2.2. Criteria of the Life Cycle Analysis
The nine LCA criteria used to assess silicon, thin film and organic solar energy cells are: I. energy efficiency; II. embedded energy; III. energy pay-back time; IV. avoided emissions; V. real lifetime; VI. balance of system; VII. cost of energy system; VIII. system dependability; and IX. decommissioning. They are briefly described below; details regarding their calculation and parameters are provided in the
Supplementary Materials.
I. Energy efficiency is the efficiency for energy conversion from a renewable (or fossil) source into practical work. For photovoltaic technology is defined as the power conversion efficiency (PCE, the ratio of power delivered by a solar module to the incident solar irradiance on the active area of the module) under standard conditions (1 kW/m2 at AM1.5 spectra, with cell temperature 25 °C and wind less than 1 m/s).
II. Embedded energy is the total amount of energy required to manufacture, transport, install, operate, and decommission the energy system. For SHS, this fluctuates between 45 and 56 GJ/kWp. The amount of embedded energy in solar systems depends on technical aspects and system boundaries, such as, for example, whether the decommissioning of batteries and panels includes their recycling [
22,
26,
34,
35,
36,
37,
38,
39,
40]. Research has demonstrated that the embedded energy in organic solar cells is relatively high, at 56.02 GJ/kWp for 5% power conversion efficiency and 28.01 GJ/kWp if 10% power conversion efficiency is assumed [
29]. For example, the embedded energy of dye-sensitized solar cells (DSSCs) is about 100–280 kWh per square metre of active solar cell area and the related CO
2 emissions have been calculated at 19 g to 47 g CO
2eq. per kWh of energy produced under different insolation levels, efficiency and lifetime [
41]. In summary, the lower this figure, the lower the level of embedded pollution.
III. Energy pay-back time
(EPBT) describes how long it takes a solar panel or solar system to generate the same amount of energy that was required to manufacture, transport and install it and perhaps also to decommission and recycle it. The shorter the period, the more recommended is the technology. Solar energy systems require between 4 to 7 years to generate the same amount of energy that was employed for their creation; this period is significantly shorter than the expected technical life of the systems, which is 20 to 25 years [
23,
24,
34,
36,
37,
38,
39].
IV. Avoided emissions implies the total CO
2eq. (when referred to CO
2 emissions, the unit used is CO
2 “equivalent”, which takes into account emissions of other Green House Gases and quantifies its impact in units’ equivalent to CO
2) that could be saved if electricity were generated by cleaner alternatives to fossil fuels. The avoided emission in relation to PV systems is, by and large, a measure dependent on location, because its calculation relies on physical indicators such as irradiance, average temperature, and energy mix of a particular region or country where the SHS is installed. Moreover, the embedded energy of the solar modules (see II above) is taken into consideration. For example, if a PV system replaces a diesel generator, the avoided emission is 1.27 kg of CO
2eq./kW [
23]. When electricity from PV panels is used instead of electricity from the national grids in the USA, the avoided emissions have been calculated as 0.522 kgCO
2eq./kWh, but it is 0.900 kgCO
2eq./kWh in Cuba [
42,
43]. The energy mix represents, for each country, all the electricity systems and their anticipated associated CO
2 emissions.
V. Real lifetime refers to the expected number of years that a PV system may remain in working order. The real life-time of SHS stated in any manufacturer’s guarantee is usually at least 25. If no technical failures had been reported, PV panels may generate electricity beyond the guaranteed lifetime. Whereas the life-time of SHS is considered primarily a technical concern, the effective operational life-time period (i.e., the operation ratio of solar systems) is often cut short by non-technical location-dependent factors. For example, regular maintenance, commercial networks that guarantee access to spare parts, socio-economic conditions such as education and social organization, and government supportive regulations and markets to enable access and equipment upkeep. System dependability (see VIII. below) is used to also achieve a deeper understanding of system lifetime and failure because it encompasses parameters such as user’s attitude and satisfaction, as well as maintenance routines [
33,
42,
43].
VI. Balance of system
(BoS
) refers to the additional parts that accompany a SHS and are necessary to achieve greater efficiency: the battery that stores power, the charger regulator, and the inverter if AC electricity is used. The embedded energy and CO
2 emissions from BoS can be substantial and therefore it is included in any LCA. The energy requirements of inverters for a 3 kWp residential PV system have been estimated at 0.5 MWhth (i.e., 0.17 MWhth/kWp) [
22]. Alsema (2000a) and Rydh & Sanden, (2005a, 2005b) [
40,
44,
45] suggest values of 1 MJ/Wel (0.277 MWhth/kWel) for inverters and charge regulators. It has been estimated that the power requirements of poor households range between 500 W and 1500 W [
46,
47]. The SURE-DSS model discussed in this article uses the highest values to calculate the energy pay-back time of BoS required for typical Solar Home Systems. The costs associated with BoS vary according to the purpose of installation, e.g., whether it is roof-top, building-integrated, or a ground-based design; country of installation; and technical characteristics such as size, surface area, and module efficiency. By 2013, the price of BoS for roof-top systems was between €1.1 to €0.9/Wp. It has been estimated that this will reduce further, to €0.75/Wp by 2020, and to less than €0.5/Wp by 2030 [
48]. A particular feature of BoS is that its cost is calculated independently of the rest of the SHS. For example, replacement of the power storage batteries—which, have the shortest lifetime of all the systems components—necessitates additional costs. Also, to a large degree, the choice of device varies, depending on the user. Cost reductions for BoS correlate with increased efficiency and reduced size of solar modules. The SURE-DSS model employs the BoS standard approved by the European Commission in 1998 [
49,
50], which has an emission factor of 66g CO
2eq./Wh for both batteries [
51] and charge regulators [
52]. Also, as SHS may employ small inverters to feed alternative current (AC) appliances, the embedded energy for a 500W inverter is used and the values are drawn on the Ecoinvent Database (2012) [
53] (
Table 1).
VII. Levelized cost of electricity represents the price per kWh of delivered electricity throughout the entire lifetime of the solar panel system; the levelized cost of electricity (LCOE) compares this value with the market costs to generate this energy. For example, in order to compete with electricity from fossil fuels, energy generation from PV should cost less than US$0.50 per Wp per installed solar panel; yet, the cost is still significantly higher at US$1.30/Wp to US$1/Wp [
54]. Cost comparisons between small stand-alone solar installations and other off-grid energy systems, such as diesel generators—widely used in rural areas—have favoured photovoltaic panels [
49,
55].
Most cost projections for solar technology have focused on silicon-based solar panels and results indicate that prices will continue to decrease at historic rates [
56,
57]. Chinese manufacturers, such as SunTech, YingLi Solar, Trina Solar, are close to achieving a market low of between €1/Wp, and €0.75/Wp by 2025, and if BoS costs were included, the price would range from €2.5/Wp for small stand-alone systems to €1.5/Wp for grid connected systems larger than 100 kWp [
58].
If the LCOE of thin film and organic cells were to be taken into consideration, additional advantages might well emerge in favour of solar energy solutions because solar thin film technologies require significantly less material and energy than conventional crystalline silicon modules. Future cost reduction of amorphous silicon (a-Si:H), cadmium telluride (CdTe) and copper indium diselenide (CIS) is forecast as the technology advances [
27,
40,
57]. Other thin film cells have been priced similarly, ranging from €0.9 to €1.1/Wp. Yet, lower prices, of between €0.6 and €0.7/Wp, have been obtained in 2016 for both a-Si:H and microcrystalline-Si modules, with efficiencies of 10% and 11% respectively. Thin film technologies have virtually attained the efficiency target set by the European Photovoltaic Technology Platform of above 10% with associated production costs below 0.7 €/Wp on rigid substrates [
48,
58]; The corresponding targets for flexible substrates are 10% and €0.6/Wp respectively. Intensive R&D, low-cost and high-volume production of thin-film PV modules are required to achieve €0.5/Wp by 2025 [
48,
58]. A main challenge facing thin film technologies is up-scaling global production capacity. Japan, the USA and Europe already deploy advanced thin film R&D infrastructure, with factory facilities, and generation via this means is forecast to reach 10 GWp/year and 13.3 GWp/year by 2017 [
48].
The prospects for improved efficiency, cost and production of organic solar technologies—including dye-sensitized solar (DSSC) [
59] and fully organic—were predicted more than two decades ago [
60,
61,
62,
63,
64]. A remarkable 10.6% efficiency high has been achieved for organic tandem cells [
65]; and over 20% on a new family of cells based on organic perovskites [
65,
66]. However, the stability of the manufactured cells remains limited and lifetimes are still well below those of Si-cells. Prices ranging between €0.5/Wp and €0.1/Wp by 2020 have been predicted for 1 GWp production scale, [
67,
68]. An organic solar cells in a lighting project in Africa has been demonstrated. Although the cost of the organic solar cells and hybrid technologies has not been compared to that of other off-grid systems, initial estimates of photovoltaic power conversion also promise cost reductions [
68].
The LCOE of organic solar cells at €0.19/kWh to €0.50kWh is significantly lower than that of silicon cells. A hybrid tandem technology with a potential 20% efficiency and a cost of $0.50 per Wp could significantly reduce the LCOE [
69].
VIII. System dependability (SD). With the exception of cost, the factors discussed above are location-dependent, which means that elements such as where the solar systems are manufactured, where to and how they are transported, and the energy mix and level of CO
2 emissions at the country of installation are all important. SD ultimately affects the amount of embedded energy, avoided emissions, and pay-back-time of any PV installation. For example, the intensity of natural radiance and the average daily temperature at a particular location affect the capacity of solar panels to generate energy per surface of installed unit. Location is crucial in determining the total energy produced by a PV system during its lifetime. Moreover, non-technical factors relating to SHS such as users’ behaviour, views and expectations can be equally sensitive to geographical location (see V. Real lifetime above). Assessment of system dependability aims to achieve a better understanding of system failure and point to ways to extend the systems’ real lifetime to their technical limit [
33,
42]. Lastly:
IX. Decommissioning is the process whereby the equipment that is left behind at the end of the systems operational life is disposed of. Recycling PV modules could save two thirds of the energy expended in their assembly [
70]; while battery recycling plays a positive role in terms of reducing the environmental impact of standalone solar systems [
71]. Advances have been made in the recycling of crystalline silicon and thin film modules. However, only preliminary results are available regarding the treatment of the aluminium and glass found in thin film and organic modules. Organic polymers, nanoparticles and other electrodes (Ca/Al) contained in the systems are not currently recycled but deposited in landfills [
35,
72].
Energy supply to the poor in developing countries could potentially be increased through solar energy installations. So far, the silicon solar cell type has dominated the provision of solar energy in poor regions. The proposed systematic assessment seeks to assist decision-makers to also take into account the overall levels of CO2 in the technology when they plan to increase energy access in developing countries.