PHE absorber.
The ANN model can represent the collected data with average deviations of 4.26%, 4.2%, and 1.74%, for the absorption mass flux, solution heat transfer coefficient, and mass transfer coefficient, respectively. Moreover, the ANN can satisfactorily predict 97% of absorption mass flux data at relative differences below 10%. Similarly, the ANN model can predict 90% and 97% of the solution heat transfer coefficient and mass transfer coefficient data, respectively, at relative differences below 10%. Values of the corresponding fit parameter, R
2, of the ANN model are indicated in
Figure 8.
3.4. Heat and Mass Transfer Rates Comparison
In this sub-section, the results of the absorption phenomenon in the H-type PHE using the semi-empirical model (Mod) and the ANN model (ANN) are contrasted with the available experimental results (Exp). This analysis was carried out under the same conditions; see
Table 2. These conditions of operation correspond to those of a single effect absorption cooling system with NH
3/LiNO
3 driven by low-temperature heat sources at a chilled-water temperature of 5 °C.
Figure 9 shows that the semi-empirical and ANN models follow similar trends to those of experimental results. In addition, uncertainty errors for the experimental results are shown with bars with a resulting maximum value of ± 8% following the procedure recommended by the National Institute of Standards and Technology [
50].
Figure 9 also presents the influence of the water-side temperature, solution-side mass flow, and water-side volumetric flow rate on the absorption mass flux and thermal load in the PHE. Furthermore, results in
Figure 9a,c were collected at a water-side volumetric flow rate of 268 L·h
−1, and results in
Figure 9b,d were obtained at a solution-side mass flow of 40 kg·h
−1.
Experimental results in
Figure 9a,c correspond to water-side temperatures of 35 and 40 °C, and solution-side mass flows ranging from 10 to 50 kg·h
−1. In these figures it can be observed that when the solution-side flow increases, the absorption mass flux rises from 0.0029 to 0.0061 kg·m
−2·s
−1 and from 0.0021 to 0.0044 kg·m
−2·s
−1 at the given temperatures, respectively. Moreover, the thermal load varied from 4.84 to 13.08 kg·m
−2 and from 3.38 to 7.56 kg·m
−2 for the same temperatures, respectively.
Experimental results in
Figure 9b,d correspond to water-side temperatures of 35 and 40 °C, while the water-side flow ranges between 130 and 450 l·h
−1. In these figures can be noted that when the water-side flow increases, the absorption mass flux rises from 0.0056 to 0.0064 kg·m
−2·s
−1, and from 0.0033 to 0.0044 kg·m
−2·s
−1 at the specified temperatures, respectively. Thermal load varies between 10.31 and 13.2 kW·m
−2, and between 6.02 and 7.97 kW·m
−2 at the specified temperatures, respectively.
Results from the present study show that when the solution-side flow rises at the given values, the absorption process and heat transfer are positively affected in the corrugated PHE. This effect is obtained by the improvement in the solution and ammonia vapor mixing when increasing the solution flow regimen. Because the absorption process is exothermic, the higher the process, the more heat is released to the water-side and thus, the thermal load increases. It can also be observed that the vapor absorption improves as the water-side temperature at the PHE inlet decreases. This effect is associated with the improvement in the absorption and heat transfer potential; that is, the absorption capacity is enhanced when excess heat is released from the absorption process to the cooling water, allowing the solution to remain subcooled. As a result, this solution sub-cooling extends the difference between the current state and equilibrium state, and therefore, the solution can continue absorbing ammonia vapor. Regarding the effect of the water-side flow, only a slight increase in the heat and mass transport is observed. Therefore, the overall heat transfer coefficient is controlled by the solution-side heat transfer coefficient.
In general, the maximum and average relative differences between the semi-empirical and experimental models were 15.8% and 6.0%, respectively, for the absorption mass flux. In addition, 83.3% of the data showed a relative difference below 10.0%. In the case of the thermal load, the maximum and average relative differences were 12.5% and 6.4%, respectively. Results also showed that 86.7% of the data presented a relative difference below 10.0%.
Figure 9 also shows that the relative differences between results from the experimental study and the semi-empirical models are more pronounced at a water-side temperature of 35 °C.
Predictions of the artificial neural network showed that the maximum and average relative differences between the ANN model and experimental results were around 10.8% and 4.3%, respectively, for the absorption mass flux. In addition, 90% of the data evidenced a relative difference below 9.0%. In the case of the thermal load, the maximum and average relative differences were 11.3% and 1.3%, respectively. Results also showed that 97% of the thermal load data presented a relative difference below 9.0%.
Results confirmed that the semi-empirical model is suitable for estimating temperatures and concentration at the inlet and outlet of each partial control of volume in the PHE absorber, in addition to heat and mass transfer. As in the case of most heat and mass transfer models, this model requires the thermodynamics properties of the fluids and dimensions of the bubble absorber under study as inputs. Alternatively, the ANN model can estimate the absorption process phenomenon in the PHE absorber with lower errors compared to the semi-empirical model. Although internal details of the absorption process phenomenon are not needed, the ANN model is not suitable for the prediction of internal parameters, such as temperature and pressure profiles, or local heat and mass transfer details. It is finally highlighted that the ANN is a more effective method for prediction and control of the absorption process performance parameters in the studied configuration compared to the semi-empirical method. Furthermore, the semi-empirical method is preferable depending on the levels of internal/local heat and mass transfer details requirements. Finally, it is worth noting that, because the semi-empirical model uses dimensionless correlations, it could be adapted to other working fluids and slight variations in the absorber geometry, whereas the ANN model is specific to the configuration investigated in the present paper and within the ranges provided for the training process (see
Table 1 and
Table 2) and thermophysical properties of NH
3/LiNO
3.
4. Conclusions
This paper presented the development and comparison of two models, a one-dimensional semi-empirical model and an ANN model, designed and developed to quantify the heat and mass transfer in an H-type PHE in bubble mode employing a NH3/LiNO3 mixture.
Correlations to estimate the solution-side heat transfer coefficient, mass transfer coefficient, and water-side heat transfer coefficient are proposed. Results from the numerical models, the semi-empirical and ANN models, were contrasted with experimental results and indicated the proposed approach was suitable. Moreover, the semi-empirical model provided a reasonable approach to internal temperature and concentration details; for instance, temperature and concentration at the PHE outlet were sufficiently close to the results obtained by experiment. Moreover, the ANN model allowed better estimation of the overall heat and mass transfer in the studied bubble absorber compared to that of the semi-empirical model. In addition, one of the advantages of the ANN is that there is no need for internal details of the absorption process and thermophysical properties, however, its application is limited to the configuration studied.
Results showed that the semi-empirical model was able to predict the absorption mass flux and thermal load with maximum differences of 15.8% and 12.5%, respectively, relative to the experimental results. In the case of the ANN model, the maximum relative difference was 10.8% and 11.3% for the absorption mass flux and thermal load, respectively. Moreover, the semi-empirical model is preferable when more details of the internal mass absorption of the absorber are needed.
Finally, results showed that the correlations developed and proposed provided a good prediction of local heat and mass transfer along the absorber. Analysis of the simulation results also demonstrated that both models can be practically applied to the design of bubble plate absorbers with NH3/LiNO3 mixtures.