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Article

Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils

1
Department of Machine Construction and Materials, Faculty of Marine Engineering, Maritime University of Szczecin, ul. Willowa 2, 71-650 Szczecin, Poland
2
Department of Power Engineering, Faculty of Marine Engineering, Maritime University of Szczecin, ul. Willowa 2, 71-650 Szczecin, Poland
3
Institute of Mathematics, Physics, and Chemistry, Maritime University of Szczecin, ul. Wały Chrobrego 1-2, 70-500 Szczecin, Poland
*
Author to whom correspondence should be addressed.
Energies 2024, 17(19), 4908; https://doi.org/10.3390/en17194908
Submission received: 7 August 2024 / Revised: 13 September 2024 / Accepted: 26 September 2024 / Published: 30 September 2024
(This article belongs to the Section J: Thermal Management)

Abstract

:
This paper proposes a simple analytical method for determining the viscosity index (VI) that effectively aligns with results obtained from the applicable standards. This method simply needs the kinematic viscosity of the tested oil at 40 and 100 °C as input parameters and does not need to use tables that are an integral part of the mentioned standards. This work presents a method and evaluates the accuracy of determining auxiliary parameters in the form of kinematic viscosity values at 40 °C for two hypothetical oils. These oils have a kinematic viscosity at 100 °C equal to that of the oil under testing and have VI = 0 and 100. The relative fitting error percentage and the coefficient of determination are found for the specified auxiliary indicators. The method is validated using data obtained from previous studies in the form of the kinematic viscosity of lubricating oil–diesel mixtures. The mixtures of viscosity grades SAE 30 and SAE 40 lubricating oil with diesel oil at concentrations of 0, 1, 2, 5, 10, 20, and 50% w/w are tested. The viscosity index for each mixture is determined using a standard-based manual calculation using the Anton Paar viscosity index calculator and the proposed method. The results obtained from the proposed analytical method are compared with those from two other methods. The maximum percentage relative fitting error (δmax ≈ 1%) and the coefficient of determination (R2 > 0.999) are determined. The obtained results demonstrate a very good fit and, thus, confirm the usefulness of the proposed approach.

1. Introduction

Viscosity is a critical characteristic of fluids (liquids and gases) and plastic solids, representing their internal friction resulting from the movement of fluid layers during flow. Dynamic viscosity and kinematic viscosity are distinguished from each other [1]. Dynamic viscosity ηt (Pa·s) represents the shear stress ratio τ (kg/m) to the shear rate γ ˙ (1/s), while the kinematic viscosity at a given temperature t is the ratio of the dynamic viscosity ηt (Pa·s) to the fluid density ρt(kg/m3) [2]. The liquid parameters are analyzed in the subsequent parts of this article.
The viscosity of liquids decreases with increasing temperature t (°C), which is due to an increase in the energy of the liquid particles and the velocity of the liquid layers, thus reducing the contact time of the particles [3]. The shorter interaction time is equivalent to a reduced internal friction resistance. For dynamic viscosity, this change is described by the Arrhenius–Guzman relationship given by the following formula [4,5]:
η t = A · e E R C T ,
where A is dependent on the mass and molar volume, a constant characteristic for a given liquid, ΔE is the viscous flow activation energy, RC = 8.31446261815324 J·mol−1·K−1 is the Clapeyron gas constant, and T (K) is the absolute temperature (T = t + 273.15).
During engine operation, lubricating oil ages and becomes contaminated, leading to a change in its viscosity. The appropriate viscosity of the oil is obtained within the set temperature range at which the oil is operated. The temperature varies in different areas of the engine, resulting in a change in oil viscosity. It is, therefore, important that the change in viscosity be as small as possible [1]. This ensures that changes in oil temperature will induce correspondingly small changes in the rheological properties of the oil and ensures the smallest possible changes in the thickness of the lubricating film that the lubricating oil creates at the tribological nodes [6].
The standardized oil viscosity at reference temperatures makes it possible to classify oils by determining their viscosity at reference temperatures. For instance, the ISO Technical Committee (TC23) has defined 20 viscosity grades labeled as ISO VG [7], with the grade number representing a rounding to the nearest integer of the average kinematic viscosity expressed in units of mm2/s (cSt) measured at 40 °C, allowing for a viscosity tolerance of ±10% relative to the average.
Another commonly used viscosity classification is the J300 classification [8], which groups oils into summer oil and winter oil viscosity grades. Oils that simultaneously meet a certain summer and winter grade are multi-season oils. Assigning a particular oil to a specific summer grade is determined by the oil’s kinematic viscosity (mm2/s) at 100 °C, which must fall within a specified range, and the minimum dynamic viscosity value is expressed in units of mPa·s at 150 °C. Winter oils are classified based on minimum kinematic viscosity expressed in mm2/s at 100 °C and two specific dynamic viscosities (mPa·s); namely, the maximum low-temperature cranking viscosity at a standardized temperature and low-temperature pumping viscosity with no yield stress at a standardized temperature.
Since the viscosity of the oil changes with temperature, it is important that the oil used in the engine be of adequate viscosity grade but also exhibit the least possible viscosity changes due to changes in oil temperature [9]. A previous paper [10] presents the viscosity–temperature coefficient (VTC) developed based on ref. [11], which can be defined as the relative decrease in kinematic viscosity (mm2/s) of the tested oil U and Y determined at 40 °C and 100 °C, respectively, relating to the viscosity U as given by the relationship:
V T C = U Y U ,
However, the mentioned index does not capture the exponential variation of viscosity as a function of temperature. The use of indicators determining the viscosity quotient at two different temperatures or the viscosity coefficient calculated as the difference in viscosity at two temperatures divided by the average value of these two viscosities is similarly limited [2]. Therefore, the variation of viscosity with temperature is commonly described by the viscosity index. This parameter is arbitrary and is based on the kinematic viscosity of the oil at 40 and 100 °C, as well as the kinematic viscosity at 40 °C of two hypothetical oils that have a kinematic viscosity at 100 °C equal to that of the oil being tested at 100 °C (a hypotetic oil with = 0 and a hypotetic oil with VI = 100). Lubricating oils of the same viscosity grade may exhibit varying viscosity index values, as depicted in Figure 1. The smaller the oil’s viscosity index, the greater the change in viscosity with temperature.
The standard procedure for determining the viscosity index of the tested oil in accordance with ASTM D2270 [12] and ISO 2909 [13] is presented in the form of an algorithm in Appendix A Figure A1. The procedure consists of the following steps:
1.
Determination of the kinematic viscosity values at 40 °C of two hypothetical oils that have a kinematic viscosity at 100 °C equal to the kinematic viscosity of the oil under testing at 100 °C. The kinematic viscosity at 40 °C is determined for oil with a conventionally assigned viscosity index of 0 (VI = 0), labeled L, and for oil with a viscosity index of 100 (VI = 100), labeled H. According to the aforementioned viscosity standards, for a test oil with a kinematic viscosity at 100 °C labeled Y, which is greater than 2 mm2/s and smaller than 70 mm2/s, the values of L and H are read from a table that is an integral part of the standard. If the oil under testing has Y greater than 70 mm2/s, the values of L and H are calculated based on the following relationships:
L = 0.8353 s m m 2 · Y 2 + 14.67 · Y 216 m m 2 s ,
H = 0.1684 s m m 2 · Y 2 + 11.85 · Y 97 m m 2 s ,
2.
Determination of viscosity index values based on functions of the viscosity of the tested oil U at 40 °C for oil with a viscosity index less than or equal to 100, or functions of the viscosity of the tested oil U and Y at 40 °C and 100 °C, respectively, for oil with a viscosity index greater than 100. The viscosity index can be calculated using the following formula:
V I = L U L H · 100 ,    ,  if  V I 100 100 + a n t i l o g log H log U log Y 1 0.00715 ,  if  V I > 100 ,
In most cases, the mentioned procedure requires the use of a table and interpolation for the read values of L and H, which results in an approximation error. Online calculators are available to determine the viscosity index. Among the most popular calculators that help calculate the viscosity index are the Anton Paar tools [14], Ölezol [15], Evonik [16], Kluber Lubrication [17], or TriboNet [18]. However, these tools employ various interpolation methods and have different precisions in calculating relationship (9), leading to discrepancies in the results obtained using each of these tools. Furthermore, the calculators operate with various ranges of input data, and some restrict the input to only integers.
Given the limitations associated with determining the viscosity index and the challenge of describing the relationships provided in the tables of the mentioned standards, the authors have proposed a simplified method for roughly estimating the viscosity index. This method is based on a model that approximates the values L and H as functions f(Y) and g(Y) which depend on the viscosity of the tested oil at 100 °C.
The method presented in the article is based on the indicators proposed in ASTM D2270 and ISO 2909 standards and uses viscosity at 40 °C and 100 °C to determine the viscosity index. However, the proposed method does not require the use of reference oil tables indicated in the mentioned standards. The difference between these approaches is demonstrated in Appendix A. The proposed method shows a very small error, and, thus, it may be practical for use. It can be implemented in online lubricant oil quality assessment systems [19,20], for example, to monitor the dilution of lubricant oil with diesel oil during operation. One of the problems that may arise during the operation of internal combustion engines is the dilution of lubricant oil with diesel fuel. The authors have analyzed this issue in several previous publications [21,22]. Research has shown that the dilution of lubricant oil with fuel can not only accelerate destructive processes occurring in the engine but also increase the risk of explosions in the engine’s crankcase [23,24]. This is due to the complex interaction associated with the formation of hot spots and the increased volatility of fuel-diluted lubricant oil [22]. One of the methods considered in previous studies to assess the degree of lubricant oil dilution with diesel fuel is the analysis of changes in lubricant oil viscosity during operation. However, viscosity depends not only on the chemical composition of the fluid but also on temperature. This article expands on these analyses and presents earlier results as an example of the application of the method proposed in this article.

2. Materials and Methods

Based on the presented assumptions and the recommendations outlined in the standards, the auxiliary functions required to determine the viscosity index are plotted, which are based on the following:
L = f ( Y ) ,
H = g Y ,
Graphs of the Functions (6) and (7) are depicted in Figure 2.
To achieve a strong model fit, the authors suggest using 5th-degree polynomials in the following form:
L = a 1 · Y 5   +   a 2 · Y 4   +   a 3 · Y 3   +   a 4 · Y 2   +   a 5 · Y   +   a 6 ,
H = b 1 · Y 5   +   b 2 · Y 4   +   b 3 · Y 3   +   b 4 · Y 2   +   b 5 · Y   +   b 6 ,
where: a1  s 4 m m 8 , a2  s 3 m m 6 ,   a3  s 2 m m 4 , a4  s m m 2 , a5 (–), a6  m m 2 s , b1  s 4 m m 8 , b2  s 3 m m 6 ,   b3  s 2 m m 4 , b4  s m m 2 , b5 (–), and b6  m m 2 s are the coefficients of approximating equations.
To reduce the fitting error of models (8) and (9), a spline function consisting of three input size ranges is utilized. These are given as follows:
1.
The range of the lowest values of kinematic viscosity of the tested oil falling within 2.1 mm2/s ≤ Y < 6.7 mm2/s. The limit value of 6.7 is adopted for the accuracy of the model approximating the median range of kinematic viscosities indicated in the tables of the ASTM D2270 and ISO 2909 standards, below which the value of the relative percentage error of the proposed models is greater than 3%, which the authors adopted as the limit value.
2.
The range of medians of kinematic viscosity of the tested oil is 6.7 mm2/s ≥ Y ≤ 70.0 mm2/s.
3.
The range of highest kinematic viscosity values of the tested oil Y > 70.0 mm2/s is modeled by relations (3) and (4) (the range is derived from models indicated explicitly in ASTM D2270 and ISO 2909).
The analysis of the accuracy of the models’ representation of empirical data was carried out in accordance with a previously developed approach. For each model, for all points in each of the analyzed ranges, the model determination coefficient R2 (–) and the relative percentage error δi (%) is determined for each value i = 1, 2, … n in line with the following equations:
R 2 = i = 1 n ( x ^ i x ¯ ) 2 i = 1 n ( x i x ¯ ) 2 ,
δ i = x i x ^ i x i · 100 % ,
where xi is the i-th value of the analyzed parameter x (viscosity or viscosity index) adopted as an exact value,   x ^ i is the i-th value of x determined based on the model, and x ¯ is the arithmetic mean of x values determined on the basis of the model.
The calculations were performed using Matlab R2024a software (MathWorks, Natick, MA, USA).

3. Results and Discussion

As a result of analyzing the values L or H indicated in the standards and for the assumptions made, the approximating coefficients for Equations (8) and (9) are determined, which provide the best fit in each of the analyzed ranges. The coefficients of the approximating equation are shown in Table 1 and Table 2. An algorithm for calculating VI based on models (8) and (9) and the determined coefficients are shown in Appendix A Figure A2.
Figure 3 shows, for models (7) and (8) with the coefficients shown in Table 1 and Table 2, the calculated relative error of model fitting compared to the values shown in ASTM D2270 and ISO 2909.
The maximum value of the fitting error is calculated for each of the analyzed ranges. The calculated coefficients of determination and maximum values of the relative percentage error of estimation for the proposed models are summarized in Table 3.
The obtained values of the coefficient of determination indicate a very good to complete fit of the proposed models, while the values of the relative percentage model fitting error over almost the entire range of kinematic viscosity of oil (≥2 mm2/s) are less than 2%, which is sufficient for the purpose of a preliminary or rough calculation of the viscosity index.

4. Example Application of the Model

To verify the suitability of the proposed approach for determining the viscosity index of lubricating oils of known kinematic viscosity at 40 and 100 °C, VI values calculated using the proposed approach and values calculated manually according to ASTM D2270 and ISO 2909 are compared. This is undertaken for an example of two datasets derived from viscosity measurements of mixtures of two single-season lubricating oils of viscosity grades SAE 30 and SAE 40 with diesel oil at concentrations of diesel oil in mixtures equal to 0, 1, 2, 5, 10, 20, and 50% w/w. As the viscosity values of the various mixtures change, the example presented is representative due to the possibility of assigning the mixtures tested to different viscosity grades, as shown in Table 4. The kinematic viscosity ranges at 40 °C of petroleum products belonging to the various ISO VG grades are presented in the literature on the subject [25].
The results obtained using this analytical approach are compared with those calculated manually according to the mentioned standards [12] and those calculated using the Anton Paar calculator [14]. Measurement data for validation are taken from a previous study [22] which used Emi/Agip Cladium 120 SAE 30 CD/CF [26] and Emi/Agip Cladium 120 SAE 40 CD/CF [27] lubricating oils and Orlen Efecta Diesel Bio (designation CN27102011D) [28] diesel oil complying with ZN-ORLEN-5 [29]. The variation in viscosity for the mixtures tested as a function of diesel oil concentration and temperature is shown for SAE 30 and SAE 40 grade oil mixtures in Figure 4 and Figure 5, respectively. The variation of viscosity index values depending on the composition of the mixture is shown in Figure 6.
Table 5 and Table 6 show a comparison of the viscosity index values calculated using three different methods for mixtures of SAE 30 and SAE 40 viscosity-grade lubricating oil with diesel oil. The viscosity index is calculated manually using the method described in the standards, the Anton Paar calculator, and the algorithm proposed in this article. The percentage relative error of estimation using the proposed model compared to the other two methods is also presented, assuming that the other mentioned methods are treated as VI exact values.
For mixtures of SAE 30 grade lubricating oil with diesel fuel, the maximum error in the tested measurement range is 1.02% when comparing the results obtained from the proposed analytical model to those attained using the Anton Paar calculator. In contrast, comparing the results of the analytical model application with a manual calculation based on standards yields a maximum percentage error of fitting of 1.12%. In turn, the coefficient of determination is determined for the sets of viscosity index values obtained by each method. When comparing the results from the model application to those from the Anton Paar calculator, the coefficient of determination R2 is 0.9995. Similarly, when comparing the results from the model application to those obtained by manual calculations according to ASTM D2270/ISO 2909, the coefficient of determination is R2 = 0.9993.
For mixtures of SAE 40 grade lubricating oil with diesel oil, fitting the results of the analytical model application to the other two methods yields maximum relative error results of 0.89% and 0.77%, respectively. In turn, the coefficient of determination is determined for the sets of viscosity index values obtained by each method. When comparing the results from the model application to those from the Anton Paar calculator, the coefficient of determination R2 is 0.9999. Similarly, when comparing the results from the model application to those obtained by manual calculations according to ASTM D2270/ISO 2909, the coefficient of determination is R2 = 0.9999.

5. Conclusions

The application of the method presented in this article showed that the proposed approach for the empirical data set analyzed provides a very good fitting between the results of the calculated VI value and those obtained by manual calculation based on the tables contained in ASTM D2270/ISO 2909 and by using the Anton Paar calculator.
The analytical method for calculating the viscosity index can be applied to the study of mixtures of lubricating products and fuels, particularly in examining the properties of their mixtures. For example, this method can be used to analyze lubricating oils enriched with suitable additives, lubricating oils diluted with fuel, and mixtures of various types of fuels.
The calculators of viscosity index use the tables provided in ASTM D2270 and ISO 2909 standards. While this approach is sufficient for calculating a single viscosity index value, algorithmic methods, including the one proposed in this article, may be more useful for applications in continuous oil quality monitoring systems.
The proposed method can be further refined in future work by increasing the number of ranges for which separate values of polynomial coefficients are determined to calculate L and H, which are intermediate indicators used to calculate viscosity index values.

Author Contributions

Conceptualization, L.C.; methodology, L.C.; software, L.C., M.S., K.Ć. and K.M.; validation, L.C., M.S., K.Ć. and K.M.; formal analysis, L.C., M.S., K.Ć. and K.M.; investigation, L.C., M.S., K.Ć. and K.M.; resources, L.C., M.S., K.Ć. and K.M.; data curation, L.C.; writing—original draft preparation, L.C. and M.S.; writing—review and editing, L.C., M.S., K.Ć. and K.M.; visualization, L.C. and M.S.; supervision, L.C.; project administration, L.C.; funding acquisition, L.C. All authors have read and agreed to the published version of the manuscript.

Funding

This research was partly funded by the Ministry of Science and Higher Education (MEiN) of Poland, grant number 1/S/KPBMiM/24.

Data Availability Statement

All data is available in this paper and the dataset Chybowski, L. Lube oil—diesel oil mixes—dataset; 2022, Ver. 3, https://doi.org/10.17632/scbx3h2bmf.3. Dataset is available at https://data.mendeley.com/datasets/scbx3h2bmf/3.

Acknowledgments

Laboratory tests were performed at the Center for Testing Fuels, Working Fluids, and Environmental Protection (CBPCRiOS) of the Maritime University of Szczecin. 3D graph plotting was supported by the Matlab script prepared by Przemysław Kowalak.

Conflicts of Interest

The authors declare no conflicts of interest. The funders had no role in the study’s design, in the collection, analyses, or interpretation of data, in the writing of the manuscript, or in the decision to publish the results.

List of Abbreviations and Symbols

Aempirical parameters for determining dynamic viscosity
a1, a2, a3, a4, a5, a6coefficients of equations approximating the viscosity L
ASTMstandard of ASTM International, formerly known as the American Society for Testing and Materials
b1, b2, b3, b4, b5, b6coefficients of equations approximating the viscosity H
ΔEactivation energy of viscous flow
eEuler number
f(Y)empirical function to determine the viscosity L
f(Y)empirical function to determine the viscosity H
Hkinematic viscosity at 40 °C of a hypothetical oil with VI = 100, which has (at 100 °C) a kinematic viscosity equal to that of the oil under test at 100 °C
ISOInternational Organization for Standardization
Lkinematic viscosity at 40 °C of a hypothetical oil with VI = 0, which has (at 100 °C) a kinematic viscosity equal to that of the oil under test at 100 °C
RCClapeyron’s gas constant
R2coefficient of determination
SAESAE International, formerly the Society of Automotive Engineers
SAE 30, SAE 40 viscosity grades of lubricating oil according to SAE J300 standard
Tabsolute temperature in K
trelative temperature in °C
TC23Technical Committee 23 of ISO
Ukinematic viscosity of the tested oil at 40 °C
VGISO viscosity grade
VIviscosity index
VTCviscosity–temperature coefficient
xanalyzed parameter (viscosity or viscosity index)
x ¯ arithmetic mean of x determined from the model
xithe i-th value of the analyzed parameter x
x ^ i the i-th value of x determined from the model
Ykinematic viscosity of the tested oil at 100 °C
γ ˙ shear rate
δirelative percentage error
ηtdynamic viscosity at t
ρ15density at 15 °C.
ρtdensity at t
τshear stresses

Appendix A

Algorithms
Figure A1. Standard procedure for determining viscosity index according to ASTM D2270 and ISO 2909.
Figure A1. Standard procedure for determining viscosity index according to ASTM D2270 and ISO 2909.
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Figure A2. Developed analytical procedure for determining viscosity index.
Figure A2. Developed analytical procedure for determining viscosity index.
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Figure 1. Example of viscosity variation with temperature of oils belonging to the same viscosity grade ISO VG 100, having different viscosity index values (based on ref. [9]).
Figure 1. Example of viscosity variation with temperature of oils belonging to the same viscosity grade ISO VG 100, having different viscosity index values (based on ref. [9]).
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Figure 2. Relationships of the viscosity at 40 °C—of a hypothetical lubricating oil with VI = 0 and VI = 100 having the same viscosity at 100 °C as the presented test oil—as functions of the viscosity of the test oil at 100 °C.
Figure 2. Relationships of the viscosity at 40 °C—of a hypothetical lubricating oil with VI = 0 and VI = 100 having the same viscosity at 100 °C as the presented test oil—as functions of the viscosity of the test oil at 100 °C.
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Figure 3. Relative percentage error of fitting the proposed models’ L or H to the values indicated in ASTM D2270 and ISO 2909.
Figure 3. Relative percentage error of fitting the proposed models’ L or H to the values indicated in ASTM D2270 and ISO 2909.
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Figure 4. Dependence of kinematic viscosity of the tested mixtures of lubricating oil of SAE 30 grade with diesel oil on the composition and temperature of the mixture.
Figure 4. Dependence of kinematic viscosity of the tested mixtures of lubricating oil of SAE 30 grade with diesel oil on the composition and temperature of the mixture.
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Figure 5. Dependence of kinematic viscosity of the tested mixtures of lubricating oil of SAE 40 grade with diesel oil on the composition and temperature of the mixture.
Figure 5. Dependence of kinematic viscosity of the tested mixtures of lubricating oil of SAE 40 grade with diesel oil on the composition and temperature of the mixture.
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Figure 6. Viscosity index values of the tested lubricating oil–diesel mixtures from the composition, calculated in accordance with ASTM D2270/ISO 2909.
Figure 6. Viscosity index values of the tested lubricating oil–diesel mixtures from the composition, calculated in accordance with ASTM D2270/ISO 2909.
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Table 1. Coefficients of the approximating equation L, the coefficient of determination, and the relative percentage error of the model (7).
Table 1. Coefficients of the approximating equation L, the coefficient of determination, and the relative percentage error of the model (7).
Ya1a2a3a4a5a6
m m 2 s s 4 m m 8 s 3 m m 6 s 2 m m 4 s m m 2 (–) m m 2 s
6.7 > Y ≥ 2.10.0074−0.30393.7190−17.697043.6760−33.9310
70.0 ≥ Y ≥ 6.7−1.84 × 10−73.20 × 10−5−0.00250.99666.1596−12.7890
Y > 700000.835314.6700−216.0000
Table 2. Coefficients of the approximating equation H, the coefficient of determination, and the relative percentage error of the model (8).
Table 2. Coefficients of the approximating equation H, the coefficient of determination, and the relative percentage error of the model (8).
Yb1b2b3b4b5b6
m m 2 s s 4 m m 8 s 3 m m 6 s 2 m m 4 s m m 2 (–) m m 2 s
2.1 ≤ Y < 6.70.0048−0.12041.0693−3.561910.0950−6.3650
6.7 ≤ Y ≤ 70−2.20 × 10−75.03 × 10−5−0.00460.39215.5020−7.7091
Y   > 700000.168411.8500−97.0000
Table 3. Summary of indicators describing the fit of the proposed models L or H .
Table 3. Summary of indicators describing the fit of the proposed models L or H .
Range of ValuesModel LModel H
Y R2δmaxR2δmax Y
(mm2/s)(–)(%)(–)(%)(mm2/s)
2.1 ≤ Y < 6.70.9999<1.541.0000<0.242.1 ≤ Y < 6.7
6.7 ≤ Y ≤ 701.0000<1.741.0000<0.836.7 ≤ Y ≤ 70
Y   > 701.00000.001.00000.00 Y   > 70
Table 4. ISO viscosity grades of the mixtures used to verify the analytical method for determining the viscosity index.
Table 4. ISO viscosity grades of the mixtures used to verify the analytical method for determining the viscosity index.
SAE Viscosity Grade of Lubricating Oil Used
to Prepare the Mixture [8]
Diesel Oil Content in the Lubricating Oil MixtureViscosity of the Mixture at 40 °CISO Viscosity Grade of the Mixture or the Limit Grades between Which the Mixture Is Rated [7]
SAE GradeCUISO VG
(–)(% w/w)(mm2/s)(–)
SAE 300105.01ISO VG 100
198.06ISO VG 100
296.64ISO VG 100
582.70[ISO VG 68, ISO VG 100]
1059.61[ISO VG 46, ISO VG 68]
2036.25[ISO VG 32, ISO VG 46].
5011.07[ISO VG 10, ISO VG 15].
1002.897ISO VG 3
SAE 400159.90ISO VG 150
1157.95ISO VG 150
2149.10[ISO VG 100, ISO VG 150]
5123.95[ISO VG 100, ISO VG 150]
1078.71[ISO VG 68, ISO VG 100]
2050.29ISO VG 46
5013.25[ISO VG 10, ISO VG 15].
1002.897ISO VG 3
Table 5. Viscosity index values of the tested mixtures of SAE 30 grade lubricating oil with diesel oil calculated by different methods, and the percentage relative error of model fitting to other methods.
Table 5. Viscosity index values of the tested mixtures of SAE 30 grade lubricating oil with diesel oil calculated by different methods, and the percentage relative error of model fitting to other methods.
SAE 30 Grade Oil Based MixturesViscosity Index VI Determined by a MethodPercentage Relative Error between Methods
With diesel oil concentration of CManual calculation
according to ASTM D2270/ISO 2909
Calculation with Anton Paar
calculator
Calculation using an analytical modelAnalytical model vs. Anton Paar calculatorAnalytical model vs. manual calculation according to ASTM D2270/ISO 2909
(% w/w)(–)(–)(–)(%)(%)
099.2799.2898.900.380.38
197.1897.2996.460.850.74
297.4997.6296.780.860.73
5106.76106.97106.040.880.67
10111.58111.46110.331.021.12
20128.91129.17129.200.030.22
50132.37132.57132.250.240.09
Table 6. Viscosity index values of the tested mixtures of SAE 40 grade lubricating oil with diesel oil calculated by different methods, and the percentage relative error of model fitting to other methods.
Table 6. Viscosity index values of the tested mixtures of SAE 40 grade lubricating oil with diesel oil calculated by different methods, and the percentage relative error of model fitting to other methods.
SAE 40 Grade Oil Based MixturesViscosity Index VI Determined by a MethodPercentage Relative Error between Methods
With diesel oil concentration of CManual calculation
according to ASTM D2270/ISO 2909
Calculation with Anton Paar
calculator
Calculation using an analytical modelAnalytical model vs. Anton Paar calculatorAnalytical model vs. manual calculation according to ASTM D2270/ISO 2909
(% w/w)(–)(–)(–)(%)(%)
095.2595.4494.890.580.38
194.8395.0594.480.600.37
295.2195.3594.830.540.41
596.4696.3095.940.380.54
10112.44112.65111.650.890.70
20125.78125.78124.820.770.77
50142.33142.33141.670.460.46
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Chybowski, L.; Szczepanek, M.; Ćwirko, K.; Marosek, K. Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils. Energies 2024, 17, 4908. https://doi.org/10.3390/en17194908

AMA Style

Chybowski L, Szczepanek M, Ćwirko K, Marosek K. Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils. Energies. 2024; 17(19):4908. https://doi.org/10.3390/en17194908

Chicago/Turabian Style

Chybowski, Leszek, Marcin Szczepanek, Konrad Ćwirko, and Konrad Marosek. 2024. "Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils" Energies 17, no. 19: 4908. https://doi.org/10.3390/en17194908

APA Style

Chybowski, L., Szczepanek, M., Ćwirko, K., & Marosek, K. (2024). Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils. Energies, 17(19), 4908. https://doi.org/10.3390/en17194908

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