Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils
Abstract
:1. Introduction
- 1.
- Determination of the kinematic viscosity values at 40 °C of two hypothetical oils that have a kinematic viscosity at 100 °C equal to the kinematic viscosity of the oil under testing at 100 °C. The kinematic viscosity at 40 °C is determined for oil with a conventionally assigned viscosity index of 0 (VI = 0), labeled L, and for oil with a viscosity index of 100 (VI = 100), labeled H. According to the aforementioned viscosity standards, for a test oil with a kinematic viscosity at 100 °C labeled Y, which is greater than 2 mm2/s and smaller than 70 mm2/s, the values of L and H are read from a table that is an integral part of the standard. If the oil under testing has Y greater than 70 mm2/s, the values of L and H are calculated based on the following relationships:
- 2.
- Determination of viscosity index values based on functions of the viscosity of the tested oil U at 40 °C for oil with a viscosity index less than or equal to 100, or functions of the viscosity of the tested oil U and Y at 40 °C and 100 °C, respectively, for oil with a viscosity index greater than 100. The viscosity index can be calculated using the following formula:
2. Materials and Methods
- 1.
- The range of the lowest values of kinematic viscosity of the tested oil falling within 2.1 mm2/s ≤ Y < 6.7 mm2/s. The limit value of 6.7 is adopted for the accuracy of the model approximating the median range of kinematic viscosities indicated in the tables of the ASTM D2270 and ISO 2909 standards, below which the value of the relative percentage error of the proposed models is greater than 3%, which the authors adopted as the limit value.
- 2.
- The range of medians of kinematic viscosity of the tested oil is 6.7 mm2/s ≥ Y ≤ 70.0 mm2/s.
- 3.
- The range of highest kinematic viscosity values of the tested oil Y > 70.0 mm2/s is modeled by relations (3) and (4) (the range is derived from models indicated explicitly in ASTM D2270 and ISO 2909).
3. Results and Discussion
4. Example Application of the Model
5. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
List of Abbreviations and Symbols
A | empirical parameters for determining dynamic viscosity |
a1, a2, a3, a4, a5, a6 | coefficients of equations approximating the viscosity L |
ASTM | standard of ASTM International, formerly known as the American Society for Testing and Materials |
b1, b2, b3, b4, b5, b6 | coefficients of equations approximating the viscosity H |
ΔE | activation energy of viscous flow |
e | Euler number |
f(Y) | empirical function to determine the viscosity L |
f(Y) | empirical function to determine the viscosity H |
H | kinematic viscosity at 40 °C of a hypothetical oil with VI = 100, which has (at 100 °C) a kinematic viscosity equal to that of the oil under test at 100 °C |
ISO | International Organization for Standardization |
L | kinematic viscosity at 40 °C of a hypothetical oil with VI = 0, which has (at 100 °C) a kinematic viscosity equal to that of the oil under test at 100 °C |
RC | Clapeyron’s gas constant |
R2 | coefficient of determination |
SAE | SAE International, formerly the Society of Automotive Engineers |
SAE 30, SAE 40 | viscosity grades of lubricating oil according to SAE J300 standard |
T | absolute temperature in K |
t | relative temperature in °C |
TC23 | Technical Committee 23 of ISO |
U | kinematic viscosity of the tested oil at 40 °C |
VG | ISO viscosity grade |
VI | viscosity index |
VTC | viscosity–temperature coefficient |
x | analyzed parameter (viscosity or viscosity index) |
arithmetic mean of x determined from the model | |
xi | the i-th value of the analyzed parameter x |
the i-th value of x determined from the model | |
Y | kinematic viscosity of the tested oil at 100 °C |
shear rate | |
δi | relative percentage error |
ηt | dynamic viscosity at t |
ρ15 | density at 15 °C. |
ρt | density at t |
τ | shear stresses |
Appendix A
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Y | a1 | a2 | a3 | a4 | a5 | a6 |
(–) | ||||||
6.7 > ≥ 2.1 | 0.0074 | −0.3039 | 3.7190 | −17.6970 | 43.6760 | −33.9310 |
70.0 ≥ ≥ 6.7 | −1.84 × 10−7 | 3.20 × 10−5 | −0.0025 | 0.9966 | 6.1596 | −12.7890 |
> 70 | 0 | 0 | 0 | 0.8353 | 14.6700 | −216.0000 |
Y | b1 | b2 | b3 | b4 | b5 | b6 |
(–) | ||||||
2.1 ≤ Y < 6.7 | 0.0048 | −0.1204 | 1.0693 | −3.5619 | 10.0950 | −6.3650 |
6.7 ≤ Y ≤ 70 | −2.20 × 10−7 | 5.03 × 10−5 | −0.0046 | 0.3921 | 5.5020 | −7.7091 |
> 70 | 0 | 0 | 0 | 0.1684 | 11.8500 | −97.0000 |
Range of Values | Model L | Model H | |||
---|---|---|---|---|---|
R2 | δmax | R2 | δmax | ||
(mm2/s) | (–) | (%) | (–) | (%) | (mm2/s) |
2.1 ≤ Y < 6.7 | 0.9999 | <1.54 | 1.0000 | <0.24 | 2.1 ≤ Y < 6.7 |
6.7 ≤ Y ≤ 70 | 1.0000 | <1.74 | 1.0000 | <0.83 | 6.7 ≤ Y ≤ 70 |
> 70 | 1.0000 | 0.00 | 1.0000 | 0.00 | > 70 |
SAE Viscosity Grade of Lubricating Oil Used to Prepare the Mixture [8] | Diesel Oil Content in the Lubricating Oil Mixture | Viscosity of the Mixture at 40 °C | ISO Viscosity Grade of the Mixture or the Limit Grades between Which the Mixture Is Rated [7] |
---|---|---|---|
SAE Grade | C | U | ISO VG |
(–) | (% w/w) | (mm2/s) | (–) |
SAE 30 | 0 | 105.01 | ISO VG 100 |
1 | 98.06 | ISO VG 100 | |
2 | 96.64 | ISO VG 100 | |
5 | 82.70 | [ISO VG 68, ISO VG 100] | |
10 | 59.61 | [ISO VG 46, ISO VG 68] | |
20 | 36.25 | [ISO VG 32, ISO VG 46]. | |
50 | 11.07 | [ISO VG 10, ISO VG 15]. | |
100 | 2.897 | ISO VG 3 | |
SAE 40 | 0 | 159.90 | ISO VG 150 |
1 | 157.95 | ISO VG 150 | |
2 | 149.10 | [ISO VG 100, ISO VG 150] | |
5 | 123.95 | [ISO VG 100, ISO VG 150] | |
10 | 78.71 | [ISO VG 68, ISO VG 100] | |
20 | 50.29 | ISO VG 46 | |
50 | 13.25 | [ISO VG 10, ISO VG 15]. | |
100 | 2.897 | ISO VG 3 |
SAE 30 Grade Oil Based Mixtures | Viscosity Index VI Determined by a Method | Percentage Relative Error between Methods | |||
---|---|---|---|---|---|
With diesel oil concentration of C | Manual calculation according to ASTM D2270/ISO 2909 | Calculation with Anton Paar calculator | Calculation using an analytical model | Analytical model vs. Anton Paar calculator | Analytical model vs. manual calculation according to ASTM D2270/ISO 2909 |
(% w/w) | (–) | (–) | (–) | (%) | (%) |
0 | 99.27 | 99.28 | 98.90 | 0.38 | 0.38 |
1 | 97.18 | 97.29 | 96.46 | 0.85 | 0.74 |
2 | 97.49 | 97.62 | 96.78 | 0.86 | 0.73 |
5 | 106.76 | 106.97 | 106.04 | 0.88 | 0.67 |
10 | 111.58 | 111.46 | 110.33 | 1.02 | 1.12 |
20 | 128.91 | 129.17 | 129.20 | 0.03 | 0.22 |
50 | 132.37 | 132.57 | 132.25 | 0.24 | 0.09 |
SAE 40 Grade Oil Based Mixtures | Viscosity Index VI Determined by a Method | Percentage Relative Error between Methods | |||
---|---|---|---|---|---|
With diesel oil concentration of C | Manual calculation according to ASTM D2270/ISO 2909 | Calculation with Anton Paar calculator | Calculation using an analytical model | Analytical model vs. Anton Paar calculator | Analytical model vs. manual calculation according to ASTM D2270/ISO 2909 |
(% w/w) | (–) | (–) | (–) | (%) | (%) |
0 | 95.25 | 95.44 | 94.89 | 0.58 | 0.38 |
1 | 94.83 | 95.05 | 94.48 | 0.60 | 0.37 |
2 | 95.21 | 95.35 | 94.83 | 0.54 | 0.41 |
5 | 96.46 | 96.30 | 95.94 | 0.38 | 0.54 |
10 | 112.44 | 112.65 | 111.65 | 0.89 | 0.70 |
20 | 125.78 | 125.78 | 124.82 | 0.77 | 0.77 |
50 | 142.33 | 142.33 | 141.67 | 0.46 | 0.46 |
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Chybowski, L.; Szczepanek, M.; Ćwirko, K.; Marosek, K. Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils. Energies 2024, 17, 4908. https://doi.org/10.3390/en17194908
Chybowski L, Szczepanek M, Ćwirko K, Marosek K. Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils. Energies. 2024; 17(19):4908. https://doi.org/10.3390/en17194908
Chicago/Turabian StyleChybowski, Leszek, Marcin Szczepanek, Konrad Ćwirko, and Konrad Marosek. 2024. "Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils" Energies 17, no. 19: 4908. https://doi.org/10.3390/en17194908
APA StyleChybowski, L., Szczepanek, M., Ćwirko, K., & Marosek, K. (2024). Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils. Energies, 17(19), 4908. https://doi.org/10.3390/en17194908