1. Introduction
The Oman Investment Authority started to invest in green hydrogen plant productions. It announced four projects with a total capacity of around 30 gigawatts (GW) of renewables to support green hydrogen production [
1]. The Al Wusta and Dhofar governorates will be the sites of these projects. The excellent wind and solar resource availability in both areas is anticipated to lower the net levelized cost of energy and, as a result, the levelized cost of hydrogen, which will become very competitive in Oman. The biggest one (the Gio project) will be powered by 25 GW of wind and solar energy [
2]. It will be located in the Al Wusta governorate with a total investment of USD 30 bn. Construction is planned to start in 2028. The Gio project will be built in stages and will reach its full capacity by 2038. The second project, Hyport Duqm, will be located in Duqm, Al Wusta, with a total capacity of 1.3 GW and is expected to produce 1 million metric tons per annum of green ammonia when it fully operates [
3]. The third and fourth projects will be in the Dhofar governorate with around 3 GW capacity.
Renewable energy systems are typically used with backup power production, such as diesel generators or batteries, for off-grid applications because of the intermittent nature of renewable energy sources and their low reliability. Due to the fluctuating cost of fuel and the challenges associated with delivering gasoline to some remote and rural regions, additional solutions are being used, such as biofuel generators and fuel cells with hydrogen production [
4].
The main advantages of hydrogen are its high energy storage capacity and that it can store energy for a longer time and in different forms. There are various studies in the literature that focus on how hydrogen can be one of the most effective ways of generating energy which leads to a better-improved environment and long-term sustainability [
5,
6,
7]. The most popular method for producing hydrogen is natural gas steam reforming; however, it emits a lot of greenhouse gases. Nearly half of the world’s hydrogen supply originates from natural gas steam reforming, with the remaining percentages coming from oil reforming, coal gasification, water electrolysis, and other sources [
8]. To counteract the negative consequences of fossil fuels, hydrogen should be produced from abundant, clean sources utilizing environmentally beneficial methods [
9,
10]. This concept is defined as “green hydrogen production”. In the literature, a number of scholars have looked into the production of hydrogen using water and renewable energy sources. High-temperature water dissociation, thermochemical water splitting, water electrolysis, and water photolysis were all studied by Lodhi [
11]. After that, Lodhi defined the main green sources for producing hydrogen as solar, wind, nuclear, hydro, and sea/ocean energy [
12]. Methods for producing hydrogen can be characterized as “green” depending on the primary energy source and/or the material employed [
13]. Green sources for hydrogen production include fresh and seawater, biomass, and hydrogen sulfide [
12].
The most fundamental commercial technology for producing nearly pure hydrogen is water electrolysis, and its significance is expected to increase in the future [
14]. Electron flow supported by an external circuit is the foundation of water electrolysis. Alkaline, polymer membrane, and solid oxide electrolyzers are the three basic electrochemical hydrogen generating technologies. The efficiency of an electrolysis cell is determined by the ideal and real energy needed to drive the reaction [
14]. Catalysts are used to boost the current density and rate of the electrolysis reaction. One of the most often utilized heterogeneous catalysts is platinum, which is used by coating electrode surfaces with it. Due to their reduced price and rapid turnover rate, homogeneous catalysts can also be utilized during electrolysis [
15]. Desalination and demineralization are required before the electrolysis process due to electrolyzers’ high sensitivity to water purity. In an electrolyzer, for instance, chlorine is more likely to be created than oxygen when brine (or seawater) is injected into the device [
16]. The literature discusses a number of strategies for halting unwanted side reactions (such as the chlorine evolving reaction) during electrolysis. One of these is the desalination of water using ion-selective membranes [
17]. Additionally, hydrogen is seen as a crucial energy source in the sustainable energy plan that will defeat the problems of cheap oil, the depletion of natural resources, and global warming [
18]. This is due to the fuel’s energy efficiency and low environmental impact [
19]. When burned with air, it emits water and a negligible amount of NO
x, having the highest energy content by weight of all traditional energy sources [
20]. Hydrogen has the capacity to store massive amounts of energy, such as terawatt-hours of volume, over extended periods of time in a variety of forms, even though it may not be a competitive solution for short-term storage [
21]. Additionally, although the idea of a “hydrogen economy” was first proposed in 1972, it has only been in recent years that the cost of every step in the value chain has come down enough to make hydrogen a viable economic option [
22]. The primary factors driving the change in the costs of the hydrogen value chain are the sharp decline in solar and wind energy costs as well as the ongoing commercialization of electrolyzers, fuel cells, and supporting infrastructure [
23,
24]. Furthermore, a global demand and supply chain is being actively developed by Japan, China, South Korea, and Germany, which lowers the cost of the hydrogen value chain [
22].
The benefits of using hydrogen in energy production can be summed up as follows [
23]:
It can be produced utilizing renewable energy sources from freshwater, seawater, or wastewater;
It has high energy conversion efficiency;
It has a high heating value;
No CO2 emission occurs if it is used in fuel cells or combusted;
It can be converted into different fuels such as methanol, ethanol, and ammonia;
It can be stored for a long time using various storage alternatives.
In order to contribute to a society without carbon emissions, this research examines the viability of substituting diesel fuel with clean and sustainable fuel utilizing the HOMER Pro software [
24]. Finally, based on both economic and environmental considerations, an ideal system is selected from among four other alternatives.
2. A Summary Comparison between Hydrogen Storage and Other Storage Methods
Large-scale energy storage is one way to enhance the stability of electric power systems, especially with more penetration of renewable energy sources. Pump hydro and compressed air are among various types of economically viable energy storage systems, but they need special geographical locations. Redox flow batteries are one of the most promising grid-scale energy storage devices. They are cost-effective batteries with fast response times and long cycle lives, and they have a flexible and scalable modular design with decoupled electrolyte and electrode materials. Their disadvantages are their low energy density due to low solubility and narrow cell voltage [
25]. Recent developments with the employment of redox-active organic materials have provided the way for high-energy-density batteries [
26,
27]. Although batteries can store energy, they are not economically feasible for long-term and large-scale storage [
28].
Another method of energy storage is using Lion batteries, which are applied in most portable electronics and grid-scale storage systems owing to their fast charging, high energy density, long cycle life and wide operating temperature range [
29]. However, there are serious safety concerns about this type of battery. Several research papers were published to enhance their safety through methods such as fire retardants in electrolytes [
30], fire retardant encapsulation by a polymer [
31] and fireproof, ultralight-weight polymer-polymer solid-state electrolytes [
32].
Another form of large-scale energy storage is a regenerative fuel cell, in which the energy is stored as hydrogen gas. One of the most severe challenges of hydrogen storage is safety. The advantage of hydrogen is that it is a low polluting, clean fuel with high energy density, a low rate of self-discharge (good for seasonal storage), a lower cost compared with battery storage [
33], and the ability to be stored in different forms such as gases, liquids, solids and chemicals. The main drawback of this method is the low round trip efficiency (ratio of total electrical energy returned by the device to the total energy consumed by the system for the lifetime) compared with lithium-ion batteries [
33].
Large-scale hydrogen storage can take different forms, including densified storage via compressed gas and liquid hydrogen (such as storage vessels, geological storage and other underground storage); circular hydrogen carriers (mainly ammonia and methanol); and liquid organic molecules [
34]. Liquid organic molecules have advantages because of their low cost and compatibility with existing fuel transport infrastructure [
34]. Furthermore, solid-state hydrogen storage technology is a promising storage method owing to its high-volume hydrogen capacity and safety, such as seen in metal hydride (MH) [
35].