Ion Transport Properties and Ionicity of 1,3-Dimethyl-1,2,3-Triazolium Salts with Fluorinated Anions
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Methods
3. Results and Discussion
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Triazolium Salt | Cation | Anion | V+ (Å3) | V− (Å3) | Tm (°C) | Td10 (°C) | ρ (g cm−3) |
---|---|---|---|---|---|---|---|
[DMTR][F] | | | 154 1 | 10 2 | --- 5 | 155 | --- |
[DMTR][OTf] | | | 154 1 | 129 3 | 49.0 | 360 | 1.467 |
[DMTR][NTf2] | | | 154 1 | 248 4 | 46.1 | 385 | 1.583 |
Ionic Liquid | Λ (S cm2 mol−1) | I | Λ∞ (S cm2 mol−1) | Ea (kJ mol−1) | T0 (K) |
---|---|---|---|---|---|
[DMTR][OTf] | 3.3 | 0.65 | 172 | 5.06 | 169 |
[DMTR][NTf2] | 3.7 | 0.76 | 264 | 5.74 | 162 |
[DMIM][NTf2] 1 | 2.5 | 0.76 | --- | --- | --- |
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Pulst, M.; Golitsyn, Y.; Reichert, D.; Kressler, J. Ion Transport Properties and Ionicity of 1,3-Dimethyl-1,2,3-Triazolium Salts with Fluorinated Anions. Materials 2018, 11, 1723. https://doi.org/10.3390/ma11091723
Pulst M, Golitsyn Y, Reichert D, Kressler J. Ion Transport Properties and Ionicity of 1,3-Dimethyl-1,2,3-Triazolium Salts with Fluorinated Anions. Materials. 2018; 11(9):1723. https://doi.org/10.3390/ma11091723
Chicago/Turabian StylePulst, Martin, Yury Golitsyn, Detlef Reichert, and Jörg Kressler. 2018. "Ion Transport Properties and Ionicity of 1,3-Dimethyl-1,2,3-Triazolium Salts with Fluorinated Anions" Materials 11, no. 9: 1723. https://doi.org/10.3390/ma11091723